Abstract
Chemical treatment of metal artifacts to determine their composition was one of the first applications of science to archaeology. In this chapter, various chemical and isotopic analytical techniques are described as they relate to the study of ancient metals. In addition, the problems and pitfalls of such analyses, especially as they relate to attempts to assign “provenance” to ancient artifacts, are discussed. In general, the chemical and isotopic analysis of metal artifacts as well as metallurgical artifacts (e.g., crucibles and slags) is essential for reconstructing the ancient technological process.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Notes
- 1.
It is important to note whether results are expressed in atomic or weight %. Atomic % denotes the percentage of the total number of atoms in a sample that are of a particular element. Weight % denotes what percentage of the mass of the sample each element contributes. If an archaeometallurgy paper does not explicitly state which system has been used, with caution, it can be assumed the results are in weight %.
- 2.
Bear in mind that, with at least 93 naturally occurring elements in the Periodic Table, no analysis containing fewer elements can truly claim to be ‘fully quantitative’!
Bibliography
Bray, P. (2009). Exploring the social basis of technology: Reanalysing regional archaeometric studies of the first copper and tin-bronze use in Great Britain and Ireland. Unpublished D.Phil. Thesis, University of Oxford.
Bray, P., & Pollard, A. M. (2012). A new interpretative approach to the chemistry of copper-alloy objects: source, recycling and technology. Antiquity 86, 853–867.
Brothwell, D. R., & Pollard, A. M. (Eds.). (2001). Handbook of Archaeological Sciences. Chichester: John Wiley and Sons.
Junghans, S., Sangmeister, E., & Schröder, M. (1960). Metallanalysen kuperzeitlicher und fühbronzezeitlicher Bodenfunde aus Europa. Studien zu den Anfängen der Metallurgie 1. Berlin: Gebr. Mann.
Junghans, S., Sangmeister, E., & Schröder, M. (1968). Kupfer und Bronze in der frühen Metallzeit Europas. Studien zu den Anfängen der Metallurgie 2 Berlin: Gebr. Mann
Pernicka, E. (1998). Whither metal analysis in archaeology? In C. Mordant, M. Peront, & V. Rychner (Eds.), L’Atelier du Bronzier en Europe du xxe au viiie siècle avant notre ère; vol 1: 259–267. Paris: Edition du CTHS.
Pollard, A. M., & Heron, C. (2008). Archaeological Chemistry. Cambridge, Royal Society of Chemistry (2nd revised ed).
Pollard, A. M., Thomas, R. G., Ware, D. P., & Williams, P. A. (1991). Experimental smelting of secondary copper minerals: implications for Early Bronze Age metallurgy in Britain. In E. Pernicka, & G.A. Wagner (Eds.) Archaeometry ’90:127–136. Basel: Birkhauser Verlag
Pollard, M., Batt, C., Stern, B., & Young, S. M. M. (2007). Analytical Chemistry in Archaeology. Cambridge: Cambridge University Press.
Rehren, Th., & Pernicka, E. (2008). Coins, artefacts and isotopes – archaeometallurgy and archaeometry. Archaeometry, 50(2), 232–248.
Rohl, B., & Needham, S. (1998). The Circulation of Metal in the British Bronze Age: the Application of Lead Isotope Analysis. Occasional Paper 102, British Museum, London
Rowlands, M. J. (1971). The archaeological interpretation of prehistoric metalworking. World Archaeology, 3, 210–224.
Shortland, A. J., Freestone, I. C., & Rehren, Th. (Eds.). (2009). From Mine to Microscope – Advances in the Study of Ancient Technology. Oxford, Oxbow Books.
Tylecote, R. F. (1976). A History of Metallurgy. Metals Society, London (2nd ed., Institute of Materials, London, 1992).
Tylecote, R. F. (1987). The Early History of Metallurgy in Europe. London: Longman.
Young, S. M. M., Pollard, A. M., Budd, P. D., & Ixer, R. A. (Eds.). (1999). Metals in Antiquity. BAR International Series 792. Oxford: Archaeopress.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Science+Business Media New York
About this chapter
Cite this chapter
Pollard, A., Bray, P. (2014). Chemical and Isotopic Studies of Ancient Metals. In: Roberts, B., Thornton, C. (eds) Archaeometallurgy in Global Perspective. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-9017-3_10
Download citation
DOI: https://doi.org/10.1007/978-1-4614-9017-3_10
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4939-3357-0
Online ISBN: 978-1-4614-9017-3
eBook Packages: Humanities, Social Sciences and LawSocial Sciences (R0)