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Photoinitiation of Ionic Polymerizations

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Macromolecular Engineering

Abstract

At present, there is growing interest in industrial applications of photopolymerizations which refers mainly to surface coating processes proceeding via free radical mechanisms [1]. However, acrylate-and methacrylate-based formulations which are largely employed for this purpose exhibit disadvantages due to shrinkage and incomplete monomer conversion. It is hoped to overcome these problems with the aid of formulations containing substances of different chemical nature such as compounds containing epoxide groups. However, the latter can be polymerized only cationically and, therefore, the photoinitiation of cationic polymerizations has recently been the subject of intense investigations at various places in the world [2,3].

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Author information

Authors and Affiliations

  1. Hahn-Meitner-Institut Berlin GmbH, Glienicker Str.100, D-14109, Berlin, Germany

    Wolfram Schnabel

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  1. Wolfram Schnabel
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Editor information

Editors and Affiliations

  1. Texaco Inc., R&D, Beacon, New York, USA

    Munmaya K. Mishra

  2. Technical University of Munich, Garching, Germany

    Oskar Nuyken

  3. Tohoku University, Aoba, Sendai, Japan

    Shiro Kobayashi

  4. Istanbul Technical University, Maslak, Istanbul, Turkey

    Yusuf Yağci

  5. PFI. Inc., Hopewell Junction, New York, USA

    Bidulata Sar

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© 1995 Springer Science+Business Media New York

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Schnabel, W. (1995). Photoinitiation of Ionic Polymerizations. In: Mishra, M.K., Nuyken, O., Kobayashi, S., Yağci, Y., Sar, B. (eds) Macromolecular Engineering. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-1905-8_6

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  • DOI: https://doi.org/10.1007/978-1-4615-1905-8_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-5778-0

  • Online ISBN: 978-1-4615-1905-8

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