Bulk and Surface Studies of Fly Ash Particles

  • Costantino Boni
  • Ezio Cereda
  • Grazia Maria Braga Marcazzan
  • Fulvio Parmigiani


Coal and oil combustion produces fly ash particulates whose dispersion into the environment represents one of the major sources of pollution.


Auger Electron Auger Spectrum Auger Spectroscopy Surface Study Toxic Trace Element 
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  1. Agarwal, B. K., 1991, X-Ray Spectroscopy, Springer-Verlag, New York.Google Scholar
  2. Asking, L., Swietlick, E., and Garg, M. L., 1987, PIGE analysis of sodium in thin aerosol samples, Nucl. Instrum. Methods B22:368–371.Google Scholar
  3. Bellagamba, B., Caridi, A., Cereda, E., Braga Marcazzan, G. M., and Valkovic, V., 1993, PIXE application to the study of trace element behaviour in coal combustion cycle, Nucl. Instrum. Methods B75:222–229.Google Scholar
  4. Bellotto, M., Boni, C., Candi, A., Cereda, E., Chemelli, C., Braga Marcazzan, G. M., Parmigiani, E, Scagliotti, M., and Bellagamba, B., 1990, Analysis of coal fly ash by bulk and surface characterisation techniques, Mater. Res. Soc. Symp. Proc. 178:45–56.CrossRefGoogle Scholar
  5. Boni, C., Cereda, E., Braga Marcazzan, G. M., and De Tomasi, V, 1988, Prompt gamma emission excitation functions for PIGE analysis of Li, B, F, Mg, Al, Si and Pin thin samples, Nucl. Instrum. Methods B35:80–86.Google Scholar
  6. Boni, C., Candi, A., Cereda, E., and Braga Marcazzan, G. M., 1990a, PIXE-PIGE analysis of thin fly-ash samples, Nucl. Instrum. Methods B45:352–355.Google Scholar
  7. Boni, C., Caridi, A., Cereda, E., and Braga Marcazzan, G. M., 1990b, A PIXE-PIGE set-up for the analysis of thin samples, Nucl. Instrum. Methods B47:133–142.Google Scholar
  8. Braga Marcazzan, G. M., Caruso, E., Cereda, E., and Redaelli, P., 1987, The CISE PIXE system for the aerosol characterization in several Italian sites, Nucl. Instrum. Methods. B22:305–314.Google Scholar
  9. Braga Marcazzan, G. M., Bellagamba, B., Bellotto, M., Boni, C., Candi, A., Cereda, E., and Chemelli, C., 1990, Fly ash from a coal power plant: Correlation of elemental and structural composition with electrostatic precipitator collection efficiency, J. Aerosol Sci. 21:697–701.CrossRefGoogle Scholar
  10. Briggs, D., and Seah, M. P., 1983, Practical Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy, John Wiley & Sons, Norwich.Google Scholar
  11. Caridi, A., Cereda, E., Fazinic, S, Jaksic, M., Braga Marcazzan, G. M., Valkovic, O., and Valkovic, V., 1992, Fluorine enrichment phenomena in coal combustion cycle, Nucl. Instrum. Methods B66:298–301.Google Scholar
  12. Candi, A., Cereda, E., Grime, G. W, Jaksic, M., Braga Marcazzan, G. M., Valkovic, V., and Watt, E, 1993, Application of proton microprobe analysis to the study of electrostatic precipitation of single fly ash particles, Nucl. Instrum. Methods B77:524–529.Google Scholar
  13. Carlson, T. A., 1976, Photoelectron and Auger Spectroscopy, Plenum Pres, New York.Google Scholar
  14. Caruso, E., and Parmigiani, E, 1987, Studio dell’ applicazione della Spettroscopia Elettronica alla Diagnostica delle ceneri di Combustione, CISE Report 4364, Segrate, Italy.Google Scholar
  15. Cereda, E., Chemelli, C., Marcazzan, G. M., and Parmigiani, E, 1988, Spettroscopia Elettronica di Fotoemissione da Particolato Prodotto Durante Processi di Combustione in Caldaia, CISE Report 5153, Segrate, Italy.Google Scholar
  16. Cernuschi, S., and Giuliano, M., 1987, Trace element emission factors from coal combustion, Sci. Total Environ. 65:95–107.Google Scholar
  17. Chu, W. K., Mayer, J. W, and Nicolet, M. A., 1978, Backscattering Spectrometry, Academic Press, New York.Google Scholar
