Abstract
The recent discovery of perchlorate contamination in the ground water of several western states has resulted in widespread concern over the quality of drinking water supplies. Ammonium perchlorate has been found in commercial fertilizers and is used as the oxidizer and main ingredient in solid rocket propellants, fireworks, and munitions. The current acceptable level for the presence of perchlorate in drinking water is 18 parts per billion (ppb). However, it has been found at concentrations as high as 0.37% in ground water near munitions manufacturing and testing facilities.1–11 Perchlorate contamination has also been found in areas such as Texas, where fertilizers are used to maintain land for cattle farming. Two of the main ingredients in these commercial fertilizers, potash and Chilean nitrate, have been shown by Air Force Research Laboratory to contain up to 0.57% by weight perchlorate. Although these deposits contain the necessary ingredients for fertilizers, they are also a very rich source of perchlorate.9–11
This work was presented at the 218th national meeting of the American Chemical Society as part of the Environmental Division symposium Perchlorate in the Environment, held August 22–24, 1999, in New Orleans, Louisiana.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Manning, M. Las Vegas Sun, September 23, 1997.
Manning, M. Las Vegas Sun, September 24–25, 1997.
Manning, M. Las Vegas Sim, September 20, 1997.
Manning, M. Las Vegas Sun, September 8, 1997.
Manning, M. Las Vegas Sun, October 3, 1997.
Manning, M. Las Vegas Sun, January 27, 1998.
“Perchlorate in California Drinking Water.” California Department of Health Services, September 1997; http://www/dhs.cahwnet.gov/perevsrv/ddwem/perchl.htm#advice.
Mattie, D.R.; Jarabek, A.M. “Perchlorate environmental contamination: testing strategy based on mode of action.” The Toxicologist. Toxicological Sciences 1999, 48, 113.
Ericksen, G.E. “Geology and origin of the Chilean nitrate deposits.” United States Government Printing Office: Washington, DC, 1981.
Van Moort, J.C. “Natural enrichment processes of nitrate, sulfate, chloride, iodate, borate, perchlorate, and chromate in the caliches of Northern Chile.” IV Congreso Geologico Chileno: Universidad del Norte Chileno, 1985.
Eldridge, J.E.; Tsui, D.T. Personal communication, May 1999.
Welcher, F. J. Organic Analytical Reagents. Van Nostrand: New York, NY, 1947; Vol. 3, pp. 138–146, and references therein.
Welcher, F. J. Organic Analytical Reagents. Van Nostrand: New York, NY, 1948; Vol. 3., pp. 326–327.
Harris, D. C. Quantitative Chemical Analysis, 3rd ed. Freeman: New York, NY, 1991; pp. 146, 722–723.
Hayes, O. B. “Studies in qualitative inorganic analysis. Part XXXII.”Mikrochimica Acta 1968, 3, 647–648.
Chadwick, T. C. “2.4.6-Triphenylpyrylium chloride. Anew organic analytical reagent for the determination of certain anions.” Analytical Chemistry 1973, 45, 985–986.
Burns, D. T.; Chimpalee, N.; Harriot, M. “Flow-injection extraction-spectrophotometric determination of perchlorate with brilliant green.” Analytica Chimica Acta, 1989, 217, 177–181.
Burns, D. T.; Hanprasopwattana, P. “The spectrophotometric and spectro-fluorimetric determination of perchlorate by extraction with amiloride hydrochloride.” Analytica Chimica Acta 1980, 118, 185–189.
Weiss, J.A.; Stanbury, J.B. “Spectrophotometric determination of micro amounts of perchlorate in biological fluids.” Analytical Chemistry 1972, 44, 619–620.
Kawase, J.; Nakae, A.; Yamanaka, M. “Determination of anionic surfactants by flow injection analysis based on ion-pair extraction.” Analytical Chemistry 1979, 51, 1640.
Kawase, J. “Automated determination of cationic surfactants by flow injection analysis based on ion-pair extraction.” Analytical Chemistry 1980, 52, 2124–2127.
Yamamoto, Y.; Okamoto, N.; Tao, E. “Spectrophotometric determination of anions by solvent extraction with cuproin or neocuproin-copper(I) chelate cations.” Analytica Chimica Acta 1969, 47, 121–137.
Avdalovic, N.; Pohl, C.A.; Rocklin, R.D.; Stillian, J.R. “Determination of cations and anions by capillary electrophoresis combined with suppressed conductivity detection.” Analytical Chemistry 1993, 65, 1470–1475.
Nann, A.; Pretsch, E. “Potentiometric detection of anions separated by capillary electro phoresis using an ion-selective microelectrode.” Journal of Chromatography A 1994, 676, 421–442.
Gross, L.; Yeung, E. S. “Indirect fluorimetric detection and quantification in capillary zone electrophoresis of inorganic anions and nucleotides.” Journal of Chromatography A 1989, 480, 169–178.
