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Electrodeposition of Copper Powders and Their Properties

  • Nebojša D. Nikolić
  • Konstantin I. Popov
Chapter
Part of the Modern Aspects of Electrochemistry book series (MAOE, volume 54)

Abstract

A powder is a finely divided solid, smaller than 1,000 μm in its maximum dimension. A particle is defined as the smallest unit of a powder. The particles of a powder may assume various forms and sizes, whereas powders, an association of such particles, exhibit, more or less, the same characteristics as if they were formed under identical conditions and if the manipulation of the deposits after removal from the electrode was the same [1, 2]. The size of particles of many metal powders can vary in a quite wide range from a few nanometers to several hundreds of micrometers. The most important properties of a metal powder are the specific surface, the apparent density, the flowability, and the particle grain size and distribution. These properties, called decisive properties, characterize the behavior of a metal powder.

Keywords

Hydrogen Evolution Copper Powder Hydrogen Evolution Reaction Pause Duration Particle Size Distribution Curve 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors are grateful to Dr. Goran Branković and Dr. Ljubica Pavlović for SEM analysis of investigated systems, as well as to Dr. Snežana Krstić and Dr. Miomir Pavlović for helpful discussions.

The work was supported by the Ministry of Education and Science of the Republic of Serbia under the research project “Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies” (No. 172046).

