Abstract
The most important achievement of molecular beam epitaxy (MBE) is the ability to prepare so-called modulated semiconducting structures (MSS), a special case of which are superlattices (SL) which consist of layers with a thickness of one or several monolayers of various materials. The first SL were prepared in the GaxAl1-xAs—GaAs system with a small misfit of the lattice constants f. A substantially broader dass of MSS and SL can be created by conjugation of crystals with a large f. In this case, defect-free strained SL are formed in which the adjoining layers are found in a pseudomorphic state. The basic principles and technical equipment of MBE are reviewed in [1–4]. In the present article, the physicochemical aspects of MBE as applied to growth of semiconducting, metal, and dielectric films are examined. Also, the effects of reflection intensity oscillation during reflection high-energy electron diffraction (RHEED), the methods of automatic ellipsometry (AE) and modulated beams which allow precision control of adsorption—desorption processes, superstructure rearrangements, kinetics of surface reactions, and mechanisms of MSS growth are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Y., Cho and J. R., Arthur, “Molecular beam epitaxy,” Prog. Solid State Chem., 10, Pt. 3, 157–191 (1975).
J. C., Bean, “Growth of doped silicon layers by molecular beam epitaxy,” in: Impurity Doping, North-Holland, Amsterdam (1981), pp. 177–215.
A. G., Denisov, N. A., Kuznetsov, and V. A., Makarenko, “Equipment for molecular beam epitaxy,” Obz. Élektron. Tekh., Ser 7, No.17 (828), 1–52 (1981).
V. V., Anashin, G. G., Emelin, B. Z., Kanter, V. P., Migal’, et al., Analytical Apparatus and Technological Equipment for Molecular Beam Epitaxy [in Russian], Preprint No. 1, Inst. Fiz. Khim., Novosibirsk (1985).
O. P., Pchelyakov, “High-energy electron diffraction applied to study of structure formation processes during molecular beam epitaxy,” in: Physics and Technical Basics of Molecular Beam Epilaxy, Eberswalde (DDR) (1979), p. 114–140.
J. J., Harris, B. A., Joyce, and P. J., Bodson, “Oscillations in the surface structure of Sn-doped GaAs during growth by MBE,” Surf. Sci., 103, L90–L96 (1981).
J. H., Neave, B. A., Joyce, F. J., Dobson, and N. Norton, “Dynamics of film growth of GaAs by MBE from RHEED observation,” Appl. Phys. A, 31, No.1, 1–8 (1983).
J. M., Van Hove, C. S., Lent, P. R., Pukite, and P. T., Cohen, “Damped oscillations in reflection high energy electron diffraction during GaAs MBE,” J. Vac. Sci. Technol B, 1, No.3, 741–746 (1983).
J. M., Van Hove, P. R., Pukite, and P. I., Cohen, “RHEED oscillations as functions of MBE growth parameters,” MBE Conf., San Francisco (1984), pp. 18–40.
L. Esaki, “Computer-controlled molecular beam epitaxy,” Jpn. J. Appl Phys., 13, No.1, 821–828 (1974).
P. E,. Lusher, “Crystal growth by molecular beam epitaxy,” Solid State Technol., No.12, 43–52 (1977).
J. C., Bean and S. A., Sadowski, “Silicon MBE apparatus for uniform high-rate deposition on standard format wafers,” J. Vac. Sci. Technol., 20, No.2, 137–142 (1982).
J. C., Bean, “Silicon molecular beam epitaxy as a VLST processing technique,” Int. Electron Devices Meeting (1981), pp. 6–13.
P. M., Petroff, A. C., Gossard, W., Wiegmann, and A., Savage, “Crystal growth kinetics in (GaAs)m-(AlAs)m superlattices deposited by molecular beam epitaxy,” J. Cryst Growth, 44, 5–13 (1978).
W. J., Schaffer, M. D., Ling, S. P., Kowalczyk, and R. W., Grant, “Nucleation and strain relaxation at the InAs/GaAs(100) heterojunction,” J. Vac. Sci. Technol B, 1, No.3, 688–695 (1983w).
