Abstract
Room-temperature ionic liquids (RTILs) are a unique class of compounds containing organic cations and anions, which melt at or close to room temperature, and thus they are called as room-temperature molten salts. Present chapter describes these compounds and analyzes advantages of ionic liquids for application in gas sensors of various types. Discussion on shortcomings of RTILs-based gas sensors is also presented. Chapter includes 4 figures, 2 Tables and 63 references.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ahmad S (2009) Polymer electrolytes: characteristics and peculiarities. Ionics 15:309–321
AlNashef IM, Leonard ML, Matthews MA, Weidner JW (2002) Superoxide electrochemistry in an ionic liquid. Ind Eng Chem Res 41:4475–4478
Anastas PT (2007) Introduction: green chemistry. Chem Rev 107:2167–2168
Anderson JL, Armstrong DW (2003) High-stability ionic liquids. A new class of stationary phases for gas chromatography. Anal Chem 75:4851–4858
Baker GA, Baker SN, Pandey S, Bright FV (2005) An analytical view of ionic liquids. Analyst 130:800–808
Bowlas CJ, Bruce DW, Seddon KR (1996) Liquid-crystalline ionic liquids. Chem Commun 1996(14):1625–1626
Broder TL, Silvester DS, Aldous L, Hardacre C, Compton RG (2007) Electrochemical oxidation of nitrite and the oxidation and reduction of NO2 in the room temperature ionic liquid [C2mim][NTf2]. J Phys Chem B 111:7778–7785
Buzzeo MC, Klymenko OV, Wadhawan JD, Hardacre C, Seddon KR, Compton RG (2003) Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide and hexyltriethylammonium is((trifluoromethyl)sulfonyl)imide: One-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide. J Phys Chem A 107:8872–8878
Buzzeo MC, Evans RG, Compton RG (2004a) Non-haloaluminate room-temperature ionic liquids in electrochemistry—a review. Chemphyschem 5:1106–1120
Buzzeo MC, Giovanelli D, Lawrence NS, Hardacre C, Seddon KR, Compton RG (2004b) Elucidation of the electrochemical oxidation pathway of ammonia in dimethylformamide and the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Electroanalysis 16(11):888–896
Buzzeo MC, Klymenko OV, Wadhawan JD, Hardacre C, Seddon KR, Compton RG (2004c) Kinetic analysis of the reaction between electrogenerated superoxide and carbon dioxide in the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and hexyltriethylammonium bis(trifluoromethylsulfonyl)imide. J Phys Chem B 108:3947–3954
Buzzeo M, Hardacre C, Compton RG (2004d) Use of room temperature ionic liquids in gas sensor design. Anal Chem 76:4583–4588
Cai Q, Xian YZ, Li H, Zhang YM, Tang J, Jin LT (2001) Studies on a sulfur dioxide electrochemical sensor with ionic liquid as electrolyte. Huadong Shifan Daxue Xuebao, Ziran Kexueban 2001(3):57–60
Demus D, Goodby J, Gray GW, Spiess H-W, Vill V (eds) (1998) Handbook of liquid crystals. Wiley, Weinheim, Vol. 1, Chap. 2, pp. 18–19
Dossi N, Toniolo R, Pizzariello A, Carrilho E, Piccin E, Battiston S, Bontempelli G (2012) An electrochemical gas sensor based on paper supported room temperature ionic liquids. Lab Chip 12:153–158
Earle MJ, Seddon KR (2000) Ionic liquids. Green solvents for the future. Pure Appl Chem 72(7):1391–1398
Fletcher KA, Pandey S, Storey IK, Hendricks AE, Pandey S (2002) Selective fluorescence quenching of polycyclic aromatic hydrocarbons by nitromethane within room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. Anal Chim Acta 453:89–96
Forzani ES, Lu D, Leright MJ, Aguilar AD, Tsow F, Iglesias RA, Zhang Q, Lu J, Li J, Tao N (2009) A hybrid electrochemical-colorimetric sensing platform for detection of explosives. J Am Chem Soc 131:1390–1391
Giovanelli D, Buzzeo MC, Lawrence NS, Hardacre C, Seddon KR, Compton RG (2004) Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Talanta 62:904–911
Goubaidoulline I, Vidrich G, Johannsmann D (2005) Organic vapor sensing with ionic liquids entrapped in alumina nanopores on quartz crystal resonators. Anal Chem 77:615–619
