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Explosive Crystallization of Amorphous Substances with Fixed Crystallites

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Growth of Crystals

Part of the book series: Growth of Crystals ((GROC,volume 17))

Abstract

The solid amorphous state arising during the highly nonequilibrium processes in a rapidly cooling liquid melt or vapor is metastable. It can relax to a stable crystalline state. In the overwhelming majority of cases, this relaxation is accompanied by release of heat and a change of specific volume, i.e., it is a first-order phase transition. However, it occurs far from conditions of phase equilibrium and includes mechanisms of crystal generation and growth. The kinetics of such a transformation have features in common with other cases of metastable phase decomposition and can be analyzed on the basis of the approach formulated by Volmer [1].

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Literature Cited

  1. M. Volmer, Kinetics of New Phase Formation [Russian translation], Nauka, Moscow (1986).

    Google Scholar 

  2. L. N. Aleksandrov, Kinetics of Crystallization and Recrystallization of Semiconducting Films [in Russian], Nauka, Novosibirsk (1985).

    Google Scholar 

  3. V. P. Zakharov and V. S. Gerasimenko, Structural Features of Semiconductors in the Amorphous State [in Russian], Naukova Dumka, Kiev (1976).

    Google Scholar 

  4. L. S. Palatnik, M. Ya. Fuks, and V. M. Kosevich, Mechanism of Formation and Substructure of Condensed Films [in Russian], Nauka, Moscow (1972).

    Google Scholar 

  5. H. J. Leamy, W. L. Brown, G. K. Celler, et aL, “Explosive crystallization of amorphous germanium,” AppL Phys. Lett, 38, 137–139 (1981).

    Article  CAS  Google Scholar 

  6. D. Turnbull, “On the melting of amorphous Ge and Si,” in: Metastable Materials Formation by Ion Implantation, Elsevier New York (1982), pp. 103–108.

    Google Scholar 

  7. L. Guttman, “On the melting point of amorphous silicon,” Solid-State Commun., 45, 551–552 (1983).

    Article  CAS  Google Scholar 

  8. L. N. Aleksandrov and F. L. fidelman, “On certain features of crystallization of dielectric films on silicon,” Izv. Akad Nauk SSSR, Ser. Fiz., 41, No. 11, 2310–2314 (1977).

    CAS  Google Scholar 

  9. V. M. Kuz’menko and V. I. Mel’nikov, “’Avalanche’ crystallization of amorphous metals,” Zh. Éksp. Teor. Fiz., 82, No. 3, 802–808 (1982).

    CAS  Google Scholar 

  10. V. M. Kuz’menko, V. I. Mel’nikov, and V. A. Rakhubovskii, “On mechanisms of spontaneous crystallization of amorphous metallic films,” Zh. Éksp. Teor. Fiz, 86, No. 3, 1049–1058 (1984).

    CAS  Google Scholar 

  11. V. P. Koverda, V. P. Skripov, and N. M. Bogdanov, “Kinetics of formation of crystalline nuclei in amorphous films of water and organic liquids,” DokL Akad Nauk SSSR, 212, No. 6, 1375–1378 (1973).

    CAS  Google Scholar 

  12. V. P. Skripov and V. P. Koverda, Spontaneous Crystallization of Supercooled Liquids [in Russian], Nauka, Moscow (1984).

    Google Scholar 

  13. V. P. Skripov and V. P. Koverda, “Homogeneous nucleation of crystals in liquids and amorphous solids,” in: Problems in Crystallography: The 100th Anniversary of the Birth of Academician A. V. Shubnikov [in Russian], Nauka, Moscow (1987), pp. 232–246.

    Google Scholar 

  14. L. N. Aleksandrov, “Kinetic parameters of the explosive (impulse) crystallization of films,” Pis’ma Zh. Tekh. Fiz, 8, No. 6, 368–371 (1982).

    CAS  Google Scholar 

  15. V. A. Shklovskii, “Thermal instability of a phase transformation front during decomposition of frozen metastable states,” DokL Akad Nauk SSSR, 261, No. 6, 1343–1346 (1981).

    Google Scholar 

  16. V. P. Koverda, V. P. Skripov, and N. M. Bogdanov, “Kinetics of crystallization of amorphous films of water and organic liquids,” Kristallografiya, 19, No. 3, 613–618 (1974).