A. V., Arkhipenko, Yu. A., Biyumkina, M. A., Lamin, et al., “Apparatus for molecular beam epitaxy with automatic ellipsometry,” Poverkhnost, No.1, 93–96 (1985).
O. P., Pchelyakov, Yu. A., Blyumkina, S. I., Stenin, et al., “Study of structural rearrangements of an atomically clean silicon surface by automatic ellipsometry and reflection electron diffraction,” Poverkhnost, No.1, 147–149 (1982).
L. V., Sokolov, M. A., Lamin, V. A., Markov, et al., “Oscillations of optical properties of Ge film growth surface during molecular beam epitaxy,” Pisma Zh. Éksp. Teor. Fiz., 44, No.6, 278–280 (1986).
A. V., Rzhanov, S. I., Stenin, and B. Z., Ol’shanetskii, “Methods of monitoring surface state and problems of molecular beam epitaxy,” MikroélekJronika, 9, No.4, 292–301 (1980).
A. V., Rzhanov and S. I., Stenin, “Molecular epitaxy: state of the question, problem, and prospects of development,” in: Growth of Semiconducting Crystals anti Films [in Russian], Nauka, Novosibirsk (1984), Part 1, pp. 5–34.
S. I., Stenin, “Molecular beam epitaxy of semiconductor, dielectric, and metal films,” Vacuum, 36, No.7/8, 419–426 (1986).
A. Y., Cho, “Growth of III-V semiconductor by molecular beam epitaxy and their properties,” Thin Solid Films, 100, No.4, 291–317 (1983).
M., Tabe, K., Arai, and H. Nakamura, “Effect of growth temperature of Si MBE films,” Jpn. J. Appl Phys., 20, No.4, 703–708 (1981).
N., Tabe, “Etching of SiO2 films by Si in ultrahigh vacuum,” Jpn. J. Appl. Phys., 21, No.3, 534–538 (1982).
A. Munoz-Yaque, J. Piqueras, and N. Fabre, “Preparation of carbon-free GaAs surfaces: AES and RHEED analysis,” J. Electrochem. Soc., 128, No.1, 149–153 (1981).
S. Wright and H. Kroemer, “Reduction of oxides on silicon by heating in a gallium molecular beam at 800°C,” Appl. Phys. Lett., 36, No.3, 210–211 (1980).
A. V., Rzhanov, S. I., Stenin, O. P. Pchelyakov, and B. Z., Kanter, “Molecular beam epitaxial growth of germanium and silicon films: surface structure, film defects, and properties,” Thin Solid Films, 139, No.1, 169–175 (1986).
Y. Ota, “Silicon molecular beam epitaxy,” Thin Solid Films, 106, No.1/2, 3–136 (1983).
B. J., Mrstik, “LEED and AES studies of the initial growth of GE epilayers on GaAs (100),” Surf. Sci., 124, 253–266 (1983).
C.-A Chang, “Interface morphology of epitaxial growth of Ge on GaAs and GaAs on Ge by molecular beam epitaxy,” J. Appl. Phys., 53, No.2, 1253–1255 (1982).
L. V., Sokolov, M. A., Lamin, O. P., Pchelyakov, et al., “Surface rearrangements during epitaxy of germanium on silicon,” Poverkhnost, No.9, 75–80 (1985).
A. I., Toropov, L. V., Sokolov, O. P., Pchelyakov, and S. I., Stenin, “Epitaxy of germanium from a molecular beam on a vicinal surface of silicon near (111),” Kristallografiya, 27, No.4, 751–756 (1982).
A. J., Noreika, M. H., Francombe, and C. E. C., Wood, “Growth of Sb and InSb by molecular beam epitaxy,” J. Appl. Phys., 52, No.12, 7416–7420 (1981).
R. Z., Bachrach, “MBE-molecular beam epitaxial evaporative growth,” in: Crystal Growth, Pergamon, New York (1980), pp. 1–52.
