Abstract
A unified algebraic model for rotation-vibration and electronic excitations in diatomic molecules is presented. Dynamical symmetries are constructed in the united atoms limit, which provide analytic bases for realistic calculations. The model is applied to a series of hydride molecules, determining many of the parameters from atomic calculations. A method to extract Born-Oppenheimer potentials for these molecules is introduced.
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© 1991 Springer Science+Business Media New York
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Frank, A., Lemus, R., Iachello, F. (1991). Algebraic Model for Molecular Electronic Spectra. In: Gruber, B., Biedenharn, L.C., Doebner, H.D. (eds) Symmetries in Science V. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3696-3_9
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DOI: https://doi.org/10.1007/978-1-4615-3696-3_9
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