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Free-Radical Chain-Growth Polymerization

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Principles of Polymer Chemistry

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Abstract

Polymerizations by free-radical mechanism are typical free-radical reactions. That is to say, there is an initiation, when the radicals are formed, a propagation, when the products are developed, and a termination, when the radical reactions end. In the polymerizations, the propagations are chain reactions. A series of very rapid repetitive steps follow each single act of initiation, leading to the addition of thousands of monomers.

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Ravve, A. (2000). Free-Radical Chain-Growth Polymerization. In: Principles of Polymer Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4227-8_2

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