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Functionalized Polyolefins via Copolymerization of Borane Monomers in Ziegler-Natta Process

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Advances in New Materials

Part of the book series: Contemporary Topics in Polymer Science ((CTPS,volume 7))

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Abstract

Polyolefins, especially polyethylene and polypropylene, are used in a wide range of applications, since they incorporate an excellent combination of mechanical, chemical and electronic properties and processibility. Nevertheless, deficiencies, such as the lack of reactive groups in the polymer structure, have limited some of their end uses, particularly those in which adhesion, dyeability, paintability, printability or compatibility with other functional polymers is paramount. Accordingly, the chemical modification of polyolefins has been an area of increasing interest as a route to higher value products and various methods of functionalization (1–3) have been employed to alter their chemical and physical properties.

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References

  1. C. Pinazzi, P. Guillaume and D. J. Reyx, Eur. Polym., 13, 711 (1977).

    Google Scholar 

  2. T. C. Chung, M. Raate, E. Berluche and D. N. Schulz, Macromolecules, 21, 1903 (1988).

    Article  CAS  Google Scholar 

  3. T. C. Chung, J. Polym. Sci., Polym. Chem. Ed., 27. 3251 (1989).

    Article  CAS  Google Scholar 

  4. J. Boor, Jr., “Ziegler-Natta Catalysts and Polymerizations”, Academic Press, New York, (1979).

    Google Scholar 

  5. M. D.Purgett: Ph.D. Thesis, University of Massachusetts (1984).

    Google Scholar 

  6. K. J. Clark and W. G. City, U. S. Patent 3, 492,277 (1970).

    Google Scholar 

  7. T. C. Chung, Macromolecules, 21, 865 (1988).

    Article  CAS  Google Scholar 

  8. T. C. Chung, U. S. Patent 4,734,472 and 4,751,276 (1988).

    Google Scholar 

  9. H. C. Brown, “Organic Synthesis via Boranes”, Wiley-lnterscience, New York (1975).

    Google Scholar 

  10. R. H. Yocum and E. B. Nyquist, “Functional Monomers”, Marcel Dekker, New York (1973).

    Google Scholar 

  11. J. G. Pritchard, “Polyvinyl Alcohol, Basic Properties and Uses”, Gordon and Breach, New York (1971).

    Google Scholar 

  12. S. Ramakrishnan, E. Berluche and T. C. Chung, Macromolecules, 23, 378 (1990).

    Article  CAS  Google Scholar 

  13. G. Ruggeri, M. Aglietto, A. Petragnani, F. Ciardelli, Eur. Polymer J. 1983, 19, 863.

    Article  CAS  Google Scholar 

  14. Each NMR sample was prepared by dissolving 70 mg of polymer in 0.7 g of d-toluene solvent, containing an internal standard of triethylborate (7 x 10-5 M), at 100 °C, then kept at 70 °C during the measurement.

    Google Scholar 

  15. T. C. Chung, U. S. Patent Application (1991).

    Google Scholar 

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© 1992 Springer Science+Business Media New York

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Chung, T.C. (1992). Functionalized Polyolefins via Copolymerization of Borane Monomers in Ziegler-Natta Process. In: Salamone, J.C., Riffle, J.S. (eds) Advances in New Materials. Contemporary Topics in Polymer Science, vol 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3456-3_29

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  • DOI: https://doi.org/10.1007/978-1-4615-3456-3_29

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6530-3

  • Online ISBN: 978-1-4615-3456-3

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