Abstract
The chemistry of oxidation of Mo(VI) and W(VI) peroxopolyoxo complexes is becoming of increasing interest in the field or oxygen transfer processes. Alkenes, alkynes, alcohols, diols, sulfides, solfoxides undergo easy oxidation by these reagents both under stoichiometric and catalytic conditions.1
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References
Ballistreri, F.P.; Failla, S.; Tomaselli, G.A.J.Org.Chem. 1988, 53, 830
Ballistreri, F.P.; Failla, S.; Spina, E.; Tomaselli, G.A.J. Org. Chem. 1989, 54, 947.
Ballistreri, F.P.; Chiacchio, U.; Rescifina, A.; Tomaselli G.A.; Toscano, R.M. Tetrahedron 1992, 48, 8677.
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Ballistreri, F.P., Chiacchio, U., Rescifina, A., Tomaselli, G.A., Toscano, R.M. (1993). Formation of Isoxazolines and Isoxazoles Via Dipolar Cycloaddition by Catalytic Oxidation of Aldoximes with Hydrogen Peroxide and W(Vi) Peroxo Complexes. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_37
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DOI: https://doi.org/10.1007/978-1-4615-3000-8_37
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