C. T., Foxon, M. R., Boudry, and B. A., Joyce, “Evaluation of surface kinetic data by the transform analysis of modulated molecular beam measurement,” Surf. Sci., 44, No.1, 69–92 (1974).
B. A., Joyce, “Present status and future directions for MBE,” Surf. Sci., 86, No.1, 92–101 (1979).
B. A., Joyce, C. T., Foxon, and J. H., Neave, “Fundamentals of molecular beam epitaxy,” J. Jpn. Assoc. Crysl Growth, 5, 185–197 (1978).
C. T., Foxon, “MBE growth of GaAs and III-V alloys,” J. Vac. Sci. Technol B, 1, No.2, 293–297 (1983).
J. H., Neave, P. K., Larsen, J. F., van der Veen, et al., “Effect of arsenic species (Asz or As4) on the crystallographic and electronic structure of MBE-grown GaAs (001) reconstructed surfaces,” Surf. Sci., 133,267–278 (1983).
H. Kunzel, J. Knecht, H. Jung, et al., “The effect of arsenic vapor species on electrical and optical properties of GaAs grown by molecular beam epitaxy,” Appl Phys. A, 28, 167–173 (1982).
T. Sakamoto, H. Funabashi, K. Ohta, et al., “Well-defined superlattice structures made by phase-locked epitaxy using RHEED intensity,” in: Proc. Int. Conf. Superlattice, Illinois (1984), pp. 1021–1029.
T. Sakamoto, H. Funabashi, K. Ohta, et al., “Phase-locked epitaxy using RHEED intensity oscillation,” Jpn. J. Appl Phys., 23, No.9, L657–L659 (1984).
T. Kajima, N. J., Kawai, T. Nakagawa, et al., “Layer-by-layer sublimation observed by reflection high-energy electron diffraction intensity oscillation in a molecular beam epitaxy system,” Appl Phys. Lett., 47, No.3, 286–288 (1985).
A. I., Toropov, B. Z., Kanter, V. Yu., Karasev, et al., “Molecular epitaxy of germanium on silicon: surface morphology, structure, diffusion,” Poverkhnost, No.1, 110–115 (1982).
J. W., Matthews, D. S., Jackson, and A., Chambers, “Effect of coherency strain at misfit dislocations on the mode of growth of thin films,” Thin Solid Films, 26, No.1, 129–134 (1975).
S. M., Pintus, S. I., Stenin, A. I., Toropov, and E. M., Trukhanov, “Morphological stability and mechanism of growth of heteroepitaxial films,” Inst. F. P., Sib. Otd. Akad. Nauk SSSR, Novosibirsk (1986).
E. Kasper and W. Pabst, “Profiling of SiGe superlattices by He backscattering,” Thin Solid Films, 37, No.1, L5–L7 (1976).
S. I.. Stenin, “Problems of the formation of dislocation structure on heteroepitaxial layers,” Phys. Status Solidi A, 55, 519–527 (1979).
S. I.. Stenin, “Processes of defect formation in epitaxial semiconductor films,” Thin Solid Films, 116, No.1, 99–110 (1984).
S. I., Stenin and A. K., Gutakovskii, “Electron-microscopic studies of the mechanisms of formation of faults in heteroepitaxial systems,” in: Contemporary Electron Microscopy tor Study of Substances [in Russian], Nauka, Moscow (1982), pp. 139–147.
A. Y., Cho and P. D., Demier, “Single-crystal-aluminum Schottky-barrier diodes prepared by molecular beam epitaxy (MBE),” J Appl Phys., 49, No.6, 3328–3333 (1978).
J. C., Bean and J. M., Poate, “Silicon/metal silicide heterostructures grown by molecular beam epitaxy,” Appl Phys. Lett., 37, No.7, 643–646 (1980).
J. M., Gibson, J. C., Bean, J. M., Poate, and R. T., Tung, “Direct determination of atomic structure at the epitaxial cobalt disilicide on (111) Si interface by ultrahigh resolution electron microscopy,” Appl Phys. Lett., 49, No.9, 818–820 (1982).
