Abstract
A large fraction of gases dissolved in surface and groundwater, mainly N2, O2 and the noble gases He, Ne, Ar, Kr and Xe, originate from the atmosphere. Whenever water comes into contact with the atmosphere, or other phases such as natural gas, oil and solid organic matter, gases are exchanged and gas concentrations of the individual phases record some characteristics of these processes. Even in the absence of a separate gas phase, dissolved gas concentrations in a water parcel may change as a result of molecular diffusion, and mixing on a variety of space and time scales. However, in many cases the impacts of most of these processes on the dissolved gas concentrations are small and the dominating processes may be reconstructed from the measured concentrations of the dissolved gases. This chapter deals with atmospheric noble gases dissolved in groundwater, which reliably record information on certain physical processes due to the lack of chemical reactions which affect them. As has been shown in studies performed over the past 40 years, atmospheric noble gases dissolved in groundwater yield valuable information on palaeoclimate, in particular temperature at the time of recharge, dynamics of groundwater flow, and denitrification and oxygen consumption rates.
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References
Aeschbach-Hertig W., Peeters F., Beyerle U. and Kipfer R. (1999) Interpretation of dissolved atmospheric noble gases in natural waters. Water Resour. Res., in press.
Amundson R.G. and Davidson E.A. (1990) Carbon dioxide and nitrogenous gases in the soil atmosphere. J. Geochem. Explor. 28, 13–41.
Andrews J.N. and Lee D.J. (1979) Inert gases in groundwater from the Bunter Sandstone of England as indicators of age and palaeoclimatic trends. J. Hydrol. 41, 233–252.
Andrews J.N. (1992) Mechanisms for noble gas dissolution by groundwaters. Isotopes of Noble Gases as Tracers in Environmental Studies, pp.87–110. IAEA, Vienna.
Andrews J.N., Fontes J.C., Aranyossy J.F., Dodo A., Edmunds W.M., Joseph A. and Travi Y. (1994) The evolution of alkaline groundwaters in the continental intercalaire aquifer of the Irhazer Plain, Niger. Water Resour. Res. 30, 45–61.
Ballentine C.J. and Hall C.M. (1999) Determining palaeotemperature and other variables using noble gas concentrations in water. Geochim. Cosmochim. Acta, in press.
Bath A.H., Edmunds W.M. and Andrews J.N. (1978) Palaeoclimatic trends deduced from the hydrochemistry of a Triassic sandstone aquifer, United Kingdom. Isotope Hydrology, Vol. 2, pp.545–566. IAEA, Vienna.
Battino R. and Clever H.L. (1979a) Helium, Neon-Gas Solubilities. Solubility Data Series, International Union of Pure and Applied Chemistry. Pergamon Press, Oxford.
Battino R. and Clever H.L. (1979b) Argon-Gas Solubilities. Solubility Data Series, International Union of Pure and Applied Chemistry. Pergamon Press, Oxford.
Bear J. and Verruijt A. (1987) Modeling Groundwater Flow and Pollution. D. Reidel, Dordrecht, 414 pp.
Benson B.B. and Krause D. Jr. (1976) Empirical laws for dilute aqueous solutions of nonpolar gases. J. Chem. Phys. 64, 689–709.
Bentley H.W., Phillips F.M. and Davis S.N. (1986) Chlorine-36 in the terrestrial environment. In Handbook of Environmental Isotope Geochemistry, Vol. 2, eds. P. Fritz and J.-C. Fontes, pp.427–480. Elsevier, Amsterdam.
Beyerle U., Purtschert R., Aeschbach-Hertig W., Imboden D.M., Loosli H.H., Wieler R. and Kipfer R. (1998) Climate and groundwater recharge during the last glaciation in an icecovered region. Science 282, 731–734.
Blavoux B., Dray M., Fehri A., Olive P., Groening M., Sonntag C., Hauquin J.P., Pelissier G. and Pouchan P. (1993) Palaeoclimatic and hydrodynamic approach to the Aquitaine Basin deep aquifer (France) by means of environmental isotopes and noble gases. Isotope Techniques in the Study of Past and Current Environmental Changes in the Hydrosphere and the Atmosphere, pp.293–305. IAEA, Vienna.
