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Complexes of Amphoteric Polyelectrolytes

  • Chapter
Polyampholytes

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Abstract

The complex formation problems of amphoteric copolymers with respect to metal ions, detergents, dyes and organic probes are of great interest. The interaction of metal ions M with polymeric ligands L proceeds as follows1: M + L ⇔ ML; ML + M ⇔ ML2; MLn-1 + M ⇔ MLn The stability constant of polymer-metal complex β is equal to: βn = k 1 k 2 k 3 … k n = [MLn]/[M]·[L]n Function n, which characterizes the average number of ligands bound to metal ions, is determined from the Eq. (3.1.1):

$$n = \frac{{{{[L]}_t} - [LH] - [L]}}{{{{[M]}_t}}}$$
(3.1.1)

where [L]t, and [M]t, are the total concentrations of ligand and metal ions; [L] and [LH] are the concentrations of free (uncomplexed) and protonated ligands respectively.

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  1. Institute of Polymer Materials and Technology, Almaty, Republic of Kazakhstan

    Sarkyt E. Kudaibergenov

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Kudaibergenov, S.E. (2002). Complexes of Amphoteric Polyelectrolytes. In: Polyampholytes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-0627-0_3

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