R. T., Tung, J. M., Gibson, and J. M., Poate, “Formation of ultrathin single-crystal silicide films on Si: surface and interfacial stabilization of Si-NiSi2 epitaxial structures,” Phys. Rev. Lett., 50, No.6, 429–432 (1983).
F. Comin, J. E., Rowe, and P. H., Citrin, “Structure and nucleation mechanism of nickel silicide on Si (111) derived from surface extended-X-ray-absorption fine structure,” Phys. Rev. Lett., 51, No.26, 2402–2405 (1983).
R. T., Tung, “Schottky barrier heights of single crystal silicides on Si(111),” J Vac. Sci. Technol B, 2, No.3, 465–470 (1984).
A. Y., Cho, “Recent developments in molecular beam epitaxy (MBE),” J Vac. Sci. Technol., 16, No.2, 275–284 (1979).
S. Yoshida, “Reactive molecular beam epitaxy,” in: CRC Crit. Rev. Solid State Mater. Sci., 11, No.4, 287–316 (1983).
C. W., Tu, T. T., Sheng, M. H., Read, et al., “Growth of single-crystalline epitaxial group II fluoride films on InP(001) by molecular beam epitaxy,” J Electrochem Soc., 130, No.10, 2081–2087 (1983).
C. W., Tu, S. R., Forrest, and W. D., Johnson, Jr., “Epitaxial InP/fluoride/InP(100) double heterostructure grown by molecular beam epitaxy,” Appl Phys. Lett., 43, No.6, 569–571 (1983).
J. M., Phillips, L. C., Feldman, J. M., Gibson, and M. L., McDonald, “Epitaxial growth of alkaline earth fluorides on semiconductors,” Thin Solid Films, 107, 217–226 (1983).
J. M., Phillips and J. M., Gibson, “The growth and characterization of epitaxial fluoride films on semiconductors,” Mater. Res. Soc. Symp., 25, 381–391 (1984).
S. L., Wright, M., Inada, and H., Kroemer, “Polar-on-nonpolar epitaxy: sublattice ordering in the nucleation and growth of GaP on Si(211),” Sci. Technol., 21, 534 (1982).
S. L., Wright, H., Kroemer, and M., Inada, “Molecular beam epitaxial growth of GaP on Si,” J Appl Phys., 55, No.8, 2916–2927 (1984).
P. W., Sullivan, J. E., Bower, and G. M., Metre, “Growth of semiconductor/insulator structures-GaAs/fluoride/GaAs(001),” J Vac. Sci Technol., 3, No.2, 500–507 (1984).
T. Asano, H. Tsiwara, H. Lee, et al., “Formation of GaAs on insulation structures on Si substrates by heteroepitaxial growth of CaF2 and GaAs,” Jpn. J Appl. Phys., 25, No.2, L139–L141 (1986).
S. Siskos, C. Fontaine, and A. Munoz-Vaque, “GaAs/(Ca, Sr)F2/(001)GaAs lattice-matched structures grown by molecular beam epitaxy,” Appl. Phys. Lett., 44, No.12, 1146–1148 (1984).
H. Ogata, S. Maruno, Y. Morishita, and T. Isu, “MBE of InP using low energy p+ ion beam,” in: IVth Int. Conf. MBE, 7-10 Sept., Univ. of York (England), York (1986), G-10.
W. T. Tsang, “Chemical beam epitaxy of InP GaAs,” Appl Phys. Lett., 45, No.2, 1234–1236 (1984).
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Consultants Bureau, New York
About this chapter
Cite this chapter
Stenin, S.I., Toropov, A.I. (1991). Molecular Beam Epitaxy of Semiconductor, Metal, and Dielectric Films. In: Bagdasarov, K.S., Lube, É.L. (eds) Growth of Crystals. Growth of Crystals, vol 16. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3662-8_8
Download citation
DOI: https://doi.org/10.1007/978-1-4615-3662-8_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-0-306-18116-0
Online ISBN: 978-1-4615-3662-8
eBook Packages: Springer Book Archive