Blicher-Mathiesen G., McCarty G.W. and Nielson L.P. (1998) Denitrification and degassing in groundwater estimated from dissolved dinitrogen and argon. J. Hydrol. 208, 16–24.
Bosch A. and Mazor E. (1988) Natural gas association with water and oil as depicted by atmospheric noble gases: case studies from the southeastern Mediterranean Coastal Plain. Earth Planet. Sci. Lett. 87, 338–346.
Brook G.A., Folkoff M.E. and Box E.O. (1983) A world model of soil carbon dioxide. Earth Surf. Process. Landforms 8, 79–88.
Clark J.F., Stute M., Schlosser P., Drenkard S. and Bonani G. (1997) An isotope study of the Floridan Aquifer in southeastern Georgia: implications for groundwater flow and palaeoclimate. Water Resour. Res. 33, 281–290.
Clark J.F., Davisson M.L., Hudson G.B. and Macfarlane P.A. (1998) Noble gases, stable isotopes, and radiocarbon as tracers of flow in the Dakota Aquifer, Colorado and Kansas. J. Hydrol. 211, 151–167.
Clever H.L. ed. (1979) Krypton, Xenon and Radon-Gas Solubilities, Solubility Data Series, Vol. 2, International Union of Pure and Applied Chemistry. Pergamon Press, Oxford.
Crank J. (1980) The Mathematics of Diffusion. Oxford University Press, New York, 424 pp.
Davidson M.R. and Airey P.L. (1982) The effect of dispersion on the establishment of a palaeoclimatic record from groundwater. J. Hydrol., 58, 131–147.
Deák J., Stute M., Rudolph J. and Sonntag C. (1987) Determination of the flow regime of Quaternary and Pliocene layers in the Great Hungarian Plain (Hungary) by D, 18O, 14C, and noble gas measurements. Isotope Techniques in Water Resources Development, pp.335–350. IAEA, Vienna.
Dennis F., Andrews J.N., Parker A., Poole J. and Wolf M. (1997) Isotopic and noble gas study of chalk groundwater in the London Basin, England. Appl. Geochem. 12, 763–773.
Domenico P.A. and Schwartz F.W. (1990) Physical and Chemical Hydrogeology. John Wiley and Sons, New York, 824 pp.
Edmunds W.M., Fellman E., Baba Goni I., McNeill G.W. and Harkness D.D. (1998) Groundwater, palaeoclimate and palaeorecharge in the southwest Chad Basin, Borno State, Nigeria. Isotope Techniques in Studying Past and Ccurrent Environmental Changes in the Hydrosphere and Atmosphere, pp.693–707. IAEA, Vienna.
Fairbanks R.G. (1989) A 17 000-year glacio-eustatic sea level record; influence of glacial melting rates on the Younger Dryas event and deep-ocean circulation. Nature 342, 637–642.
Fairbanks R.G. and Matthews R.K. (1978) The marine oxygen isotope record in Pleistocene coral, Barbados, West Indies. Quat. Res. 10, 181–196.
Fontes J.-C. and Gamier J.M. (1979) Determination of the initial !4C activity of the total dissolved carbon—a review of the existing models and a new approach. Water Resour. Res. 15, 399–413.
Fontes J.-C, Andrews J.N., Edmunds W.M., Guerre A. and Travi Y. (1991) Palaeorecharge by the Niger River (Mali) deduced from groundwater geochemistry. Water Resour. Res. 27, 199–214.
Franson M.A.H. (1992) Standard Methods for the Examination of Water and Wastewater. American Public Health Association, Washington, DC.
Freeze R.A. and Cherry J.A. (1979) Groundwater. Prentice-Hall, Englewood Cliffs, 604 pp.
Fuchs G., Roether W. and Schlosser P. (1987) Excess 3He in the ocean surface layer. J. Geophys. Res. 92(C6), 6559–6568.
