Abstract
Over the past decade, angle-resolved photoemission spectroscopy has matured from an exotic technique into a very powerful tool to determine the electronic structure of solids, surfaces, and interfaces. 1,2 Since not only the energy but also the direction of the photoexcited electrons and thus the components of the electron momentum vector are determined by the experiment, all relevant quantum numbers of the electronic states of a solid or a surface can be determined. Angle-resolved photoemission spectroscopy is indeed the only existing technique that allows a direct and unambiguous determination of a two-or three-dimensional band structure E(k) of a solid or a surface. These band structures have been calculated for many decades and the concepts can be found in any elementary solid-state physics textbook. It is therefore very fascinating to have an experimental technique at hand to verify these calculations. Even more important than this connection with theory is the potential technological impact generated by these measurements. The electron interactions among the individual atoms forming a solid or a surface, as shown by the electronic structure, determine all the properties of the material, as for example its mechanical stability, corrosion resistance, chemical reactivity, electrical and thermal conductivity, or magnetism.
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Eberhardt, W. (1992). Angle-Resolved Photoelectron Spectroscopy. In: Bachrach, R.Z. (eds) Synchrotron Radiation Research. Synchrotron Radiation Research, vol 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3280-4_4
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