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Design of New Elastomeric Matrix Composites: Comparison of Mechanical Properties and Determining Viscoelastic Parameters via Continuous Micro Indentation

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Composite Materials and Joining Technologies for Composites, Volume 7

Abstract

The aim of this study is to compare the influence of vulcanizates strategy on the mechanical properties and viscoelastic behaviour of the new elastomeric based composites based on NR/BR compound that we try actually to design the new compositions in order to improve the new family of elastomeric composites used extensively in engineering applications.

Essentially the basic mixture of NR/BR based elastomeric composites with different vulcanization temperatures and curing systems containing different filler s and reinforcements were characterized (for example in two vulcanizates: 140°C and 160°C) and to compare their tensile properties and viscoelastic behaviours were determined using of micro indentation technique that is a more reliable and efficient tool for practical applications.

Essentially, in detail with the elastic indentation load-depth model at the maximum indentation load describes the indentation depth versus time curves quite well for the four different compounds of elastomeric based composites. It is hoped that these parameters may be used in the evaluation and development of more strong and long lasting elastomeric composites. It was also observed that the model describes the indentation depth versus time curves very well for the mixture of NR/BR elastomeric composite sheets.

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References

  1. Siqueira Filho AS, Bo MC (1985) Controle de Qualidade na Indu stria de Artefatos de Borracha, Manuais CNI

    Google Scholar 

  2. Klei B, Koenig JL (1997) The competitive vulcanization of natural rubber and polybutadiene blends. Rubber Chem Technol 70:231–238

    Article  Google Scholar 

  3. Thorn A.D., Robinson R.A. (1994) Compound design. In: Rubber products manufacturing technology. Marcel Dekker, New York, p 1, Chap. 1

    Google Scholar 

  4. Brydson J.A. (1988) Natural rubber. In: Rubber materials and their compounds. Elsevier Science, New York, p 69, Chap. 4

    Google Scholar 

  5. Kohl JG, Singer IL, Simonson DL (2008) Determining the viscoelastic parameters of thin elastomer based materials using continuous micro indentation. Polym Test 27(6):679–682

    Article  Google Scholar 

  6. Eng A.H., Ong E.L. (2001) Hevea natural rubber. In: Bhowmick AK, Stephens HL (eds) Handbook of elastomers, 2nd edn. Marcel dekker, New York

    Google Scholar 

  7. Bloomfield GF (1967) New forms of natural rubber. In: Brydson JA (ed) Developments with natural rubber. Maclaren & Sons, London

    Google Scholar 

  8. Ciesielski A. (1999) Types of rubber and their essential properties. In: An introduction to rubber technology, Rapra Technology Limited, Shawbury, Shrewsbury, Shropshire

    Google Scholar 

  9. Andrews EH, Gent AN (1963) Crystallization in natural rubber. In: Bateman L (ed) The chemistry and physics of rubber like substances. Wiley, New York

    Google Scholar 

  10. Fischer-Cripps AC (2004) A simple phenomenological approach to nanoindentation creep. Mater Sci Eng A 385:74–82

    Article  Google Scholar 

  11. Nyburg SC (1945) X-ray determination of crystallinity in deformed natural rubber. Br J Appl Phys 5:321

    Article  Google Scholar 

  12. Kohl JG, Bolstes RN (2001) A study on the elastic modulus of silicone duplex or bi-layer coatings using micro-indentation. Prog Org Coating 41:135–141

    Article  Google Scholar 

  13. Subramaniam A (1987) Natural rubber. In: Morton M (ed) Rubber technology, 3rd edn. Van Nostrand Reinhold Company, New York

    Google Scholar 

  14. Gent AN, Razzaghi-Kashani M, Hamed GR (2003) Why do cracks turn sideways? Rubber Chem Technol 76:122

    Article  Google Scholar 

  15. Hamed GR, Al-Sheneper AA (2003) Effect of carbon black concentration on cut growth in NR Vulcanizates. Rubber Chem Technol 76:436

    Article  Google Scholar 

  16. Kohl JG, Singer IL (1999) Pull-off behavior of epoxy bonded to silicone duplex coatings. Prog Org Coating 36:15–20

    Article  Google Scholar 

  17. Hofmann A. (1988) Natural rubber. In: Rubber technology handbook. Hanser Publishers, New York

    Google Scholar 

  18. Nielsen LE, Landel LE (1994) Mechanical properties of polymers and composites, 2nd edn. Marcel Dekker, New York

    Google Scholar 

  19. Chapman AV, Porter M (1988) In: Roberts AD (ed) Natural rubber science and technology. Oxford Scientific, New York, Chap. 12

    Google Scholar 

  20. Singer IL, Kohl JG, Patterson M (2000) Mechanical aspects of silicone coatings for hard foulant control. Biofouling 16:301–309

    Article  Google Scholar 

  21. Brady RF, Singer IL (2000) Mechanical factors favoring release from fouling release coatings. Biofouling 15:73–82

    Article  Google Scholar 

  22. Oliver WC, Pharr GM (1992) An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res 7:1564–1583

    Article  Google Scholar 

  23. Kohl JG, Singer IL, Schwarzer N, Yu VY (2006) Effect of bond coat modulus on the durability of silicone duplex coatings. Progr Org Coating 56:220–226

    Article  Google Scholar 

  24. Ngan AHW, Wang HT, Tang B, Sze KY (2005) Correcting power-law viscoelastic effects in elastic modulus measurement using depth-sensing indentation. Int J Solids Struct 42:1831–1846

    Article  MATH  Google Scholar 

  25. Kohl JG, Singer IL, Griffith JR (2000) Evaluating the durability of silicone duplex coatings using a scratch tester. Rubber Chem Technol 73:607–618

    Article  Google Scholar 

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Correspondence to E. Bayraktar .

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Zaimova, D., Bayraktar, E., Berthout, G., Dishovsky, N. (2013). Design of New Elastomeric Matrix Composites: Comparison of Mechanical Properties and Determining Viscoelastic Parameters via Continuous Micro Indentation. In: Patterson, E., Backman, D., Cloud, G. (eds) Composite Materials and Joining Technologies for Composites, Volume 7. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-4553-1_24

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  • DOI: https://doi.org/10.1007/978-1-4614-4553-1_24

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  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4614-4552-4

  • Online ISBN: 978-1-4614-4553-1

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