Abstract
The use of organic basic dyes for the determination of the surface adsorption in different materials is one of the oldest ways of measuring the adsorption capacity or the amount of exchange sites of small-size particles and colloidal material (Mäkitie and Erviö, 1966). Methylene blue (MB) is an organic cationic dye with formula C16H18N3SCI.3H20. The molecule can be regarded approximately as a rectangular volume of dimensions 17.0 x 7.6 x 3.3 Å. The projected area of the molecule has been given by several authors (quoted in Hang and Brindley, 1970; Taylor, 1985). Estimated values ranged between 130-135 Å2.
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References
Bergmann, K. and O’Konski, CT., 1963. A spectroscopic study of methylene blue monomer, dimer, and complexes with montmorillonite. J. Phys. Chem., 67, 2169–2177.
Casanova, F.J., 1986. O ensaio do azul de metileno na caracterizaçao de solos lateriticos. 21 Reuniao Annual de Pavimentaçao. Salvador-Ba, 277–285.
Gillman, G.P., Bruce, R.C., Davey, B.G., Kimble, J.M., Searle P.L. and Skjemstad, J.O., 1983. A comparison of methods used for determination of cation exchange capacity. Commun. Soil Sci. Plant Anal., 14,1005–1014.
Hang, P.T. and Brindley, G.W., 1970. Methylene blue absorption by clay minerals. Determination of surface areas and cation exchange capacities (Clay-organic studies XVIII). Clays and Clay Minerals, 18,203–212.
Kitsopoulos, K.P., 1997. Comparison of the methylene blue absorption and the ammonium acetate saturation methods for the determination of CEC values of zeolite-rich tuffs. Clay Minerals, 32, 319–322.
Leiteizen, M.G., Pashkevich, L.A., Firfarova, I.B. and Tsekhovolskaya, D.I., 1978. Characteristics of sodium hydroalumino-silicates forming during bauxite digestion. In: Research Inst. Non-ferrous Metal (Editor). Proc. 2nd Conf. VAMI and FKI. Leningrad, pp. 167–179.
Mäkitie, O. and Erviö, R., 1966. Comparative studies on the cation exchange properties of mineral soils by the methylene-blue adsorption method and by the ammonium acetate method. Annales Agriculturae Fenniae, 5,260–266.
Plesh, P.H. and Robertson, R.H.S., 1948. Adsorption on to ionogenic surfaces. Nature, 161, 1020–1021.
Savant, N.K., 1994. Simplified methylene blue method for rapid determination of cation exchange capacity of mineral soils. Commun. Soil Sci. Plant Anal., 25, 3357–3364.
Taylor, R.K., 1985. Cation exchange in clays and mudrocks by methylene blue. J. Chem. Tech. Biotechnol., 35A, 195–207.
Wang, M.K. and Wang, S.H., 1987. Evaluation of methylene blue tests for determining CEC of bentonite and shales. Journal of the Chinese Agricultural Chemical Society, 25,387–397.
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© 1999 Springer Science+Business Media New York
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Arias, M. et al. (1999). Adsorption of Methylene Blue by Red Mud, An Oxide- Rich Byproduct of Bauxite Refining. In: Berthelin, J., Huang, P.M., Bollag, JM., Andreux, F. (eds) Effect of Mineral-Organic-Microorganism Interactions on Soil and Freshwater Environments. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4683-2_39
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DOI: https://doi.org/10.1007/978-1-4615-4683-2_39
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