References

  1. 1.
    German RM (1994) Powder metallurgy science, 2nd edn. Metal Powder Industries Federation, Princeton, NJGoogle Scholar
  2. 2.
    Pavlović MG, Popov KI (2005) Electrochemistry encyclopedia. http://electrochem.cwru.edu/ed/encycl/
  3. 3.
    Calusaru A (1979) Electrodeposition of metal powders, Materials science monographs. Elsevier, New YorkGoogle Scholar
  4. 4.
    Orhan G, Hapci G (2010) Powder Technol 201:57CrossRefGoogle Scholar
  5. 5.
    Popov KI, Djokić SS, Grgur BN (2002) Fundamental aspects of electrometallurgy. Kluwer Academic/Plenum, New YorkGoogle Scholar
  6. 6.
    Popov KI, Pavlović MG (1993) Electrodeposition of metal powders with controlled grain size and morphology. In: White RE, Bockris JO’M, Conway BE (eds) Modern aspects of electrochemistry, vol 24. Plenum, New York, pp 299–391CrossRefGoogle Scholar
  7. 7.
    Hirakoso K (1935) Denkikogaku Kyokoishi 3:7Google Scholar
  8. 8.
    Hirakoso K (1935) Chem Abst 29:5749uGoogle Scholar
  9. 9.
    Ibl N (1962) Advances in electrochemistry and electrochemical engineering, vol 2. Interscience, New YorkGoogle Scholar
  10. 10.
    Ibl N (1954) Helv Chim Acta 37:1149CrossRefGoogle Scholar
  11. 11.
    Kudra O, Lerner ME (1951) Ukrain Khim Zh 17:890Google Scholar
  12. 12.
    Kudra O, Gitman E (1952) Elektroliticheskoe Poluchenie Metallicheskiekh Poroshkov, Izd. Akad. Nauk Ukr. SSR, KievGoogle Scholar
  13. 13.
    Ibl N, Schadegg K (1967) J Electrochem Soc 114:54CrossRefGoogle Scholar
  14. 14.
    Calusaru A (1957) Revista de Chemie Bucuresti 8:369Google Scholar
  15. 15.
    Atanasiu I, Calusaru A (1957) Studii Cercet Met Bucuresti 2:237Google Scholar
  16. 16.
    Russev D (1981) J Appl Electrochem 11:177CrossRefGoogle Scholar
  17. 17.
    Theis G, Fassler C, Robertson PM, Dossenbach O, Ibl N (1981) 32nd ISEMeeting, Dubrovnik/Cavtat, vol 1, p 383Google Scholar
  18. 18.
    Popov KI, Maksimović MD, Trnjančev JD, Pavlović MG (1981) J Appl Electrochem 11:239CrossRefGoogle Scholar
  19. 19.
    Barton JL, Bockris JO’M (1962) Proc Roy Soc A268:485Google Scholar
  20. 20.
    Maksimović MD, Popov KI, Pavlović MG (1979) Bull Soc Chim 44:687Google Scholar
  21. 21.
    Maksimović MD, Popov KI, Jović LjJ, Pavlović MG (1979) Bull Soc Chim 44:47Google Scholar
  22. 22.
    Krichmar SI (1965) Electrokhim 1:609Google Scholar
  23. 23.
    Diggle JW, Despić AR, Bockris JO’M (1969) J Electrochem Soc 116:1503CrossRefGoogle Scholar
  24. 24.
    Despić AR, Diggle JW, Bockris JO’M (1968) J Electrochem Soc 115:507CrossRefGoogle Scholar
  25. 25.
    Popov KI, Despić AR (1971) Bull Soc Chim 36:173Google Scholar
  26. 26.
    Despić AR (1970) Croat Chim Acta 42:265Google Scholar
  27. 27.
    Despić AR, Popov KI (1972) Transport controlled deposition and dissolution of metals. In: Conway BE, Bockris JO’M (eds) Modern aspects of electrochemistry, vol 7. Plenum, New York, pp 199–313Google Scholar
  28. 28.
    Popov KI, Pavlović MG, Maksimović MD (1982) J Appl Electrochem 12:525CrossRefGoogle Scholar
  29. 29.
    Popov KI, Krstajić NV, Čekerevac MI (1996) The mechanism of formation of coarse and disperse electrodeposits. In: White RE, Conway BE, Bockris JO’M (eds) Modern aspects of electrochemistry, vol 30. Plenum, New York, pp 261–312Google Scholar
  30. 30.
    Nikolić ND, Popov KI, Pavlović LjJ, Pavlović MG (2006) J Electroanal Chem 588:88CrossRefGoogle Scholar
  31. 31.
    Nikolić ND, Popov KI, Pavlović LjJ, Pavlović MG (2007) Sensors 7:1CrossRefGoogle Scholar
  32. 32.
    Nikolić ND, Pavlović LjJ, Pavlović MG, Popov KI (2008) Powder Technol 185:195CrossRefGoogle Scholar
  33. 33.
    Lowenheim FA (1978) Electroplating. McGraw-Hill Book, New York, St. LouisGoogle Scholar
  34. 34.