Hu C, Bai X, Wang Y, Jin W, Zhang X, Hu S (2012) Inkjet printing of nanoporous gold electrode arrays on cellulose membranes for high-sensitive paper-like electrochemical oxygen sensors using ionic liquid electrolytes. Anal Chem 84:3745–3750
Huang X-J, Silvester DS, Streeter I, Aldous L, Hardacre C, Compton RG (2008) Electroreduction of chlorine gas at platinum electrodes in several room temperature ionic liquids: evidence of strong adsorption on the electrode surface revealed by unusual voltammetry in which currents decrease with increasing voltage scan rates. J Phys Chem C 112:19477–19483
Huang XJ, Aldous L, O’Mahony AM, del Campo FJ, Compton RG (2010) Toward membrane-free amperometric gas sensors: a microelectrode array approach. Anal Chem 82:5238–5245
Huddleston JG, Visser AE, Reichert WM, Willauer HD, Broker GA, Rogers RD (2001) Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation. Green Chem 3(4):156–164
Jiang YY, Zhou Z, Jiao Z, Li L, Wu YT, Zhang ZB (2007) SO2 gas separation using supported ionic liquid membranes. J Phys Chem B 111:5058–5061
Jin X, Yu L, Garcia D, Ren RX, Zeng X (2006) Ionic liquid high temperature gas sensor array. Anal Chem 78:6980–6989
Jin H, Baker GA, Arzhantsev S, Dong J, Maroncelli M (2007) Survey of solvation and rotational dynamics of Coumarin 153 in a broad range of ionic liquids and comparisons to conventional solvents. J Phys Chem B 111:7291–7302
Kou Y, Xiong W, Tao G, Liu H, Wang T (2006) Absorption and capture of methane into ionic liquid. J Nat Gas Chem 15:282–286
Kroon MC, Buijs W, Peters CJ, Witkamp GJ (2007) Quantum chemical aided prediction of the thermal decomposition mechanisms and temperatures of ionic liquids. Thermochim Acta 465(1–2):40–47
Lee YG, Chou TC (2004) Ionic liquid ethanol sensor. Biosens Bioelectron 20(1):33–40
Liang C, Yuan CY, Warmack RJ, Barnes CE, Dai S (2002) Ionic liquids: a new class of sensing materials for detection of organic vapors based on the use of a quartz crystal microbalance. Anal Chem 74:2172–2176
Mank M, Stahl B, Boehm G (2004) 2,5-Dihydroxybenzoic acid butylamine and other ionic liquid matrixes for enhanced MALDI-MS analysis of biomolecules. Anal Chem 76:2938–2950
Mantz AR, Trulove PC (2003) Physicochemical properties of ionic liquids. In: Wasserscheid P, Welton T (eds) Ionic liquids in synthesis. Wiley, Berlin, pp 75–143
O’Mahony AM, Silvester DS, Aldous L, Hardacre C, Compton RG (2008) The electrochemical reduction of hydrogen sulfide on platinum in several room temperature ionic liquids. J Phys Chem C 112:7725–7730
Oter O, Ertekin K, Topkaya D, Alp A (2006a) Room temperature ionic liquids as optical sensor matrix materials for gaseous and dissolved CO2. Sens Actuators B Chem 117:295–301
Oter O, Ertekin K, Topkaya D, Alp S (2006b) Emission-based optical carbon dioxide sensing with HPTS in green chemistry reagents: room-temperature ionic liquids. Anal Bioanal Chem 386:1225–1234
Oter O, Ertekin K, Derinkuyu S (2008) Ratiometric sensing of CO2 in ionic liquid modified ethyl cellulose matrix. Talanta 76:557–563
Oter O, Ertekin K, Derinkuyu S (2009) Photophysical and optical oxygen sensing properties of tris(bipyridine)ruthenium(II) in ionic liquid modified sol–gel matrix. Mater Chem Phys 113:322–328
Peng JF, Liu JF, Hu XL, Jiang GB (2007) Direct determination of chlorophenols in environmental water samples by hollow fiber supported ionic liquid membrane extraction coupled with high-performance liquid chromatography. J Chromatogr A 1139:165–170
Pinkert A, Marsh KN, Pang S, Staiger MP (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728
Qi S, Cui S, Cheng Y, Chen X, Hu Z (2006) Rapid separation and determination of aconitine alkaloids in traditional Chinese herbs by capillary electrophoresis using 1-butyl-3-methylimidazoium-based ionic liquid as running electrolyte. Biomed Chromatogr 20:294–300