Grootes P.M., Stuiver M., White J.W.C., Johnsen S. and Jouzel J. (1993) Comparison of oxygen isotope records from the GISP2 and GRIP Greenland ice cores. Nature 366, 552–554.
Heaton T.H.E. (1981) Dissolved gases: some applications to groundwater research. Trans. Geol. Soc. S. Afr. 84, 91–97.
Heaton T.H.E. and Vogel J.C. (1981) ‘Excess air’in groundwater. J. Hydrol. 50, 201–216.
Heaton T.H.E., Talma A.S. and Vogel J.C., (1983) Origin and history of nitrate in confined groundwater in the Western Kalahari. J. Hydrol. 62, 243–262.
Heaton T.H.E., Talma A.S. and Vogel J.C. (1986) Dissolved gas palaeotemperatures and 18O variations derived from groundwater near Uitenhage, South Africa. Quat. Res. 25, 79–88.
Heaton T.H.E. (1984) Rates and sources of 4He accumulation in groundwater. Hydrol. Sci. J. 29, 29–47.
Herzberg O. and Mazor E. (1979) Hydrological applications of noble gases and temperatures measurements in underground water systems: examples from Israel. J. Hydrol. 41, 217–231.
Hofer M. and Imboden D.M. (1998) Simultaneous determination of CFC-11, CFC-12, N2, and Ar in water. Anal. Chem. 70, 724–729.
Jähne B., Heinz G. and Dietrich W. (1987) Measurements of the diffusion coefficients of sparingly soluble gases in water. J. Geophys. Res. 92(C10), 10767–10776.
Jenkins W.J. and Clarke W.B. (1976) The distribution of 3He in the western Atlantic Ocean. Deep Sea Res. 23, 481–494.
Kappelmeyer O. (1968) Beiträge zur Erschliessung von Thermalwässern und natürlichen Dampfvorkommen. Ceol. Jahrbuch 85, 708–808.
Levich V.G. (1962) Physicochemical Hydromechanics. Prentice Hall, Englewood Cliffs, 700 pp.
Lide D.R. ed. (1994) Handbook of Chemistry and Physics. CRC Press, Boca Raton.
Lehmann B.E., Oeschger H., Loosli H.H., Hurst G.S., Allman S.L., Chen C.H., Kramer S.D., Payne M.G., Phillips R.C., Willis R.D. and Thonnard N. (1985) Counting 81Kr atoms for analysis of groundwater. J. Geophys. Res. 90(B13), 11547–11551.
Lehmann B.E., Davis S.N. and Fabryka-Martin J.T. (1993) Atmospheric and subsurface sources of stable and radioactive nuclides used for groundwater dating. Water Resour. Res. 29, 2027–2040.
Mazor E. (1972) Palaeotemperatures and other hydrological parameters deduced from noble gases dissolved in groundwaters, Jordan Rift Valley Israel. Geochim. Cosmochim. Acta 36, 1321–1336.
Mazor E. (1997) Chemical and Isotopic Groundwater Hydrology; the Applied Approach. Marcel Dekker, New York, 413 pp.
Meese D., Alley R., Gow T., Grootes P.M., Mayewski P., Ram M., Taylor K., Waddington E. and Zielinski G. (1994) Preliminary depth-age scale of the GISP2 ice core. CRREL Special Report 94-1.
Oana S. (1957) Bestimmung des Argons im besonderen Hinblick auf gelöste Gases in natürlichen Wässern. J. Earth Sci. (Nagoya Univ.) 5, 103–124.
Ozima M. and Podosek F.A. (1983) Noble Gas Geochemistry. Cambridge University Press, Cambridge, 367 pp.
Pearson Jr. F.J. Fisher D.W. and Plummer L.N. (1978) Correction of ground-water chemistry and carbon isotopic composition for effects of CO2 outgassing. Geochim. Cosmochim. Acta 42, 1799–1807.
