Abstract
Silicon and germanium are among the most promising anode materials for high performance lithium ion batteries, due to their unprecedented high capacities. In recent few years, increasingly enormous efforts have been dedicated to these two important anodes, leading to significant improvement in their cycling life, practical capacity, rate capability, and coulombic efficiency. Nanostructuring is playing a crucial role in enabling the improvement and will lead to their widespread use in various battery markets. Nanoscale particles can better tolerate the wild volume change upon cycling and maintain their integrity than micron-sized particles. They can also shorten the diffusion distance of lithium ions and electrons and thus have high capacity. Further, one-dimensional nanowires exhibit superior stress behavior and electron transport. Porous and hierarchical nanostructures can provide extra space to accommodate the volume change. Wisely manipulating these handles have produced impressively better-performing systems. Porous single-crystal silicon nanowires have shown more stable capacity than solid nanowires. Hierarchical porous amorphous \(\mathrm{{GeO}}_\mathrm{x}\) is another system with very long cycle life and high capacity.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Li, H., Huang, X.J., Chen, L.Q., Wu, Z.G., Liang, Y.: A high capacity nano-Si composite anode material for lithium rechargeable batteries. Electrochem. Solid State Lett. 2, 547–549 (1999)
Wang, C.S., Wu, G.T., Zhang, X.B., Qi, Z.F., Li, W.Z.: Lithium insertion in carbon-silicon composite materials produced by mechanical milling. J. Electrochem. Soc. 145, 2751–2758 (1998)
Kim, H., Seo, M., Park, M.H., Cho, J.: A critical size of silicon nano-anodes for lithium rechargeable batteries. Angew. Chem. Int. Ed. 49, 2146–2149 (2010)
Wang, X.L., Feygenson, M., Aronson, M.C., Han, W.Q.: Sn/\({\rm {SnO}}_{\rm {x}}\) core-shell nanospheres: synthesis, anode performance in Li ion batteries, and superconductivity. J. Phys. Chem. C 114, 14697–14703 (2010)
Huang, J.Y., Zhong, L., Wang, C.M., Sullivan, J.P., Xu, W., Zhang, L.Q., Mao, S.X., Hudak, N.S., Liu, X.H., Subramanian, A., Fan, H.Y., Qi, L.A., Kushima, A., Li, J.: In situ observation of the electrochemical lithiation of a single \({\rm {SnO}}_2\) Nanowire electrode. Science 330, 1515–1520 (2010)
Chan, C.K., Peng, H.L., Liu, G., McIlwrath, K., Zhang, X.F., Huggins, R.A., Cui, Y.: High-performance lithium battery anodes using silicon nanowires. Nat. Nanotechnol. 3, 31–35 (2008)
Graetz, J., Ahn, C.C., Yazami, R., Fultz, B.: Nanocrystalline and thin film germanium electrodes with high lithium capacity and high rate capabilities. J. Electrochem. Soc. 151, A698–A702 (2004)
Magasinski, A., Dixon, P., Hertzberg, B., Kvit, A., Ayala, J., Yushin, G.: High-performance lithium-ion anodes using a hierarchical bottom-up approach. Nat. Mater. 9, 353–358 (2010)
Fan, Q., Chupas, P.J., Whittingham, M.S.: Characterization of amorphous and crystalline tin-cobalt anodes. Electrochem. Solid State Lett. 10, A274–A278 (2007)
Besenhard, J.O., Yang, J., Winter, M.: Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? J. Power Sources 68, 87–90 (1997)
Mao, O., Dunlap, R.A., Dahn, J.R.: Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries-I. The \({\rm {Sn}}_2{\rm {Fe}}\)-C system. J. Electrochem. Soc. 146, 405–413 (1999)
