Abstract
The effect of grain boundary type on intergranular oxidation was studied in a nickel-40at%iron alloy. It has been found that intergranular oxidation takes place preferentially at random boundaries while low-Σ coincidence boundaries, particularly Σ3, Σ11, Σ19 and Σ27 coincidence boundaries have excellent oxidation resistance. The grain boundary engineering for the control of oxidation-assisted intergranular brittleness has been attempted by taking account important roles of the grain size, the grain boundary character distribution (GBCD) and the grain boundary connectivity. The presence of an optimal grain boundary microstructure for this purpose has been predicted.
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References
Birks, N. and Meier, G. H., Introduction of High Temperature Oxidation of Metals, Edward Arnold, (1983).
Rapp, R. A., The high temperature oxidation of metals forming cation-diffusing scales, Met Trans., 15(b): 195, (1984).
Matsuno, F., Nishikida, S. and Harada, T., Oxidation of Fe-Ni alloys at high temperatures, Tetsu to Hagane, 67: 2029, (1981).
Bricknell, R. H. and Woodford, D. A, Grain boundary embrittlement of the iron-based superalloy IN903A, Met. Trans., 12A: 1673, (1981).
Katsman, A., Grabke, H. J. and Levin, L., Penetration of oxygen along grain boundaries during oxidation of alloys and intermetallics, Oxidation of Metals, 46: 313, (1996).
Czerwinski, F. and Szpunar, J. A., The effect of reactive element on texture and grain boundary character distribution in nickel oxide, Corrosion Science, 39: 1459, (1997).
Kusabiraki, K., Ikegami, J., Nishimoto, T. and Ooka, T., High-temperature oxidation of Fe-38Ni-13Co-4.7Nb-l.5Ti-0.4Si superalloy in Ar-H2O atmosphere, Tetsu to Hagane, 80:574,(1994).
Kusabiraki, K., Sakuradani, K., and Saji, S., Effect of tensile stress on grain boundary selective oxidation in an Fe-36%Ni alloy, Tetsu to Hagane, 84: 291, (1998).
Watanabe, T., An approach to grain boundary design for strong and ductile polycrystals, Res Mechanica, 11: 47, (1984).
Watanabe, T., Grain boundary design and control for high temperature materials, Mater. Sci.Eng., A166: 11,(1993).
Palumbo, G., Lehockey, E. M.and Lin, P., Applications for grain boundary engineered materials, J. Metals, 50,40, (1998).
Watanabe, T., Observation of plane-matching grain boundaries by electron channelling patterns, Phil. Mag., A47: 141, (1983).
Kaur, I. and Gust, W., Fundamentals of Grain and Interphase Boundary Diffusion, Ziegler Press, Stuttgart, (1988).
Smith, D. A., On the density of coincidence sites in grain boundaries, Scripta Met., 8: 1197, (1974).
Yamaura, S., Igarashi, Y., Tsurekawa, S. and Watanabe, T., Structure-dependent intergranular oxidation in Ni-Fe polycrystalline alloy, Acta Mater., 47: 1163, (1999).
Was, G. S., Thaveeprungsriporn, V. and Crawford, D. C., Grain boundary misorientation effect on creep and cracking in Ni-Based Alloys, J. Metals, 50: 44, (1998).
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Yamaura, S., Igarashi, Y., Tsurekawa, S., Watanabe, T. (2000). Grain Boundary Engineering for the Control of Oxidation Embrittlement. In: Meike, A., Gonis, A., Turchi, P.E.A., Rajan, K. (eds) Properties of Complex Inorganic Solids 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-1205-9_3
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DOI: https://doi.org/10.1007/978-1-4615-1205-9_3
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