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Macrophotoinitiators

Synthesis and Their Use in Block Copolymerization

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Macromolecular Engineering

Abstract

There has been growing interest in the preparation of polymeric photoinitiators [1]. They present several atractive aspects over low molecular weight counterparts including low volatility and migration. As far as migration is concerned, their value in UV curing associated with food packing will be more important since future legislation will require photoinitiating systems with zero migration. Besides UV curing applications, block and graft copolymers can be prepared by using main and side chain polymeric photoinitiators, respectively [2]. These systems consists of a photochemical reactions by which active sites are produced at the chain ends or side chains, which themselves initiates the polymerization of a second monomer.

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Yağci, Y. (1995). Macrophotoinitiators. In: Mishra, M.K., Nuyken, O., Kobayashi, S., Yağci, Y., Sar, B. (eds) Macromolecular Engineering. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-1905-8_12

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  • DOI: https://doi.org/10.1007/978-1-4615-1905-8_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-5778-0

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