  18. Clayton, P, Duerden, P, and Cohen, D. D., 1987, A discussion of PIXAN and PtxwrrwC: The AAEC PIXE analysis computer packages, Nucl Instrum. Methods B22:64–67.Google Scholar
  19. Coles, D. G., Ragaini, R. C., Ondov, J.M., Fisher, G. L., Silberman, D., and Prentice, B. A., 1979, Chemical studies of stack fly ash from a coal-fired power plant, Environ. Sci. Technol. 13: 455–459.CrossRefGoogle Scholar
  20. Cox, X. B., Bryan, S. R., Linton, R. W, and Griffis, D. P, 1987, Microcharacterization of trace elemental distribution within individual coal combustion particles using secondary ion mass spectrometry and digital imaging, Anal. Chem. 59:2018–2023.CrossRefGoogle Scholar
  21. Davis, L. E., MacDonald, N. C., Palmberg, P W, Riach, G. E., and Weber, R. E., 1976, Handbook of Auger Electron Spectroscopy, Physical Electronic Industries, Inc., Eden Prairie, Minnesota.Google Scholar
  22. Davison, R. L., Natusch, D. I. S., Wallace, J. R., and Evans, C. A. Jr., 1974, Trace elements in fly ash, dependence of concentration on particle size, Environ. Sci. Technol. 8:1107–1113.CrossRefGoogle Scholar
  23. Fisher, G. L., Prentice, B. A., Silberman, D., Ondov, J. M., Biermann, A. H.,Ragaini, R. C., and McFarland, A. R., 1978, Physical and morphological studies of size-classified coal fly ash, Environ. Sci. Technol . 12:447–451.CrossRefGoogle Scholar
  24. Grime, G. W, Dawson, M., Marsh, M., McArthur, I. C., and Watt, E, 1991, The Oxford submicron nuclear microscopy facility, Nucl. Instrum. Methods B54:52–63.Google Scholar
  25. Hansen, L. D., and Fisher, G. L., 1980, Elemental distribution in coal fly ash particles, Environ. Sci. Technol. 14:1111–1117.CrossRefGoogle Scholar
  26. Hock, J. L., and Lichtman, D., 1982, Studies of surface layers on single particles of in-stack coal fly ash, Environ. Sci. Technol. 16:423–427.CrossRefGoogle Scholar
  27. Jaksic, M., Watt, F, Grime, G. W, Cereda, E., Braga Marcazzan, G. M., and Valkovic, V., 1991, Proton microprobe analysis of the trace element distribution in fly ash particles, Nucl. Instrum. Methods B56/57:699–702.Google Scholar
  28. Jaksic, M., Bogdanovic, I.,Cereda, E., Fazinic, S., and Valkovic, V, 1993, Quantitative PIXE analysis of single fly ash particles by a proton microbeam, Nucl. Instrum. Methods B77:505–508.Google Scholar
  29. Johansson, S. A. E., and Campbell, J. L., 1988, PIXE: A Novel Technique for Elemental Analysis, John Wiley & Sons, New York.Google Scholar
  30. Kaakinen, J. W., Jordan, R. M., Lawasani, M. H., and West, R. E., 1975, Trace element behavior in coal-fired plant, Environ. Sci. Technol. 9:862–869.CrossRefGoogle Scholar
  31. Kauppinen, E. I.,and Pakkanen, T. A., 1990, Coal combustion aerosol: A field study, Environ. Sci. Technol.24:1811–1818.CrossRefGoogle Scholar
  32. Kiss, A. Z., Koltay, E., Nyako, B., Somorjai, E., Anttila, A., and Raisanen, J., 1985, Measurements of relative thick target yields for PIGE analysis of light elements in the proton energy interval 2.44.2 MeV, J. Radioanal. Chem. 89:123–141.CrossRefGoogle Scholar
  33. Klein, D. H., Andren, A. W., Carter, J. A., Emery, J. F, Feldman, C., Fulkenon, W, Lyon, W. S., Ogle, J. C., Talmi, Y., Van Hook, R., and Bolton, N., 1975, Pathways of thirty-seven trace elements through coal-fired power plant, Environ. Sci. Technol. 9:973–979.CrossRefGoogle Scholar
  34. Lee, R. E., Jr., Crist, H. L., Riley, A. E., and MacLeod, K. E., 1975, Concentration and size of trace metal emissions from a power plant, a steel plant and a cotton gin, Environ. Sci. Technol. 9: 643–647.CrossRefGoogle Scholar
  35. Linton, R. W, Loh, A., Natusch, D. F. S., Evans, C. A., and Williams, P., 1976, Surface predominance of trace elements in airborne particles, Science 191:852–854.CrossRefGoogle Scholar
