Abstract
In this chapter, the thermodynamics of self-healing is considered with an emphasis on metallic materials. All complex biological organisms have the ability to repair minor damage. Incorporating the self-repair function into inorganic systems is of growing interest for materials scientists. So far, most recent studies have concentrated on polymers and ceramics because it is easier to incorporate self-healing in nonmetallic materials than in metallic materials. However, metallic self-healing alloys and composites are of great practical importance. We review the design principles of self-healing materials using the nonequilibrium thermodynamics approach and the concept of hierarchical organization. The generalized thermodynamic force that leads to healing is induced by bringing the system away from thermodynamic equilibrium. We focus on the three major methods of imparting the ability for self-healing in metallic systems: precipitation-induced healing, embedding shape-memory alloys, and embedding a low-melting point alloy in the alloy matrix.
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Anderson, H.M., Keller, M.W., Moore, J.S., Sottos, H.R., White, S.R.: Self-healing polymers and composites. In: van der Zwaag, S. (ed.) Self Healing Materials – An Alternative Approach to 20 Centuries of Materials Science, pp. 19–44. Springer, Dordrecht, The Netherlands (2007)
Belko, V.O., Bondarenko, P.N., Emelyanov, O.A.: The dynamic characteristics of self-healing processes in metal film capacitors. Russ Electr Eng 78, 138–142 (2007)
Bender, M., Olson, G.B.: Computational thermodynamics-based design of nanodispersion-strengthened shape memory alloys. SMST-2007: Proceedings of International Conference on Shape Memory and Superelastic Technol., pp. 115–122. (2008).
Bond, I.P., Trask, R.S., Williams, H.R., Williams, J.R.: Self-healing fiber-reinforced polymer composites: an overview. In: van der Zwaag, S. (ed.) Self Healing Materials – An Alternative Approach to 20 Centuries of Materials Science, pp. 115–138. Springer, Dordrecht, The Netherlands (2007)
Brinson, L.C.: 1D constitutive behavior of shape memory alloys: thermomechanical derivation with non-constant materials functions and redefined martensite internal variable. J. Intelligent Mater Sys. Struct. 4, 229–242 (1993)
Bruck, H.A., Evans, J.J., Peterson, M.L.: The role of mechanics in biological and biologically-inspired materials. Exp Mech 42, 361–371 (2002)
Bryant, M.D., Khonsari, M.M., Ling, F.F.: On the thermodynamics of degradation. Proc. R. Soc. Lond. A 464, 2001–2014 (2008)
Buha, J., Lumley, R.N., Crosky, A.J., Hono, K.: Secondary precipitation in an Al-Mg-Si-Cu alloy. Acta Mater. 55, 3015–3024 (2007)
Burgess, S.C.: Reliability and safety strategies in living organisms: potential for biomimicking. J. Proc Inst. Mech Eng E 216, 1–13 (2002)
Burton, D.S., Gao, X., Brinson, L.C.: Finite element simulation of a self-healing shape memory alloy composite. Mech. Mater. 38, 525–537 (2006)
Chen, Q., Amano, R.S., Xin, M.: Experimental and computational study of R134A condensation heat transfer inside the micro-FIN tubes. Int. J. Heat Mass Transfer 41, 785–791 (2005)
Craig, N.: Entropy analysis: an introduction to chemical thermodynamics. VCH, New York (1992)
Dry, C.: Matrix cracking repair and filling using active and passive modes for smart timed release of chemicals from fibers into cement matrices. Smart Mater. Struct 3, 118–123 (1994)
Feng, Q.L., Cui, F.Z., Pu, G., Wang, R.Z., Li, H.D.: Crystal orientation, toughening mechanisms and a mimic of nacre. Mater. Sci. Eng. C 11, 19–25 (2000)
Files, B., Olson, G.: Terminator 3: biomimetic self-healing alloy composite in SMST. In: Proceedings of Second International Conference on Shape Memory and Superelastic Technology, pp. 281–286. Pacific Grove, CA (1997)
Fox-Rabinovich, G.S., Totten, G.E. (eds.): Self-organization during friction: advance surface engineered materials and systems design. CRC Taylor and Francis, Boca Raton, FL (2006)
Ghosh, S.K. (ed.): Self-Healing Materials: Fundamentals, Design Strategies, and Applications. Wiley WCH, Weinheim (2009)
Ghosh, P.K., Ray, S., Rohatgi, P.K.: Incorporation of alumina particles in aluminum-magnesium alloy by stirring the melt. Trans Jn. Inst. Metals. 25, 440–444 (1984)
De Groot, S.R., Mazur, P.: Non-Equilibrium Thermodynamics. Interscience, NY (1962)
Hautakangas, S.: Positron Annihilation Spectroscopy as a Tool to Develop Self Healing in Aluminium Alloys. In Proceedings of 14th International Conference on Positron Annihilation, ICPA 14, July 23–28, 2006
Hautakangas, S., Schut, H., van der Zwaag, S., Rivera Diaz del Castillo, P.E.J., van Dijk, N.H.: Positron annihilation spectroscopy as a tool to develop self-healing in aluminum alloys. Phys. Status. Solid. 4, 3469–3472 (2007a)
Hautakangas, S., Schut, H., van der Zwaag, S., del Castillo, R.D., van Dijk, N.H.: The role of the aging temperature in the self-healing kinetics in an underaged AA2024 aluminum alloy. Proceedings of 1st International Conference on Self-Healing Materials, Noordwijik aan Zee, The Netherlands, 18–20 April 2007.
