Abstract
The electrospray (ES) process is the action of liquid dispersion into a fine aerosol, a phenomenon that takes place when a strong electric field is exerted on the liquid. The electrical atomization of liquids was first observed by George Bose in 1745 [1,2]. Rayleigh determined an instability criterion for charged liquid droplets in 1882 [3]. In 1917, Zeleny established a criterion for the instability of an electrified liquid at the end of a capillary tube [4].
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References
Hogan JJ, Hendricks CD (1965) AIAA J 3:296
Drozin VDJ (1955) J Colloid Sci 10:158
Rayleigh L (1882) Phil Mag 14:184
Zeleny J (1917) Phys Rev 10:1
Fenn J, Mann M, Meng C, Wong S, Whitehouse C (1989) Science 246:64
Fenn JB, Mann M, Meng CK, Wong SF, Whitehouse CM (1990) Mass Spectrom Rev 9:37
Mann M (1990) Org Mass Spectrom 25:575
Cole RB (ed) (2010) Electrospray and MALDI mass spectrometry. Wiley, New York
Serway RA (1992) Physics for scientists and engineers, 3rd edn. Saunders College Publishing, Philadelphia
Eyring CF, Mackeown SS, Millikan RA (1928) Phys Rev 31:900
Loeb LB, Kip AF, Hudson GG, Bennett WH (1941) Phys Rev 60:714
Pfeifer RJ, Hendricks CD (1968) AIAA J 6:496
Kebarle P, Tang L (1993) Anal Chem 65:972A
Hiraoka K (1992) Rapid Commun Mass Spectrom 6:463
Hiraoka K, Fukasawa H, Aizawa K (1995) Rapid Commun Mass Spectrom 9:1349
Niessen WMA (1998) J Chromatogr A 794:407
Constantopoulos TL, Jackson GS, Enke CG (1999) J Am Soc Mass Spectrom 10:625
Taylor G (1964) Proc Roy Soc Lond Ser A 280:392
Wilm MS, Mann M (1994) Int J Mass Spectrom Ion Processes 136:167
Chen LC, Yu Z, Nonami H, Hashimoto Y, Hiraoka K (2009) Environ Control Biol 47:73
Marginean I, Parvin L, Hefferman L, Vertes A (2004) Anal Chem 76:4202
Fernandez de la Mora J, Locertales IG (1994) J Fluid Mech 243:561
Rossel J, Leiompart IG, Fernandez de la Mora J (1994) J Aerosol Sci 25:1093
Gomez A, Tang K (1994) Phys Fluids 6:404
Kebarle P, Ho Y (1997) In: Cole RB (ed) Electrospray ionization mass spectrometry. Wiley, New York
Cech NB, Enke CG (2010) In: Cole RB (ed) Electrospray and MALDI mass spectrometry. Wiley, New York
Dole M, Mack LL, Hines RL, Mobley RC, Ferguson LD, Alice MB (1968) J Chem Phys 49:2240
Schmelzeisen-Redeker Butfering GL, Röllgen FW (1989) Int J Mass Spectrom Ion Processes 90:139
Irribarne JV, Thomson BA (1976) J Chem Phys 64:2287
Thomson BA, Iribarne JV (1979) J Phys Chem 71:4451
Kebarle P, Verkerk UH (2010) In: Cole RB (ed) Electrospray and MALDI mass spectrometry. Wiley, New York
Bruins AP, Covey TR, Henion JD (1987) Anal Chem 59:2642
Takamizawa A, Fujimaki S, Sunner J, Hiraoka K (2005) J Am Soc Mass Spectrom 16:860
Takamizawa A, Maeda H, Kambara S, Furuya H, Hiraoka K (2008) Rapid Commun Mass Spectrom 22:2453
Shi X, Takamizawa A, Nishimura Y, Hiraoka K, Akashi S (2008) Rapid Commun Mass Spectrom 22:1430
Shi X, Nishimura Y, Akashi S, Takamizawa A, Hiraoka K (2006) J Am Soc Mass Spectrom 17:611
Shi X, Takamizawa A, Nishimura Y, Hiraoka K, Akashi S (2006) J Mass Spectrom 41:1086
Akashi S, Shi X, Takamizawa A, Nishimura Y, Hiraoka K (2008) J Mass Spectrom Soc Jpn 56:155
Wilm M, Mann M (1996) Anal Chem 68:1
Hiraoka K, Nishidate K, Mori K, Asakawa D, Suzuki S (2007) Rapid Commun Mass Spectrom 21:3139
Chen LC, Nishidate K, Saito Y, Mori K, Asakawa D, Takeda S, Kubota T, Terada N, Hashimoto Y, Hori H, Hiraoka K (2008) Rapid Commun Mass Spectrom 22:2366
Chen LC, Nishidate K, Saito Y, Mori K, Asakawa D, Takeda S, Kubota T, Hori H, Hiraoka K (2008) J Phys Chem B 112:11164
Hiraoka K, Chen LC, Asakawa D, Takeda S, Kubota T (2009) J Surf Anal 15:279
Chen LC, Yoshimura K, Yu Z, Iwata R, Itoh H, Suzuki H, Mori K, Ariyada O, Takeda S, Kubota T, Hiraoka K (2009) J Mass Spectrom 44:1469
Mandal MK, Chen LC, Hashimoto Y, Yu Z, Hiraoka K (2010) Anal Methods 2:1905
Mandal MK, Chen LC, Yu Z, Nonami H, Erra-Balsells R, Hiraoka K (2011) J Mass Spectrom 46:967
Mandal MK, Chen LC, Hiraoka K (2011) J Am Soc Mass Spectrom 22:1493
Adamson AW (1990) Physical chemistry of surfaces, 5th edn. Wiley, New York
Chen LC, Mandal MK, Hiraoka K (2011) J Am Soc Mass Spectrom 22:539
Chen LC, Mandal MK, Hiraoka K (2011) J Am Soc Mass Spectrom 22:2108
Atkins PW (1986) Physical chemistry, 3rd edn. Oxford University Press, Oxford
McEwen CN, Larsen BS (1997) In: Cole RB (ed) Electrospray ionization mass spectrometry. Wiley, New York
Gross JH (2011) Mass spectrometry, a textbook, 2nd edn. Springer, Berlin
Wahl JH, Goodlet DR, Udseth HR, Smith RD (1992) Anal Chem 64:3194
Emmenett MR, Caprioli RM (1994) J Am Soc Mass Spectrom 5:605
Yoshimura K, Chen LC, Asakawa D, Hiraoka K, Takeda S (2009) J Mass Spectrom 44:978
Loscertales IG, Fernandez de la Mora J (1995) J Chem Phys 103:5041
Jackson SN, Ugarov M, Egan T, Post JD, Langlais D, Schultz JA, Woods AS (2007) J Mass Spectrom 42:1093
Taira S, Sugiura Y, Moritake S, Shimma S, Ichiyanagi Y, Setou M (2008) Anal Chem 80:4761
Müller EW (1953) Ergebnisse der Exakten Naturwissenschaften 27:290
Beckey HD (1977) Principles of field ionization and field desorption mass spectrometry. Pergamon Press, Oxford
Wong SS, Giessmann U, Karas M, Röllgen FW (1984) Int J Mass Spectrom Ion Processes 56:139
Sen AK, Darabi J, Knapp DR, Liu J (2006) J Micromech Microeng 16:620
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Hiraoka, K. (2013). Fundamentals of Electrospray. In: Hiraoka, K. (eds) Fundamentals of Mass Spectrometry. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-7233-9_8
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DOI: https://doi.org/10.1007/978-1-4614-7233-9_8
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