Wang, X.L., Han, W.Q., Chen, J.J., Graetz, J.: Single-crystal intermetallic M-Sn (\({\rm M} = {\rm {Fe}}\), Cu, Co, Ni) nanospheres as negative electrodes for lithium-ion batteries. ACS Appl. Mater. Interfaces 2, 1548–1551 (2010)
Wang, X.L., Feygenson, M., Chen, H.Y., Lin, C.H., Ku, W., Bai, J.M., Aronson, M.C., Tyson, T.A., Han, W.Q.: Nanospheres of a new intermetallic FeSn(5) phase: synthesis, magnetic properties and anode performance in Li-ion batteries. J. Am. Chem. Soc. 133, 11213–11219 (2011)
Wang, X.L., Chen, H.Y., Bai, J.M., Han, W.Q.: CoSn5 phase: crystal structure resolving and stable high capacity as anodes for Li ion batteries. J. Phys. Chem. Lett. 3, 1488–1492 (2012)
Wang, X.L., Han, W.Q.: Graphene enhances Li storage capacity of porous single-crystalline silicon nanowires. ACS Appl. Mater. Interfaces 2, 3709–3713 (2010)
Huang, R., Fan, X., Shen, W.C., Zhu, J.: Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes. Appl. Phys. Lett. 95, 133119 (2009)
Obrovac, M.N., Krause, L.J.: Reversible cycling of crystalline silicon powder. J. Electrochem. Soc. 154, A103–A108 (2007)
Wang, X.L., Han, W.Q., Chen, H.Y., Bai, J.M., Tyson, T.A., Yu, X.Q., Wang, X.J., Yang, X.Q.: Amorphous hierarchical porous \({\rm {GeO}}_{\rm x}\) as high-capacity anodes for Li ion batteries with very long cycling life. J. Am. Chem. Soc. 133, 20692–20695 (2011)
Yoon, S., Park, C.M., Sohn, H.J.: Electrochemical characterizations of germanium and carbon-coated germanium composite anode for lithium-ion batteries. Electrochem. Solid State Lett. 11, A42–A45 (2008)
Kim, H., Cho, J.: Superior lithium electroactive mesoporous Si@carbon core-shell nanowires for lithium battery anode material. Nano Lett. 8, 3688–3691 (2008)
Han, W.Q., Zhang, Y.: Magnéli phases \({\rm {Ti}}_{\rm {n}}{\rm {O}}_{2{\rm {n}}-1}\) nanowires: formation, optical, and transport properties. Appl. Phys. Lett. 92, 203117 (2008)
Han, W.Q., Wang, X.L.: Carbon-coated magnéli-phase Ti(n)O(2n\(-\)1) nanobelts as anodes for Li-ion batteries and hybrid electrochemical cells. Appl. Phys. Lett. 97, 243104 (2010)
Wang, Q., Wen, Z.H., Li, J.H.: A hybrid supercapacitor fabricated with a carbon nanotube cathode and a \({\rm {TiO}}_2\)-B nanowire anode. Adv. Funct. Mater. 16, 2141–2146 (2006)
Wang, D.W., Fang, H.T., Li, F., Chen, Z.G., Zhong, Q.S., Lu, G.Q., Cheng, H.M.: Aligned titania nanotubes as an intercalation anode material for hybrid electrochemical energy storage. Adv. Funct. Mater. 18, 3787–3793 (2008)
Acknowledgments
We thank our colleagues Drs. J. J. Chen, J. Graetz, M. Feygenson, M. C. Aronson, H. Y. Chen, C. H. Lin, W. Ku, J. M. Bai, T. A. Tyson, X. Q. Yu, X. J. Wang, and X. Q. Yang for their helpful advice. We also are grateful to Dr. H. Li (Institute of Physics, Chinese Academy of Sciences) and Drs. J. Hong, F. Wang, L. H. Zhang, L. J. Wu. and C. Ma (Brookhaven National Laboratory) for their technical support and valuable discussions.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media New York
About this chapter
Cite this chapter
Wang, XL., Han, WQ. (2013). The Development of Si and Ge-Based Nanomaterials for High Performance Lithium Ion Battery Anodes. In: Li, H., Wu, J., Wang, Z. (eds) Silicon-based Nanomaterials. Springer Series in Materials Science, vol 187. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-8169-0_2
Download citation
DOI: https://doi.org/10.1007/978-1-4614-8169-0_2
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4614-8168-3
Online ISBN: 978-1-4614-8169-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)