Pearson Jr. F.J. and White D.E. (1967) Carbon-14 ages and flow rates of water in the Carrizo Sand, Atascosa County, Texas. Water Resour. Res. 3, 251–261.
Phillips F.M. (1981) Noble gases in ground water as palaeoclimatic indicators. Unpubl. PhD thesis, University of Arizona.
Phillips F.M., Tansey M.K. and Peeters L.A. (1989) An isotopic investigation of groundwater in the central San Juan Basin, New Mexico: carbon 14 dating as a basis for numerical flow modeling. Water Resour. Res. 25, 2259–2273.
Plummer L.N., Prestemon E.C. and Parkhurst D.L. (1991) An interactive code (NETPATH) for modeling net geochemical reactions along a flow path. U.S. Geological Survey, Water-Resources Investigation Report 91-4078.
Poole J.C., McNeill G.W., Langman S.R. and Dennis F. (1997) Analysis of noble gases in water using a quadrupole mass spectrometer in static mode. Appl. Geochem. 12, 707–714.
Rind D. (1987) Components of the ice age circulation. J. Geophys. Res. — Atmos. 92, 4241–4281.
Rudolph J. (1981) Edelgastemperaturen und Heliumalter 14C-datierter Paläowässer. Unpubl. thesis, University of Heidelberg.
Rudolph J., Rath H.K. and Sonntag C. (1984) Noble gases and stable isotopes in 14C-dated palaeowaters from central Europe and the Sahara. Isotope Hydrology, pp.467–477. IAEA, Vienna.
Schachtschabel P., Blume H.P., Hartge K.H. and Schwertmann U. (1982) Lehrbuch der Bodenkunde, Enke, Stuttgart.
Severinghaus J.P., Bender M.L., Keeling R.F. and Broecker W.S. (1996) Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion. Geochim. Cosmoschim. Acta 60, 1005–1018.
Smith G.D., Newhall F., Robinson L.H. and Swanson D. (1964) Soil temperature regimestheir characteristics and predictability. US Department of Agriculture, Soil Conservation Service. Rep. SCS-TP-144.
Smith S.P. and Kennedy B.M. (1983) The solubility of noble gases in water and in NaCl brine. Geochim. Cosmochim. Acta 47, 503–515.
Sowers T., Bender M., Labeyrie L., Martinson D., Jouzel J., Raynaud D., Pichon J.J. and Korotkevich Y. (1993) 135 000 Year Vostok-SPECMAP common temporal framework. Palaeoceanography 8, 737–766.
Stuiver M., Grootes P.M. and Braziunas T.F. (1995) The GISP2 δ18O climate record of the past 16,500 years and the role of the sun, ocean, and volcanoes. Quat. Res. 44, 341–354.
Stute M. (1989) Edelgase im Grundwasser-Bestimmung von Paläotemperaturen und Untersuchung der Dynamik von Grundwasserfließsystemen. Unpubl. PhD thesis, University of Heidelberg.
Stute M. and Deák J. (1989) Environmental isotope study (14C, 13C, 18O, D, noble gases) on deep groundwater circulation systems in Hungary with reference to palaeoclimate. Radiocarbon 31, 902–918.
Stute M. and Sonntag C. (1992) Palaeotemperatures derived from noble gases dissolved in groundwater and relation to soil temperature. Isotopes of Noble Gases as Tracers in Environmental Studies, pp.111–122. IAEA, Vienna.
Stute M. and Schlosser P. (1993) Principles and applications of the noble gas palaeothermometer. In Climate Change in Continental Isotopic Records, eds. P.K. Swart, K.C. Lohmann, J. McKenzie and S. Savin, pp.89-100. American Geophysical Union, Geophysical Monograph 78.
Stute M, Schlosser P., Clark J.F. and Broecker W.S. (1992) Palaeotemperatures in the southwestern United States derived from noble gas measurements in groundwater. Science 256, 1000–1003.
Stute M., Forster M., Frischkorn H., Serejo A., Clark J.F. Schlosser P., Broecker W.S. and Bonani G. (1995a) Cooling of tropical Brazil (5°C) during the last glacial maximum. Science 269, 379–383.