Hautakangas, S., Schut, H., van Dijk, N.H.: Self-healing of deformation damage in underaged Al-Cu-Mg alloys. Scripta Mater. 58, 719–722 (2008)
He, S.M., van Dijk, N.H., Schut, H., van der Zwaag, S.: Self healing in Fe-Cu and Fe-Cu-B-N-Ce alloys studied by positron annihilation spectroscopy. In Proceedings of 2nd International Conference on Self-healing Materials, Chicago, 2009.
Jha, A.K., Prasad, S.V., Upadhyaya, G.S.: Sintered 6061 aluminium alloy – solid lubricant particle composites: sliding wear and mechanism of lubrication. Wear 133, 163 (1989)
Jones, F.R., Zhang, W., Hayes, S.A.: Thermally induced self-healing of thermosetting resins and matrices of smart composites. In: van der Zwaag, S. (ed.) Self Healing Materials – An Alternative Approach to 20 Centuries of Materials Science. Springer, Dordrecht, The Netherlands (2007)
Jonkers, H.M.: Self healing concrete: a biological approach. In: van der Zwaag, S. (ed.) Self healing materials – An Alternative Approach to 20 Centuries of Materials Science, pp. 195–204. Springer, New York (2007)
Jonkers, H.M., Schlangen, E.: Towards a sustainable bacterially-mediated self healing concrete. Proceedings of 2nd International Conference on Self-Healing Materials, Chicago (2009)
Kalra, A., Garde, S., Hummer, G.: Osmotic water transport through carbon nanotube membranes. Proc. Natl. Acad. Sci. U.S.A 100, 10175–10180 (2003)
Kim, S., Lorente, S., Bejan, A.: Vascularized materials: tree-shaped flow architectures matched canopy to canopy. J. Appl. Phys. 100, 063525 (2006)
Laha, K., Kyono, J., Sasaki, T., Kishimoto, S., Shinya, N.: Improved creep strength and creep ductility of type 347 austenitic stainless steel through the self-healing effect of boron for creep cavitation. Metal. Mater. Trans. 36A, 399–409 (2005)
Laha, K., Kyono, J., Shinya, N.: Some chemical and microstructural factors influencing creep cavitation resistance of austenitic stainless steels. Phil. Mag. 87, 2483–2505 (2007a)
Laha, K., Kyono, J., Shinya, N.: An advanced creep cavitation resistance Cu-containing 18Cr-12Ni-Nb austenitic stainless steels. Scripta Mater. 56, 915–918 (2007b)
Lee, E.-K., Amano, R.S., Rohatgi, P.K.: Metal matrix composite solidification in the presence of cooled fibers: numerical simulation and experimental observation. Heat Mass Transfer 43, 741–748 (2007)
Lee, L., Kim, S., Lorente, S., Bejan, A.: Vascularization with trees matched canopy to canopy: diagonal channels with multiple sizes. Int. J. Heat Mass Transfer 51, 2029–2040 (2008)
Liu, Z.W., Bando, Y., Mitome, M., Zhan, J.: Unusual freezing and melting of gallium encapsulated in carbon nanotubes. Phys. Rev. Lett. 93, 095504 (2004)
Lucci, J.M., Amano, R., Rohatgi, P.K.: Computational analysis of self-healing in a polymer matrix with microvascular networks. Proceedings of ASME Design Engineering Technical Conference 2008DETC, ASME, NY (2008)
Lucci, J.M., Amano, R., Rohatgi, P.K., Schultz, B.: Experimental and computational analysis of self-healing in an aluminum alloy. Proceedings of Mechanical Congress and Exhibition, IMECE2008-68304 (2008a)
Lucci, J.M., Amano, R.S., Rohatgi, P.K., Schultz, B.: Self-healing in an aluminum alloy reinforced with microtubes. Proceedings of Energy Nano08 2008b ASME Turbo Expo, ENIC2008-53011