Rogers EI, Silvester DS, Poole DL, Aldous L, Hardacre C, Compton RG (2008) Voltammetric characterization of the ferrocene|ferrocenium and cobaltocenium|cobaltocene redox couples in RTILs. J Phys Chem C 112:2729–2735
Scott MP, Brazel CS, Benton MG, Mays JW, Holbrey JD, Rogers RD (2002) Application of ionic liquids as plasticizers for poly(methyl methacrylate). Chem Commun 2002:1370–1371
Seddon KR (1997) Ionic liquids for clean technology. J Chem Tech Biotechnol 68:315–316
Seddon KR, Stark A, Torres MJ (2000) Influence of chloride, water, and organic solvents on the physical properties of ionic liquids. Pure Appl Chem 72:2275–2287
Seddon KR, Stark A, Torres MJ (2002) Viscosity and density of 1-alkyl-3-methylimidazolium ionic liquids. ACS Symp Ser 819:34–49
Seyama M, Iwasaki Y, Tate A, Sugimoto I (2006) Room-temperature ionic-liquid-incorporated plasma-deposited thin films for discriminative alcohol-vapor sensing. Chem Mater 18(11):2656–2662
Silvester DS, Compton RG (2006) Electrochemistry in room temperature ionic liquids: a review and some possible applications. Z Phys Chem (N F) 220:1247–1274
Silvester DS, Ward KR, Aldous L, Hardacre C, Compton RG (2008a) The electrochemical oxidation of hydrogen at activated platinum electrodes in room temperature ionic liquids as solvents. J Electroanal Chem 618:53–60
Silvester DS, Rogers EI, Compton RG, McKenzie KJ, Ryder KS, Endres F, MacFarlane D, Abbott AP (2008b) Reference electrodes for use in room-temperature ionic liquids. In: Endres F, MacFarlane DR, Abbot A (eds) Electrodeposition from ionic liquids. Wiley, Weinheim, pp 296–309
Silvester DS (2011) Recent advances in the use of ionic liquids for electrochemical sensing. Analyst 136:4871–4882
Singh VV, Nigam AK, Batra A, Boopathi M, Singh B, Vijayaraghavan R (2012) Applications of ionic liquids in electrochemical sensors and biosensors. Int J Electrochem 2012:165683
Stetter JR, Korotcenkov G, Zeng X, Liu Y, Tang Y (2011) Electrochemical gas sensors: fundamentals, fabrication and parameters. In: Korotcenkov G (ed) Chemical sensors: comprehensive sensor technologies, vol 5, Electrochemical and optical sensors. Momentum Press, New York, pp 1–89
Sun P, Armstrong DW (2010) Ionic liquids in analytical chemistry. Anal Chim Acta 661:1–16
Wang R, Okajima T, Kitamura F, Ohsaka T (2004) A novel amperometric O2 gas sensor based on supported room-temperature ionic liquid porous polyethylene membrane-coated electrodes. Electroanalysis 16:66–72
Wang Z, Lin P, Baker GA, Stetter J, Zeng X (2011) Ionic liquids as electrolytes for the development of a robust amperometric oxygen sensor. Anal Chem 83:7066–7073
Wasserschied P, Welton T (2003) Ionic liquids in synthesis. Wiley, Weinheim
Wei D, Ivaska A (2008) Applications of ionic liquids in electrochemical sensors. Anal Chim Acta 607:126–135
Welton T (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem Rev 99:2071–2084
Xiong SQ, Wei Y, Guo Z, Chen X, Wang J, Liu JH, Huang XJ (2011) Toward membrane-free amperometric gas sensors: an ionic liquid–nanoparticle composite approach. J Phys Chem C 115:17471–17478
Yu L, Diego G, Ren XR, Zeng X (2005) Ionic liquid high temperature gas sensors. Chem Commun 2005:2277–2279
Yu L, Jin X, Zeng X (2008) Methane interactions with polyaniline/butylmethylimidazolium camphorsulfonate ionic liquid composite. Langmuir 24:11631–11636
Zevenbergen MAG, Wouters D, Dam VAT, Brongersma SH, Crego-Calama M (2011) Electrochemical sensing of ethylene employing a thin ionic-liquid layer. Anal Chem 83:6300–6307
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Science+Business Media New York
About this chapter
Cite this chapter
Korotcenkov, G. (2014). Ionic Liquids in Gas Sensors. In: Handbook of Gas Sensor Materials. Integrated Analytical Systems. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-7388-6_7
Download citation
DOI: https://doi.org/10.1007/978-1-4614-7388-6_7
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4614-7387-9
Online ISBN: 978-1-4614-7388-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)