    CAS  Google Scholar 

  17. N. M. Bogdanov, V. P. Koverda, and V. P. Skripov, “Kinetics of crystallization of glassy layers of heavy water, thiophene, and pseudocumene,” Fiz Khim. Stekla, 6, No. 4, 395–400 (1980).

    CAS  Google Scholar 

  18. V. P. Koverda and V. P. Skripov, “’Hot’ centers of crystallization in amorphous films,” Kristallografiya, 28, No. 1, 185–187 (1983).

    CAS  Google Scholar 

  19. V. P. Koverda and V. P. Skripov, “Growth of crystallization centers in amorphous layers,” Zh. Fiz Khim., 58, No. 10, 2538–2540 (1984).

    CAS  Google Scholar 

  20. V. P. Koverda, N. M. Bogdanov, and V. P. Skripov, “Self-sustaining crystallization of amorphous layers of water and heavy water,” J. Non–Cryst Solids, 57, 203–212 (1983).

    Article  CAS  Google Scholar 

  21. V. P. Koverda, N. M. Bogdanov, and V. P. Skripov, “Explosive crystallization of amorphous solids under intensive nucleation,”J. Non-Cryst Solids, 74, 181–188 (1985).

    Article  CAS  Google Scholar 

  22. Yu. Estrin and B. Petukhov, “Effect of heat release on the motion of phase boundaries,” in: Recent Dev. Condens. Matter Phys., First Gen. Conf. Condens. Matter Div. Europ. Phys. Soc, Vol. 4, London, New-York (1981), pp. 77–80.

    Google Scholar 

  23. V. A. Shklovskii and E. I. Druinskii, “Explosive regimes of nonisothermal growth of a phase transition spherical center on decay of frozen metastable states,” Zh. Éksp. Teor. Fiz., 90, No. 1, 240–247 (1986).

    CAS  Google Scholar 

  24. W. Saarloos and D. Weeks, “Surface undulations in explosive crystallization: a thermal instability,” Phys. Rev. Lett, 51, 1046–1049 (1983).

    Article  Google Scholar 

  25. D. Stock, H.-D. Geiler, and K. Hehl, “A model of crystallization processes controlled by temperature pulses in amorphous semiconductors,” Phys. Status Solidi A, 89, 57–63 (1985).

    Article  CAS  Google Scholar 

  26. A. V. Shubnikov, How Crystals Grow [in Russian], Izd. Akad. Nauk SSSR, Moscow-Leningrad (1935).

    Google Scholar 

  27. A. A. Chernov, E. I. Givargizov, Kh. S. Bagdasarov, et aL, Modern Crystallography, VoL 3, Formation of Crystals [in Russian], Nauka, Moscow (1980).

    Google Scholar 

  28. B. Ya. Lyubov, Theory of Crystallization in Large Volumes [in Russian], Nauka, Moscow (1975).

    Google Scholar 

  29. H. Suga and S. Seki, “Thermodynamic investigation on glassy states of pure simple compounds,” J. Non-Cryst Solids, 16, 171–194 (1974).

    Article  CAS  Google Scholar 

  30. V. S. Chirkin, Thermophysical Properties of Nuclear Technology Materials [in Russian], Atomizdat, Moscow (1968)

    Google Scholar 

  31. Yu. A. Osipov, B. V. Zheleznyi, and N. F. Bondarenko, “Shear viscosity of water supercooled to-35°C,” Zh. Fiz Khim., 51, No. 5, 1264–1265 (1977).

    CAS  Google Scholar 

  32. A. N. Kolmogorov, “Toward a statistical theory of metal crystallization,” Izv. Akad Nauk SSSR, Ser. Mat, No. 3, 355–359 (1937).

    Google Scholar 

  33. V. N. Skokov, A. A. Dik, V. P. Koverda, and V. P. Skripov, “Crystal nucleation in supercooled germanium,” Kristallografiya, 30, No. 2, 409–410 (1985).

    CAS  Google Scholar 

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Koverda, V.P., Boganov, N.M., Skripov, V.P. (1991). Explosive Crystallization of Amorphous Substances with Fixed Crystallites. In: Givargizov, E.I., Grinberg, S.A. (eds) Growth of Crystals. Growth of Crystals, vol 17. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3660-4_7

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  • DOI: https://doi.org/10.1007/978-1-4615-3660-4_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6629-4

  • Online ISBN: 978-1-4615-3660-4

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