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Effect of Soluble and Insoluble Additives on the Crystallization of Metals from the Melt

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Growth of Crystals

Part of the book series: Growth of Crystals ((GROC,volume 16))

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Abstract

Impurities are known to play an important role in hardening processes and are widely used in metallurgy for improving the quality of castings. However, the nature and mechanism of their effect have been insufficiently studied. This impedes development of a theory of modification. Therefore, the choice of modifying additives is made empirically in the majority of cases. Elucidation of the effect of soluble and insoluble additives on the kinetics of formation and growth of crystals and on their morphology is crucial from the viewpoint of primary structure modification since formation of a casting is determined namely by these factors. Investigation of these questions has a rather lengthy history. A definite contribution to progress on this problem has been made by the studies carried out at the Metal Physics Institute of the Academy of Sciences of the Ukrainian SSR. Fundamental concepts about the role and mechanism of the effect of impurities on crystallization processes and formation of cast structures have been based on these studies. The present work is also concerned with these.

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References

  1. M. Volmer, Kinetik der Phasenbildung, Leipzig (1939).

    Google Scholar 

  2. Ya. I. Frenkel’, Kinetic Theory of Liquids [in Russian], Nauka, Leningrad (1975), Vol. 3.

    Google Scholar 

  3. J., Holloman and D. Turnbull, “Formation of nuclei during phase transitions,” in:Advances in Metal Physics [Russian translation], Metallurgizdat, Moscow (1959), Vol. 1, pp. 304–367.

    Google Scholar 

  4. D. E., Ovsienko, “On crystallization center nucleation in undercooled liquid metals,” in: Current Problems in Crystallography [in Russian], Nauka, Moscow (1975), pp. 127–149.

    Google Scholar 

  5. D. E., Ovsienko, “On homogeneous crystallization center nucleation in liquid metals,” Growth of Crystals [in Russian], Izd. Erevan Univ., Erevan (1975), Vol. 2, pp. 11–25.

    Google Scholar 

  6. V. I., Danilov, Structure and Crystallization of Liquids [in Russian], Naukova Dumka, Kiev (1956).

    Google Scholar 

  7. Yu. Z., Babaskin, D. E., Ovsienko, L. A., Rostovskaya, and G. A., Alfintsev, “Modification of steel by high-melting particles and its effect on the structure and properties of castings,” Liteinoe Proizdvod., No.2, 17–19 (1975).

    Google Scholar 

  8. S. S., Zatulovskii, Suspension Casting [in Russian], Naukova Dumka, Kiev (1981).

    Google Scholar 

  9. D. E., Ovsienko, G. A., Alfintsev, B. A., Kirievskii, G. I., Gershtein, and G. P., Chemerinskii, “Dendrite splitting upon incorporation of solid particles,” Metallofizika, 5, No.6, 110–111 (1983).

    CAS  Google Scholar 

  10. D. E., Ovsienko, O. P., Fedorov, B. A., Kirievskii, G. I., Gershtein, and G. P., Chemerinskii, “Effect of solid and liquid inclusions in a melt on crystallization front morphology,” Metallofizika, 8, No.4, 64–71 (1986).

    CAS  Google Scholar 

  11. D. E., Ovsienko, O. P., Fedorov, B. A., Kiriyevsky, G. I. Gershtein, and G. P., Chemerinsky, “The effect of solid and liquid inclusions on morphology of crystallization front,” Cryst. Res. Technol, 21, No.6, 721–727 (1986).

    Article  CAS  Google Scholar 

  12. D. E., Ovsienko, D. E., Temkin, O. P., Fedorov, and G. P., Chemerinskii, “Interaction of solid particles with crystals growing from a melt,” Kristallografiya, 32, No.5, 1246–1252 (1987).

    CAS  Google Scholar 

  13. D. E., Temkin, A. A., Chernov, and A. M., Mel’nikova, “Theory of solid inclusion incorporation during crystal growth from a melt,” Kristallografiya, 21, No.4, 652–660 (1976).

    Google Scholar 

  14. D. E., Temkin, A. A., Chernov, and A. M., Mel’nikova, “Incorporation of foreign particles by a crystal growing from a melt with impurities,” Kristallografiya, 22, No.1, 27–35 (1977).

    Google Scholar 

  15. M. B., Movchan, “Solid-phase modification of the primary structure of cast alloys by dispersed nonmetallic particles,” Author’s Abstract of Candidate’s Dissertation, Technical Sciences, Kiev (1983).

    Google Scholar 

  16. D., Turnbull and R. E., Cech, “Microscopic observation of the solidification of small metal droplets,” J Appl Phys, 21, No.8, 804–810 (1950).

    Article  Google Scholar 

  17. G. L. F., Powell and L. M., Hagen, “Undercooling of copper and copper-oxygen alloys,” Trans. Metall Soc. AIME, 242, No.10, 2133–2138 (1968).