Stute M., Clark J.F., Schlosser P., Broecker W.S. and Bonani G. (1995b) A high altitude continental palaeotemperature record derived from noble gases dissolved in groundwater from the San Juan Basin, New Mexico. Quat. Res. 43, 209–220.
Stute M. and Talma S. (1998) Glacial temperatures and moisture transport regimes reconstructed from noble gases and O-18, Stampriet aquifer, Namibia. Isotope Techniques in Studying Past and Current Environmental Changes in the Hydrosphere and the Atmosphere, pp.307–318. IAEA, Vienna.
Suckow A. and Sonntag C. (1993) The influence of salt on the noble gas thermometer. Isotope Techniques in Studying Past and Current Environmental Changes in the Hydrosphere and the Atmosphere, pp.307–318. IAEA, Vienna.
Sugisaki R. (1961) Measurements of effective flow velocity of ground water by means of dissolved gases. Am. J. Sci. 259, 144–153.
Tamers M.A. (1967) Radiocarbon ages of groundwater in an arid zone unconfined aquifer. In Isotope Techniques in the Hydrologic Cycle, ed. G.E. Stout, Geophys. pp. 143-152, American Geophysical Union, Geophysical Monograph 11.
Top Z., Eismont W.C. and Clarke W.B. (1987) Helium isotope effect and solubility of helium and neon in distilled water and seawater. Deep Sea Res. 34, 1139–1148.
Toy T.J., Kuhaida Jr. A.J. and Munson B.E. (1978) The prediction of mean monthly soil temperature from mean monthly air temperature. Soil Sci. 126, 181–189.
Tredoux G. and Kirchner J. (1981) The evolution of the chemical composition of artesian water in the Auob sandstone (Namibia/South West Africa). Trans. Geol. Soc. S. Afr. 84, 169–175.
U.S. Standard Atmosphere (1976) National Oceanic Administration, National Aeronautics and Space Administration, and the United States Air Force, Washington, DC.
Vogel J.C., (1967) Investigation of groundwater flow with radiocarbon. Isotope Hydrology, pp.235–237. IAEA, Vienna.
Vogel J.C., Talma A.S. and Heaton T.H.E. (1981) Gaseous nitrogen as evidence for denitrification in groundwater. J. Hydrol. 50, 191–200.
Weiss R.F. (1970) The solubility of nitrogen, oxygen and argon in water and seawater. Deep Sea Res. 17, 721–735.
Weiss R.F. (1971) Solubility of helium and neon in water and seawater. J. Chem. Eng. Data, 16, 235–241.
Weiss R.F. (1968) Piggyback samplers for dissolved gas studies on sealed water samples. Deep Sea Res. 15, 695–699.
Weiss R.F. and Price B.A. (1989) Dead Sea gas solubilities. Earth Planet. Sci. Lett. 92, 7–10.
Wilson G.B. and McNeill G.W. (1997) Noble gas recharge temperatures and the excess air component. Appl. Geochem. 12, 747–762.
Wilson G.B., Andrews J.N. and Bath A.H. (1990) Dissolved gas evidence for denitrification in the Lincolnshire limestone groundwaters, Eastern England. J. Hydrol. 113, 51–60.
Winograd I.J. and Robertson F.N. (1982) Deep oxygenated ground water: anomaly or common occurrence? Science 216, 1227–1230.
Zanker A. (1977) Inorganic gases in petroleum. Hydrocarbon Processing 56, 255–256.
Zuber A., Weise S.M., Osenbrück K., Grabczak J. and Ciezkowski W. (1995) Age and recharge area of thermal waters in Ladek Spa (Sudeten, Poland) deduced from environmental isotope and noble gas data. J. Hydrol. 167, 327–349.
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Stute, M., Schlosser, P. (2000). Atmospheric Noble Gases. In: Cook, P.G., Herczeg, A.L. (eds) Environmental Tracers in Subsurface Hydrology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4557-6_11
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