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Dispersion of Impedances at Solid Electrodes

  • Andrzej Lasia
Chapter

Abstract

The impedance of liquid at ideally polarizable electrodes (e.g., mercury, amalgams, indium-gallium) may be modeled by an R-C circuit (Fig. 4.1a). However, most impedance studies are now carried out at solid electrodes. At these electrodes the double-layer capacitance is not purely capacitive and often displays a certain frequency dispersion. Such behavior cannot be modeled by a simple circuit consisting of R, L, and C elements. To explain such behavior, a constant phase element (CPE) is usually used.

Keywords

Fractal Dimension Charge Transfer Resistance Constant Phase Element Bide Plot Faradaic Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Andrzej Lasia
    • 1
  1. 1.Département de chimieUniversité de SherbrookeSherbrookeCanada

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