    CAS  Google Scholar 

  18. G. L. F., Powell and L. M., Hagen, “The influence of oxygen content on the grain size of undercooled silver,” Trans. Metall Soc. AIME, 245, No.2, 407–412 (1969).

    CAS  Google Scholar 

  19. J. Fehling and E. Scheil, “Untersuchung der Unterkuhlbarkeit von Metallschmelzen,” Z. Metallk., 53, No.9, 593–600 (1962).

    CAS  Google Scholar 

  20. D. W., Gomersal and S. X., Shirashi, “Undercooling phenomena in liquid metal droplets,” J Aust. Inst Met, 10, No.5, 220–222 (1965).

    Google Scholar 

  21. A. I., Dukhin, “Crystallization of metals and alloys in small volumes,” in: Problems in Metal Science and Metal Physics [in Russian], Metallurgizdat, Moscow (1959), Vol. 6, pp. 9–33.

    Google Scholar 

  22. V. P., Skripov and V. P., Koverda, Spontaneous Crystallization of Undercooled Liquids [in Russian], Nauka, Moscow (1984).

    Google Scholar 

  23. J. H., Perepezko, “Nucleation in undercooled liquids,” Mater. Sci. Eng., 65, 125–135 (1984).

    Article  CAS  Google Scholar 

  24. C., Merton, M., Flemings, and Y., Schiohara, “Solidification of undercooled metals,” Mater. Sci. Eng., 65, 157–170 (1984).

    Article  Google Scholar 

  25. D. E., Ovsienko, M. V., Laputskii, O., Nechiporenko, and A. Medvedovskii, “Effect of aluminum on undercooling and spheroidization of metal drops,” in: Metal Physics [in Russian], Naukova Dumka, Kiev (1971), No.3, pp. 62–64.

    Google Scholar 

  26. D. E., Ovsienko, V. P., Kostyuchenko,. V., Maslov, and G. A., Alfintsev, “Effect of undercooling on the structure of a nickel ingot,” in: Kinetics and Mechanism of Crystallization [in Russian], Nauka i Tekhnika, Minsk (1973), pp. 75–81.

    Google Scholar 

  27. D. E., Ovsienko, G. A., Alfintsev, and V. V., Maslov, “Kinetics and shape of crystal growth from melt for substances with low L/kT values,” J Cryst Growth, 26, 233–238 (1974).

    Article  CAS  Google Scholar 

  28. D. E., Ovsienko and G. A., Alfintsev, “Crystal growth from the melt. Experimental investigation of kinetics and morphology,” in: Crystal Growth. Properties and Applications, Springer, Berlin-Heidelberg (1980), pp. 119–170.

    Google Scholar 

  29. V. K., Semenchenko, Surface Effects in Metals and Alloys [in Russian], Gostekhizdat, Moscow (1957).

    Google Scholar 

  30. N. L., Pokrovksif and T. G., Smirnova, “Growth of tin grains in the presence of surface-active and-inactive impurities,” in: Growth and Imperfection of Metallic Crystals [in Russian], Naukova Dumka, Kiev (1966), pp. 82–88.

    Google Scholar 

  31. D. E., Ovsienko, V. V., Maslov, and G. A., Alfintsev, “Mechanism of effect of soluble impurities on tin crystallization,” Kristallograjiya, 22, No.5, 1042–1050 (1977).

    CAS  Google Scholar 

  32. D. E., Ovsienko, V. V., Maslov, and G. A., Alfintsev, “Effect of some soluble additives on undercooling and structure of an iron ingot,” in: Problems of Steel Casting: Works of the VIth Conf. on Casting [in Russian], Metallurgiya, Moscow (1976), pp. 60–62.

    Google Scholar 

  33. D. E., Ovsienko, V. V., Maslov, and G. A., Alfintsev, “Effect of silicon additives on undercooling and structure of a nickel ingot,” Izv. Akad. Nauk SSSR, Metally, No.4, 92 (1974).

    Google Scholar 

  34. T. Takahashi and W. A., Tiller, “Nucleation experiments of some alloys with low eutectic temperatures,” Acta Metall, 17, No.5, 651–656 (1969).

    Article  CAS  Google Scholar 

  35. G. I. Distler, A. N., Lobanov, V. P., Vlasov, O. K., Mel’nikov, and N. S., Grindina, “Novel method of single crystal growth,” Dokl Akad. Nauk SSSR, 215, No.1, 91–94 (1974).

    CAS  Google Scholar 

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Ovsienko, D.E. (1991). Effect of Soluble and Insoluble Additives on the Crystallization of Metals from the Melt. In: Bagdasarov, K.S., Lube, É.L. (eds) Growth of Crystals. Growth of Crystals, vol 16. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3662-8_3

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  • DOI: https://doi.org/10.1007/978-1-4615-3662-8_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-18116-0

  • Online ISBN: 978-1-4615-3662-8

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