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Homologation Reactions of Alkanes on Transition-Metal Surfaces

  • R. H. Cunningham
  • R. A. van Santen
  • A. V. G. Mangnus
  • J. H. B. J. Hoebink

Abstract

A combination of experiments using TAP, and isotopic labelling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temperature CO or CH4 adsorption was shown to be more likely at high temperatures, and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso- ratio between labelled and non-labelled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane.

Keywords

Surface Species Adsorption Temperature Boudouard Reaction Hydrogenation Step Hydrogenolysis Activity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • R. H. Cunningham
    • 1
  • R. A. van Santen
    • 1
  • A. V. G. Mangnus
    • 1
  • J. H. B. J. Hoebink
    • 1
  1. 1.Schuit Institute of CatalysisEindhoven University of TechnologyEindhovenThe Netherlands

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