Okada, T. “Electrophoretic detection and evaluation of heteroconjugate anion formation between Bronsted acids and the perchlorate ion in acetonitrile.” Chemical Communi cations 1996, 6, 1779–1780.
Holderbeke, M.V.; Vanhoe, H.; Moens, L.; Dams, R. “Determination of ten inorganic anions in drinking and waste waters with capillary zone electrophoresis (CZE) via indirect UV-detection.” Biomedical Chromatography 1995, 9, 281–282.
De Backer, B. L.; Nagels, L. J.; Alderweireldt, F. C. “Liquid Chromatographic determination of acids and anions using liquid membrane ion-selective electrodes in a potentiometric flow-through detector.” Analytica Chimica Acta 1993, 273, 449–456.
Hauser, P.C.; Renner, N.D.; Hong, A.P.C. “Anion detection in capillary electrophoresis with ion-selective microelectrodes.” Analytica Chimica Acta 1994, 295, 181–186.
Hauser, P.C.; Hong, A.P.C; Renner, N.D. “Surface charge reversal for inorganic anion determination in capillary electrophoresis with an ion-selective microelectrode as detector.” Journal of Capillary Electrophoresis 1995, 5, 209–212.
Guilbault, G.G.; Rohm, T. “Ion-selective electrodes and enzyme electrodes in environ mental and clinical studies.” International Journal of Environmental and Analytical Chemistry 1975, 4, 51–64.
Krokhin, O.V.; Elefterov, A.I.; Obrezkov, O.N.; Shpigun, O.A. “Increase in the sensi tivity of the ion Chromatographic determination of strongly retained anions.” Zhurnal Analiticheskoi Khimii 1993, 48, 111–116.
Williams, R. J. “Determination of inorganic anions by ion chromatography with ultraviolet absorbance detection.” Analytical Chemistry 1983, 55, 851–854.
California Department of Health Services, Sanitation and Radiation Laboratories Branch. Determination of Perchlorate by Ion Chromatography, Rev. O. June 3, 1997.
Dionex Application Note 121. Dionex Corporation: Sunnyvale, CA, 1998.
Wirt, K.; Laikhtman, M.; Rohrer, J.; Jackson, P.E. American Environmental Laboratory 1998, 10,1,5.
“Standard Operating Procedure for Perchlorate.” EPA Office of Water. URL: http://www.epa.gov/OGWDW/ccl/perchlor/perchlo.html.
Chaudhuri, S.; Okamoto, H.; Pia, S.; Tsui, D. “Interagency perchlorate steering committee analytical subcommittee report.” Environmental Protection Agency Collabor ative Study, 1999.
Skoog, D. A.; Leary, J. J. Principles of Instrumental Analysis, 4th ed. Harcourt Brace: Fort Worth, TX, 1992; 639–640, 654-656.
Clewell, R.; Tsui, D.T.; Mattie, D.R. “Feasibility study for the reduction of perchlorate, iodide, and other aqueous anions.” In press.
TSQ 7000 ES1/APCI Techniques—Course Manual, Revision A. Finnigan-Mat Institute: San Rafael, CA, March 1994.
Watson, T. J. Introduction to Mass Spectrometry, 3rd ed. Lippincott-Raven: Philadelphia, PA, 1997; 303–313, 337-338, 432-450, and references therein.
Desidero, D.M.Mass Spectrometry: Clinical and Biomedical Applications. Plenum: New York, NY, 1992; Vol. 1., pp. 1–33, and references therein.
Marchand, R.E.; Hughes, R.J. Quadrupole Storage Mass Spectrometry. Wiley: New York, NY, 1989, passim.
McLafferty, F.W. Interpretation of Mass Spectra, 3rd ed. University Science Books: Mill Valley, CA, 1980, passim.
Code of Federal Regulations 40, Ch. 1, Pt. 136, Appendix B. Definition and Procedure For the Determination of the Method Detection Limit, Rev. 1.1.
Tsui, D.T.; Clewell, R.; Eldridge, J.E.; Mattie, D.R. “Perchlorate Analysis with the AS16 Separation Column.” THIS VOLUME: Perchlorate in the Environment, E.T. Urbansky, Ed. Kluwer/Plenum: New York, NY, 2000; Ch. 7.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media New York
About this chapter
Cite this chapter
Clewell, R.A. et al. (2000). Analysis of Trace Level Perchlorate in Drinking Water and Ground Water by Electrospray Mass Spectrometry. In: Urbansky, E.T. (eds) Perchlorate in the Environment. Environmental Science Research, vol 57. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4303-9_6
Download citation
DOI: https://doi.org/10.1007/978-1-4615-4303-9_6
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-6931-8
Online ISBN: 978-1-4615-4303-9
eBook Packages: Springer Book Archive