Abstract
In addition to the algae-mediated process discussed in Chap. 7, to generate hydrocarbon-based fuels and useful chemicals from CO2, it is also possible to use electrochemical and photocatalytic processes to carry out CO2 reduction. As previously mentioned in Chap. 7, today, an even stronger policy driver than climate change is the expansion of alternatives to crude oil for transportation fuels. Another driver for advancing electrochemical and photocatalytic reduction of CO2 is that it may allow for the storage of stranded energy from resources such as wind, solar, tidal, and geothermal in the form of chemical energy within the bonds of hydrocarbons.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsNotes
- 1.
To form hydrocarbons from CO2 reduction, the source of hydrogen does not necessarily have to be water and may be of the form of H2, H3O +, etc.
References
O’hayre R, Cha SW, Colella W, Prinz FB (2009) Fuel cell fundamentals. John Wiley & Sons, Inc, New York
(a) Jaramillo TF, Jørgensen KP, Bonde J, Nielsen JH, Horch S, Chorkendorff I (2007) Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science 317(5834):100; (b) Surendranath Y, Kanan MW, Nocera DG (2010) Mechanistic studies of the Oxygen evolution reaction by a cobalt-phosphate catalyst at neutral pH. J Am Chem Soc 132;16501–16509; (c) Yeo BS, Klaus SL, Ross PN, Mathies RA, Bell AT (2010) Identification of hydroperoxy species as reaction intermediates in the electrochemical evolution of Oxygen on Gold. Chemphyschem 11;1854–1857; (d) Bell AT (2003) The impact of nanoscience on heterogeneous catalysis. Science 299(5613):1688; (e) Nann T, Ibrahim SK, Woi PM, Xu S, Ziegler J, Pickett CJ (2010) Water splitting by visible light: a nanophotocathode for hydrogen production Angew Chem Int Ed Engl 49(9):1574–1577; (f) Cowan AJ, Tang J, Leng W, Durrant JR, Klug DR (2010) Water Splitting by Nanocrystalline TiO2 in a complete photoelectrochemical cell exhibits efficiencies limited by charge recombination. J Phys Chem C 114(9):4208–4214
O’hayre R, Cha SW, Colella W, Prinz FB (2009) Fuel cell fundamentals, 2nd edn. John Wiley & Sons, Inc., New York
Bard AJ, Faulkner LR (2001) Electrochemical methods, fundamentals and applications, 2nd edn. John Wiley & Sons, Inc., New York
Strasser P, Ogasawara H (2008) Surface electrochemistry. In: chemical bonding at surfaces and interfaces Nilsson A, Pettersson L, Nörskov JK (eds). Elsevier, Amsterdam
(a) Whipple DT, Kenis PJA (2010) Prospects of CO2 Utilization via direct heterogeneous electrochemical reduction. J Phys Chem Lett 1:3451–3458; (b) Hori Y (2008) electrochemical CO2 reduction on metal electrodes. In: modern aspects of electrochemistry Vayenas CG, White RE, Gamboa-Aldeco ME (eds). Springer, New York, pp 89–189
(a) Benson EE, Kubiak CP, Sathrum AJ, Smieja JM (2008) Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. Chem Soc Rev 38(1):89–99; (b) Savéant JM (2008) Molecular catalysis of electrochemical reactions. Mechanistic aspects. Chem Rev 108(7):2348–2378
(a) Hori Y, Kikuchi K, Suzuki S (1985) Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution. Chem Lett (11):1695–1698; (b) Hori Y, Kikuchi K, Murata A, Suzuki S (1986) Production of methane and ethylene in electrochemical reduction of carbon dioxide at copper electrode in aqueous hydrogencarbonate solution. Chem Lett 15:897–898
Hori Y, Murata A, Takahashi R (1989) Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution. J Am Chem Soc Farad Trans 1 85:2309–2326
De Jesús-Cardona H, del Moral C, Cabrera CR (2001) Voltammetric study of CO2 reduction at Cu electrodes under different KHCO3 concentrations, temperatures and CO2 pressures. J Electroanal Chem 513(1):45–51
Arakawa H, Dubois JL, Sayama K (1992) Selective conversion of CO2 to Methanol by catalytic-hydrogenation over promoted copper catalyst. Energy Convers Manag 33(5–8):521–528
Peterson AA, Abild-Pedersen F, Studt F, Rossmeisl J, Norskov JK (2010) How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels. Energ Environ Sci 3 (9):1311–1315
Koci K, Obalova L, Lacny Z (2008) Photocatalytic reduction of CO2 over TiO2 based catalysts. Chem Pap 62(1):1–9
Wu JCS (2009) Photocatalytic reduction of greenhouse gas CO2 to fuel. Catal Surv Asia 13(1):30–40
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2012 Springer Science+Business Media, LLC
About this chapter
Cite this chapter
Wilcox, J. (2012). The Role of CO2 Reduction Catalysis in Carbon Capture. In: Carbon Capture. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-2215-0_8
Download citation
DOI: https://doi.org/10.1007/978-1-4614-2215-0_8
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4614-2214-3
Online ISBN: 978-1-4614-2215-0
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)