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Enantioselective Hydrogenation of α-Ketoesters: A Molecular View on the Enantio-Differentiation

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Chiral Reactions in Heterogeneous Catalysis

Abstract

Three mechanistic models, which have been proposed for the interpretation of enantioselective hydrogenation of α-ketoesters on platinum metal catalysts modified by cinchona alkaloids, are critically reviewed and compared. The characteristics and the implicit contradictions of the models are discussed in the light of relevant experimental observations.

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Author information

Authors and Affiliations

  1. Department of Chemical Engineering and Industiral Chemistry, Swiss Federal Institute of Technology, ETH Zentrum, CH - 8092, Zürich, Switzerland

    A. Baiker, T. Mallat, B. Minder & K. E. Simons

  2. Department of Physical Chemsitry, University of Geneva, 30 quai Ernest-Ansermet, Geneva 4, CH — 1211, Switzerland

    O. Schwalm & J. Weber

Authors
  1. A. Baiker
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  2. T. Mallat
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  3. B. Minder
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  4. O. Schwalm
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  5. K. E. Simons
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  6. J. Weber
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Editor information

Editors and Affiliations

  1. CERIA/Meurice Institute, Brussels, Belgium

    Georges Jannes  & Vincent Dubois  & 

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Baiker, A., Mallat, T., Minder, B., Schwalm, O., Simons, K.E., Weber, J. (1995). Enantioselective Hydrogenation of α-Ketoesters: A Molecular View on the Enantio-Differentiation. In: Jannes, G., Dubois, V. (eds) Chiral Reactions in Heterogeneous Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-1909-6_10

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  • DOI: https://doi.org/10.1007/978-1-4615-1909-6_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-5780-3

  • Online ISBN: 978-1-4615-1909-6

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