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Analysis of the Capacitance of the Metal—Solution Interface: Role of the Metal and the Metal—Solvent Coupling

  • Chapter
Modern Aspects of Electrochemistry

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 22))

Abstract

A specific role of the metal in many properties of the metal/solution interface has been known for a very long time. Insofar as the capacitance of the ideally polarized electrode is concerned, a possible contribution of the metal was suspected very early. However, the early attempts to include this idea in the modeling of the interface by using the theoretical methods available at that time were unsuccessful. For about the next 50 years, the so-called “traditional approach” was based on a macroscopic picture of the electrode surface. All the models for the capacitance proposed in this approach were based on two premises. The first is that the metal behaves like an ideal conductor. This means, for example, that a possible contribution to the capacitance related to a change of the surface potential of the metal with the applied potential is negligible. The second is that the electrode surface forms a rigid boundary on the solution side. This means that the distance of closest approach of solvent molecules or ions to the “electrode plane” is mainly determined by steric effects related to their size.

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  1. Laboratoire Structure et Réactivité aux Interfaces, Université P. M. Curie, 75230, Paris Cedex, 05, France

    S. Amokrane & J. P. Badiali

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  1. S. Amokrane
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  2. J. P. Badiali
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Editors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, USA

    J. O’M. Bockris

  2. Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada

    B. E. Conway

  3. Department of Chemical Engineering, Texas A&M University, College Station, Texas, USA

    Ralph E. White

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Amokrane, S., Badiali, J.P. (1992). Analysis of the Capacitance of the Metal—Solution Interface: Role of the Metal and the Metal—Solvent Coupling. In: Bockris, J.O., Conway, B.E., White, R.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 22. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3376-4_1

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