Abstract
Many reactions of industrial importance are electrocatalytic, i.e., they involve the specific adsorption of intermediates, for example hydrogen, chlorine, and oxygen evolution, oxygen reduction, and methanol or ethanol oxidation in fuel cells. Many different electrochemical techniques were used to study these reactions, and EIS is one of them, providing interesting kinetic and surface information. Certain model reactions will be presented in what follows with a detailed method of relating impedance parameters with mechanistic and kinetic equations.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
A.J. Bard, L.R. Faulkner, Electrochemical Methods. Fundamentals and Applications (Wiley, New York, 2001)
A. Lasia, Applications of electrochemical impedance spectroscopy to hydrogen adsorption, evolution and absorption into metals, in Modern Aspects of Electrochemistry, vol. 35, ed. by B.E. Conway, R.E. White (Kluwer/Plenum, New York, 2002), p. 1
L. Birry, A. Lasia, Electrochim. Acta 51, 3356 (2006)
J. Barber, S. Morin, B.E. Conway, J. Electroanal. Chem. 446, 125 (1998)
D.A. Harrington, B.E. Conway, Electrochim. Acta 32, 1703 (1987)
A. Lasia, A. Rami, J. Electroanal. Chem. 294, 123 (1990)
M.R.G. de Chialvo, A.C. Chialvo, J. Electrochem. Soc. 147, 1619 (2000)
E. Leiva, Electrochim. Acta 41, 2185 (1996)
A. Lasia, J. Electroanal. Chem. 562, 23 (2004)
D.A. Harrington, B.E. Conway, J. Electroanal. Chem. 221, 1 (1987)
M.R. Gennero de Chialvo, A.C. Chialvo, Electrochim. Acta 44, 841 (1998)
A. Lasia, J. Electroanal. Chem. 562, 23 (2004)
B. Losiewicz, R. Jurczakowski, A. Lasia, Electrochim. Acta 80, 292 (2012)
B. Losiewicz, M. Martin, C. Lebouin, A. Lasia, J. Electroanal. Chem. 649, 19 (2010)
C. Gabrielli, P.P. Grand, A. Lasia, H. Perrot, J. Electrochem. Soc. 151, A1943 (2004)
H. Duncan, A. Lasia, Electrochim. Acta 52, 6195 (2007)
B. Losiewicz, R. Jurczakowski, A. Lasia, Electrochim. Acta 56, 5746 (2011)
R. Jurczakowski, B. Losiewicz, A. Lasia, Kinetics and thermodynamics of HUPD on iridium in perchloric and sulfuric acids. 59th Meeting of the International Society for Electrochemistry, Seville, September 2008
F. Dion, A. Lasia, J. Electroanal. Chem. 475, 28 (1999)
S. Morin, H. Dumont, B.E. Conway, J. Electroanal. Chem. 412(1999), 39 (1996)
A. Lasia, Curr. Top. Electrochem. 2, 239 (1993)
E.R. Gonzalez, G. Tremiliosi-Filho, M.J. de Giz, Curr. Top. Electrochem. 2, 167 (1993)
M.R.G. de Chialvo, A.C. Chialvo, Electrochem. Commun. 1, 379 (1999)
P.M. Quaino, M.R.G. de Chialvo, A.C. Chialvo, Electrochim. Acta 52, 7396 (2007)
C. Hitz, A. Lasia, J. Electroanal. Chem. 532, 133 (2002)
L. Bai, D.A. Harrington, B.E. Conway, J. Electroanal. Chem. 32, 1713 (1987)
J.H. Barber, B.E. Conway, J. Electroanal. Chem. 461, 80 (1999)
M.J. de Giz, G. Tremiliosi-Filho, E.R. Gonzalez, Electrochim. Acta 39, 1775 (1994)
R.K. Shervedani, A. Lasia, J. Electrochem. Soc. 145, 2219 (1998)
L.L. Chen, A. Lasia, J. Electrochem. Soc. 138, 3321 (1991)
N.A. Assungao, M.J. de Giz, G. Tremiliosi-Filho, E.R. Gonzalez, J. Electrochem. Soc. 144, 2794 (1997)
J.-P. Diard, B. Le Gorrec, C. Montella, J. Electroanal. Chem. 466, 122 (1999)
J. Barber, B.E. Conway, J. Electroanal. Chem. 466, 124 (1999)
A. Lasia, J. Electroanal. Chem. 593, 159 (2006)
J.O.’.M. Bockris, J. McBreen, L. Nanis, J. Electrochem. Soc. 112, 1025 (1965)
S.Y. Qian, B.E. Conway, G. Jerkiewicz, Int. J. Hydrog. Energy 25, 539 (2000)
A. Lasia, D. Gregoire, J. Electrochem. Soc. 142, 3393 (1995)
C. Lim, S.-I. Pyun, Electrochim. Acta 38, 2645 (1993)
C. Lim, S.-I. Pyun, Electrochim. Acta 39, 363 (1994)
I.A. Bagotskaya, Zh. Fiz. Khim. 36, 2667 (1962)
J.S. Chen, J.P. Diard, R. Durand, C. Montella, J. Electroanal. Chem. 406, 1 (1996)
M.H. Martin, A. Lasia, Electrochim. Acta 53, 6317 (2008)
H. Duncan, A. Lasia, Electrochim. Acta 52, 6195 (2007)
M.H. Martin, A. Lasia, Electrochim. Acta 54, 5292 (2009)
H. Duncan, A. Lasia, J. Electroanal. Chem. 621, 62 (2008)
L. Birry, Etude des reactions d’insertion d’hydrogene dans des electrodes de palladium, PhD Thesis, Universite de Sherbrooke, 2005
L.O. Valeen, S. Sunde, R. Tunold, J. Alloy Comp. 253–254, 656 (1997)
B.S. Haran, B.N. Popov, R.E. White, J. Power Sources 75, 56 (1998)
C. Wang, J. Electrochem. Soc. 145, 1801 (1998)
L.O. Valeen, A. Lasia, J.O. Jensen, R. Tunold, Electrochim. Acta 47, 2871 (2002)
P. Zoltowski, Electrochim. Acta 44, 4415(1999); 51, 1576 (2006); 55, 6274 (2010)
P. Zoltowski, Acta Mater. 51, 5489 (2003)
J.S. Chen, R. Durand, C. Montella, J. Chim. Phys. 91, 383 (1994)
Y.-G. Yoon, S.I. Pyun, Electrochim. Acta 40, 999 (1995)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Science+Business Media New York
About this chapter
Cite this chapter
Lasia, A. (2014). Electrocatalytic Reactions Involving Hydrogen. In: Electrochemical Impedance Spectroscopy and its Applications. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-8933-7_7
Download citation
DOI: https://doi.org/10.1007/978-1-4614-8933-7_7
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4614-8932-0
Online ISBN: 978-1-4614-8933-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)