    Wolery TJ (1992) EQ3NR – a computer program for geochemical aqueous speciation-solubility calculations: theoretical manual and user’s guide, version 7.0. Lawrence Livermore National Laboratory, Livermore, CAGoogle Scholar
  35. 35.
    Roine A (1999) HSC chemistry: chemical reaction and equilibrium software with extensive thermochemical database. 4.0. Outokumpu Research Oy, FinlandGoogle Scholar
  36. 36.
    Casas JM, Alvarez F, Cifuentes L (2000) Chem Eng Sci 55:6223CrossRefGoogle Scholar
  37. 37.
    Pitzer KS (1991) Activity coefficients in electrolyte solutions, 2nd edn. CRC, Boca Raton, FLGoogle Scholar
  38. 38.
    Nikolić ND, Popov KI (2010) Hydrogen co-deposition effects on the structure of electrodeposited copper. In: Djokić SS (ed) Electrodeposition: theory and practice. Modern aspects of electrochemistry, vol 48. Springer, Berlin, pp 1–70Google Scholar
  39. 39.
    Nikolić ND, Pavlović LjJ, Krstić SB, Pavlović MG, Popov KI (2008) Chem Eng Sci 63:2824CrossRefGoogle Scholar
  40. 40.
    Nikolić ND, Pavlović LjJ, Branković G, Pavlović MG, Popov KI (2008) J Serb Chem Soc 73:753CrossRefGoogle Scholar
  41. 41.
    Nikolić ND, Branković G, Pavlović MG, Popov KI (2008) J Electroanal Chem 621:13CrossRefGoogle Scholar
  42. 42.
    Nikolić ND, Pavlović LjJ, Pavlović MG, Popov KI (2007) Electrochim Acta 52:8096CrossRefGoogle Scholar
  43. 43.
    Popov KI, Maksimović MD (1989) Theory of the effect of electrodeposition at periodically changing rate on the morphology of metal deposition. In: Conway BE, Bockris JO’M, White RE (eds) Modern aspects of electrochemistry, vol 19. Plenum, New York, pp 193–250Google Scholar
  44. 44.
    Li Y, Jia W-Z, Song Y-Y, Xia XH (2007) Chem Mater 19:5758CrossRefGoogle Scholar
  45. 45.
    Shin H-C, Liu M (2004) Chem Mater 16:5460CrossRefGoogle Scholar
  46. 46.
    Kim J-H, Kim R-H, Kwon H-S (2008) Electrochem Commun 10:1148CrossRefGoogle Scholar
  47. 47.
    Nikolić ND, Branković G (2010) Electrochem Commun 12:740CrossRefGoogle Scholar
  48. 48.
    Shin H-C, Dong J, Liu M (2003) Adv Mater 15:1610CrossRefGoogle Scholar
  49. 49.
    Everhart JL (n.d) Copper and copper alloy powder metallurgy properties and applications. http://www.copper.org/resources/properties/129_6/homepage.html
  50. 50.
    Walker R, Duncan SJ (1984) Surf Technol 23:301CrossRefGoogle Scholar
  51. 51.
    Maksimović VM, Pavlović LjJ, Pavlović MG, Tomić MV (2009) J Appl Electrochem 39:2545CrossRefGoogle Scholar
  52. 52.
    Owais A (2009) J Appl Electrochem 39:1587CrossRefGoogle Scholar
  53. 53.
    Pavlović MG, Pavlović LjJ, Maksimović VM, Nikolić ND, Popov KI (2010) Int J Electrochem Sci 5:1862Google Scholar
  54. 54.
    Djokić SS, Nikolić ND, Živković PM, Popov KI, Djokić NS (2011) ECS Trans 33:7CrossRefGoogle Scholar
  55. 55.
    Nikolić ND, Branković G, Pavlović MG (2012) Powder Technol. http://dx.doi.org/10.1016/j.powtec.2012.01.014
  56. 56.
    Nikolić ND, Branković G, Maksimović VM, Pavlović MG, Popov KI (2009) J Electroanal Chem 635:111CrossRefGoogle Scholar
  57. 57.
    Nikolić ND, Popov KI, Pavlović LjJ, Pavlović MG (2007) J Solid State Electrochem 11:667CrossRefGoogle Scholar
  58. 58.
    Popov KI, Nikolić ND, Rakočević Z (2002) J Serb Chem Soc 67:635CrossRefGoogle Scholar
  59. 59.
    Popov KI, Nikolić ND, Rakočević Z (2002) J Serb Chem Soc 67:769CrossRefGoogle Scholar
  60. 60.
    Nikolić ND, Krstić SB, Pavlović LjJ, Pavlović MG, Popov KI (2008) The mutual relation of decisive characteristics of electrolytic copper powder and effect of deposition conditions on them. In: Hayashi K (ed) Electroanalytical chemistry research trends. Nova, New York, pp 185–209Google Scholar
  61. 61.
