Abstract
SiLK (trademark of The Dow Chemical Company) semiconductor dielectric is a low-k organic polymer, based on the synthesis of crosslinked polyphenylenes by the reaction of poly functional cyclopentadienone- and acetylene-containing materials1. SiLK dielectric is used for high performance integrated circuits with subtractive Al/W 2–4 or Cu damascene 5–7 wiring technology. The properties of cured SiLK enable integration with current interlayer dielectric (ILD) processes: for example, high thermal stability, high Tg, low dielectric constant, no fluorine, spin-on application, good adhesion and mechanical durability, low moisture absorption, and solvent resistance. Some of these properties are listed in Table 1.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. P. Godschalx, D. R. Romer, Y. H. So, Z. Lysenko, M. E. Mills, G. R. Buske, P. H. Townsend, D. W. Smith, Jr., S. J. Martin, and R. A. DeVries, US Patent 5,965, 679 (1999).
Lee, M. Chae, H. Kim, S. Kim, C. T. Kim, J. M. Hwang, in proc. Int. Interconnect Tech. Conf., San Francisco, CA, June 5–7, 137–139 (2000)
J. Waeterloos, M. Simmonds, A. Achen, and M. Meier, Semicond. Eur. Aug. 26 (1999)
H. Maynard, C. S. Pai, C. B. Case, R. O. Adebanjo, M. R. Baker, W. Wai Tai, R. Liu, in proc. Int. Interconnect Tech. Conf., San Francisco, CA, May 24–26, 212–214 (1999)
R. D. Goldblatt, et al., in proc. Int. Interconnect Tech. Conf., San Francisco, CA, June 5–7, 261–263 (2000)
M. Ikeda, H. Kudo, R. Shinohara, F. Shimpuku, M. Yamada, Y. Furumura, in proc. Int. Interconnect Tech. Conf, San Francisco, CA, June 1–3,131–133 (1998)
O. Demollien, et. al., in proc. Int. Interconnect Tech. Conf., San Francisco, CA, May 24–26, 198–199 (1999)
P. Townsend, S. Martin, J. Godschalx, D. Romer, D. Smith, D. Castillo, R. DeVries, G. Buske, N. Rondan, S. Froelicher, J. Marshall, E. O. Shaffer II, and J-H. Im, Thermosetting Polymer Coating with Low Dielectric Constant and High Thermal Stability for ULSI Interlayer Dielectric, proc. MRS Symp. 476, 9–17 (1997)
S. Martin, J. P. Godschalx, M. E. Mills, E. O. Shaffer II, and P. H. Townsend, Development of a Low-Dielectric-Constant Polymer for the Fabrication of Integrated Circuit Interconnect, Adv. Mater., 12, No. 23,1769–1778 (2000)
E. O.Shaffer II, L. Hoang, and F. J. McGarry, Edge Liftoff: A New Test for Adhesion, Polym. Sci. & Eng., 36,18,2375–2381(1996)
J. Im, E. O. Shaffer II, T. Stokich, Jr., A. Strandjord, J. Hetzner, J. Curphy, C. Karas, G. Meyers, D. Hawn, A. Chakrabarti, and S. Froelicher, On the Mechanical Reliability of Photo-BCB-Based Thin Film Dielectric Polymer for Electronic Packaging Applications, J. Elec. PKG, 122, 1, 28–33 (2000)
J. Hay, E. G. Liniger, and X. H. Liu, Evaluation of the Modified Edge Lift-Off Test for Adhesion Characterization in Microelectronic Multifilm Applications, J. Mater. Res., 16, 2, 385–393 (2001).
A. S. Voloshin, P.-H. Tsao, and R. A. Pearson, In Situ Evaluation of Residual Stress in an Organic Die-Attach Adhesive, trans. ASME, J. Elec. PKG, 120, 314–318 (1998).
S. Rzepka, M. A. Korhonen, E. Meusel, C.-Y. Lee, The Effect of Underfill and Underfill Delamination on the Thermal Stress in Flip-Chip Solder Joints, trans. ASME, J. Elec. PKG, 120, 342–348 (1998)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media New York
About this chapter
Cite this chapter
Im, J., Townsend, P.H., Curphy, J., Karas, C., Shaffer, E.O. (2002). Mechanical Properties of Cured SiLK Low-K Dielectric Films. In: Sacher, E. (eds) Metallization of Polymers 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-0563-1_6
Download citation
DOI: https://doi.org/10.1007/978-1-4615-0563-1_6
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-5134-4
Online ISBN: 978-1-4615-0563-1
eBook Packages: Springer Book Archive