Abstract
We present here results that impact our fundamental knowledge regarding metal catalyzed O2 based oxidations and systems that address the mechanism of the Ishii/Venturello H2O2 based catalytic epoxidation chemistry. Our efforts continue to focus on fundamental energetic and mechanistic issues that define and indeed limit further development in the burgeoning area of selective catalytic oxidation. One particular application of a selective O2 based oxidation applied to an issue of practical and growing importance, the selective bleaching of wood pulp for paper manufacture, is a collaborative venture between our laboratories at Emory University and those of Dr. Weinstock and collaborators at the U.S. Department of Agriculture Forest Products Laboratory.
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Hill, C.L., Duncan, D.C., Hecht, E.A., Weinstock, I. (1993). Homogeneous Catalyzed Selective Oxidations Based on O2 or H2O2. New Systems and Fundamental Studies. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_6
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