    Pavlović MG, Pavlović LjJ, Ivanović ER, Radmilović V, Popov KI (2001) J Serb Chem Soc 66:923Google Scholar
  62. 62.
    Popov KI, Pavlović LjJ, Ivanović ER, Radmilović V, Pavlović MG (2002) J Serb Chem Soc 67:61CrossRefGoogle Scholar
  63. 63.
    Popov KI, Nikolić ND, Rakočević Z (2002) J Serb Chem Soc 67:861CrossRefGoogle Scholar
  64. 64.
    Popov KI, Krstić SB, Pavlović MG (2003) J Serb Chem Soc 68:511CrossRefGoogle Scholar
  65. 65.
    Popov KI, Krstić SB, Obradović MČ, Pavlović MG, Pavlović LjJ, Ivanović ER (2003) J Serb Chem Soc 68:771CrossRefGoogle Scholar
  66. 66.
    Popov KI, Pavlović MG, Pavlović LjJ, Ivanović ER, Krstić SB, Obradović MČ (2003) J Serb Chem Soc 68:779CrossRefGoogle Scholar
  67. 67.
    Popov KI, Živković PM, Krstić SB (2003) J Serb Chem Soc 68:903CrossRefGoogle Scholar
  68. 68.
    Popov KI, Krstić SB, Obradović MČ, Pavlović MG, Pavlović LjJ, Ivanović ER (2004) J Serb Chem Soc 69:43CrossRefGoogle Scholar
  69. 69.
    Popov KI, Krstić SB, Pavlović MG, Pavlović LjJ, Maksimović VM (2004) J Serb Chem Soc 69:817CrossRefGoogle Scholar
  70. 70.
    Popov KI, Nikolić ND, Krstić SB, Pavlović MG (2006) J Serb Chem Soc 71:397CrossRefGoogle Scholar
  71. 71.
    Nikolić ND, Popov KI, Pavlović LjJ, Pavlović MG (2007) Mater Prot 48:3 (in Serbian)Google Scholar
  72. 72.
    Pavlović MG, Nikolić ND, Popov KI (2003) J Serb Chem Soc 68:649CrossRefGoogle Scholar
  73. 73.
    Pavlović MG, Pavlović LjJ, Doroslovački ID, Nikolić ND (2004) Hydrometallurgy 73:155CrossRefGoogle Scholar
  74. 74.
    Popov KI, Pavlović LjJ, Pavlović MG, Čekerevac MI (1988) Surf Coat Technol 35:39CrossRefGoogle Scholar
  75. 75.
    Popov KI, Pavlović MG, Pavlović LjJ, Čekerevac MI, Remović GŽ (1988) Surf Coat Technol 34:355CrossRefGoogle Scholar
  76. 76.
    Popov KI, Maksimović MD, Pavlović MG, Lukić DT (1980) J Appl Electrochem 10:299CrossRefGoogle Scholar
  77. 77.
    Nikolić ND, Rakočević Z, Popov KI (2005) Nanostructural analysis of bright metal surfaces in relation to their reflectivities. In: Conway BE, Vayenas CG, White RE, Gamboa-Adelco ME (eds) Modern aspects of electrochemistry, vol 38. Kluwer Academic/Plenum, New York, pp 425–474Google Scholar
  78. 78.
    Nikolić ND, Rakočević Z, Popov KI (2001) J Electroanal Chem 514:56CrossRefGoogle Scholar
  79. 79.
    Nikolić ND, Popov KI, Pavlović LjJ, Pavlović MG (2006) Surf Coat Technol 201:560CrossRefGoogle Scholar
  80. 80.
    Chassaing E, Rosso M, Sapoval B, Chazalviel J-N (1993) Electrochim Acta 38:1941Google Scholar
  81. 81.
    Schatt W, Wierters KP (1997) Powder metallurgy – processing and materials. European Powder Metallurgy Association, Technical University Dresden, Dresden, p 8Google Scholar
  82. 82.
    Peissker E (1984) Int J Powder Metallurgy Powder Technol 20:87Google Scholar
  83. 83.
    Popov KI, Pavlović MG, Maksimović MD, Krstajić SS (1978) J Appl Electrochem 8:503CrossRefGoogle Scholar
  84. 84.
    Pavlović LjJ, Nikolić ND, Popov KI (2000) Mater Sci Forum 352:65CrossRefGoogle Scholar
  85. 85.
    Murashova I, Pomosov B (1989) In: Polukarov YuM (ed) Itogi nauki i tehniki, Seria Elektrokhimiya, vol 30. Acad. Sci., Moscow, p 90Google Scholar
  86. 86.
    Nikolić ND, Novaković G, Rakočević Z, Djurović DR, Popov KI (2002) Surf Coat Technol 161:188CrossRefGoogle Scholar
  87. 87.
    Nikolić ND, Rakočević Z, Popov KI (2004) J Solid State Electrochem 8:526CrossRefGoogle Scholar
  88. 88.
    Nikolić ND, Rakočević Z, Djurović DR, Popov KI (2006) Russ J Electrochem 42:112Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.ICTM-Institute of ElectrochemistryUniversity of BelgradeBelgradeSerbia
  2. 2.Faculty of Technology and MetallurgyUniversity of BelgradeBelgradeSerbia

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