Abstract
Complex intermetallic phases such as Frank Kasper, Laves and Zintl compounds have local structural units of high symmetry, often tetrahedral or icosahedral. Such systems can undergo both translational and orientational disorder, leading to a variety of possible phases, shown schematically in Figure 1. They tend to have a semiconducting electronic structure, characterized by a small gap (or pseudo-gap) at the Fermi surface and leading to relatively high resistivities (103-104 mΩ cm).
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Saboungi, ML., Johnson, G.K., Long Price, D. (1994). Orientational Phase Transitions in Alloys. In: Turchi, P.E.A., Gonis, A. (eds) Statics and Dynamics of Alloy Phase Transformations. NATO ASI Series, vol 319. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2476-2_14
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DOI: https://doi.org/10.1007/978-1-4615-2476-2_14
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