  36. Linton, R. W, Williams, P., Evans, C. A., and Natusch, D. F. S., 1977, Determination of the surface predominance of toxic elements in airborne particles by ion mass spectrometry and Auger electron spectrometry, Anal. Chem. 49:1514–1521.CrossRefGoogle Scholar
  37. Maclas, E. S., Radcliffe, C. D., Lewis, C. W, and Sawicki, C. R., 1978, Proton induced y-ray analysis of atmospheric aerosols for carbon, nitrogen, and sulfur composition, Anal. Chem. 50:1120–1124.CrossRefGoogle Scholar
  38. Mamane, Y., Miller, J. L., and Dzubay, T. G., 1986, Characterization of individual fly ash particles emitted from coal-and oil-fired power plants, Atmos. Environ. 20:2125–2135.CrossRefGoogle Scholar
  39. Markowski, G. R., and Filby, R., 1985, Trace element concentration as a function of particle size in fly ash from a pulverized coal utility boiler, Environ. Sci. Technol. 19:796–804.CrossRefGoogle Scholar
  40. Moulder, J. F, Stickle, W. F, Sobol, P. E., and Bomben, K. D., 1992, Handbook of X-ray Photoelectron Spectroscopy (Jill Chastain, ed.), Perkin-Elmer Corporation Physical Electronics Division, Eden Prairie, Minnesota.Google Scholar
  41. Raisanen, J., and Lapatto, R., 1988, Analysis of sulphur with external beam proton induced gamma-ray emission analysis, Nucl. Instrum. Methods B30:90–93.Google Scholar
  42. Ramsden, A. R., and Shibaoka, M., 1982, Characterization and analysis of individual fly-ash particles from coal-fired power stations by a combination of optical microscopy, electron microscopy and quantitative electron microprobe analysis, Atmos. Environ. 16:2191–2206.CrossRefGoogle Scholar
  43. Robaye, G., Delbrouck-Habaru, J. M., Roelandts, I., Weber, C., Girard-Reydet, L., Morelli, J., and Qiusefit, J. P, 1985, PIGE coupled with PIXE for sodium determination in atmospheric aerosol samples, Nucl. Instrum. Methods. B6:558–561.Google Scholar
  44. Siegbahn, K., et al., 1969, ESCA Applied to Free Molecules, North-Holland, Amsterdam.Google Scholar
  45. Smith, R. D., Campbell, J. S., and Nielson, K. K., 1979, Characterization and formation of submicron particles in coal-fired plants, Atmos. Environ. 13:607–617.CrossRefGoogle Scholar
  46. Stinespring, C. D., and Stewart, G. W, 1981, Surface enrichment of aluminosilicate minerals and coal combustion ash particles, Atmos. Environ. 15:307–313.CrossRefGoogle Scholar
  47. Tazaki, K., Fyfe, W. S., Sahn, K. C., and Powell, M., 1989, Observations on the nature of fly ash particles, Fuel 68:727–734.CrossRefGoogle Scholar
  48. Valkovic, V., 1983, Trace Elements in Coal, CRC Press, Boca Raton, Florida.Google Scholar
  49. Valkovic, V, Makjanic, J., Jaksic, M., Popovic, S., Bos, A., Vis, R. D., Wiederspahn, K., and Verheul, H., 1984, Analysis of fly ash by X-ray emission spectroscopy and proton microbeam analysis, Fuel 63:1357–1363.CrossRefGoogle Scholar
  50. Vis, R. D., Bos, A., Valkovic, V, and Verheul, H., 1983, The analysis of fly ash particles with a proton microbeam, IEEE Trans. Nucl. Sci. NS-30:1236–1239.CrossRefGoogle Scholar
  51. Watt, F, and Grime, G. W, 1987, Principles and Applications of High-Energy Ion Microbeams, Adam Hilger, Bristol.Google Scholar

Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • Costantino Boni
    • 1
  • Ezio Cereda
    • 1
  • Grazia Maria Braga Marcazzan
    • 2
  • Fulvio Parmigiani
    • 3
    • 4
  1. 1.Materials DivisionCISE Tecnologie Innovative S.p.A.MilanItaly
  2. 2.Istituto di Fisica Generale ed ApplicataUniversità degli Studi di MilanoMilanItaly
  3. 3.Materials DivisionCISE Tecnologie Innovative S.p.A.MilanItaly
  4. 4.Facoltà di ScienzeUniversità di ComoComoItaly

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