Lumley, R.: Advances in self healing of metals. In: van der Zwaag, S. (ed.) Self Healing Materials: an Alternative Approach to 20 Centuries of Materials Science. Springer Series in Materials Science, vol. 100, pp. 219–254. Springer, Dordrecht (2007)
Lumley, R.M., Schaffer, G.B.: Precipitation induced densification in a sintered Al-Zn-Mg-Cu alloy. Scripta Mater. 55, 207–210 (2006)
Lumley, R.N., Morton, A.J., Polmear, L.J.: Enhanced creep performance in an Al-Cu-Mg-Ag alloy through underageing. Acta Mater. 50, 3597–3608 (2002)
Lumley, R.N., Polmear, L.J., Morton, A.J.: Interrupted aging and secondary precipitation in aluminum alloys. Mater. Sci. Technol. 19, 1483–1490 (2003)
Manuel, M.V.: Design of a biomimetic self healing alloy composite. PhD thesis, Northwestern University (2007)
Manuel, M.V.: Principles of self-healing in metals and alloys: an introduction. In: Ghosh, S.K. (ed.) Self-healing Materials: Fundamentals, Design Strategies, and Applications, pp. 251–266. Wiley WCH, Weinheim (2009)
Manuel, M.V., Olson, G.B.: Biomimetic self-healing metals. Proceedings of 1st International Conference on Self-Healing Materials, Noordwijik aan Zee, The Netherlands, 18–20 April 2007
Manuel, M., Olson, G.B.: Biologically inspired self-healing metals. Proceednigs of 2nd International Conference on Self-healing Materials, Chicago, 2009
Nakao, W., Mori, S., Nakamura, J., Takahashi, K., Ando, K.: Self-crack-healing behavior of mullite/SiC particle/SiC whisker multi–composite and potential use for ceramic springs. J. Am. Ceramic Soc. 89, 1352–1357 (2006)
Nosonovsky, M.: From wear to self-healing in nanostructured biological and technical surfaces. Proceedings of ASME/STLE International Joint Tribology Conference IJTC2009, Memphis, ASME (2009)
M. Nosonovsky. Entropy in Tribology (2010a)
M. Nosonovsky. Self-organization at the frictional interface for green tribology. Phil. Trans. R. Soc. A (2010b)
Nosonovsky, M., Bhushan, B.: Multiscale friction mechanisms and hierarchical surfaces in nano- and bio-tribology. Mater. Sci. Eng. R 58, 162–193 (2007a)
Nosonovsky, M., Bhushan, B.: Multiscale Dissipative Mechanisms and Hierarchical Surfaces: Friction, Superhydrophobicity, and Biomimetics. Springer-Verlag, Heidelberg, Germany (2008d)
Nosonovsky, M., Esche, S.K.: A Paradox of decreasing entropy in multiscale Monte Carlo grain growth simulation. Entropy 10, 49–54 (2008a)
Nosonovsky, M., Esche, S.K.: Multiscale effects in crystal grain growth and physical properties of metals. Phys. Chem. Chem. Phys. 10, 5192–5195 (2008b)
Nosonovsky, M., Amano, R., Lucci, J.M., Rohatgi, P.K.: Physical chemistry of self-organization and self-healing in metals. Phys. Chem. Chem. Phys. 11, 9530–9536 (2009c)
Olson, G.B.: Computational design of hierarchically structured materials. Science 277, 1237–1242 (1997)
Olson, G.B., Hartman, H.: Martensite and life-displacive transformations as biological processes. Journal De Physique 43, 855–865 (1982)
Olson, G., Zhang, S., Manuel, M.: Self-healing metals: perspective from the Chicago school. In Proceedings of 2nd International Conference on Self-healing Materials, Chicago (2009)
Perkins, J.: Ti-Ni and Ti-Ni-X shape memory alloys. Metals Forum 4, 153–163 (1981a)
Perkins, J.: Shape memory behavior and thermoelastic martensitic transformations. Mater. Sci. Eng. 51, 181–192 (1981b)
Prigogine, I.: Introduction to thermodynamics of irreversible processes, 2nd edn. Interscience, New York, NY (1961)
Prigogine, I., Nicolis, G.: Self-organization in Non-equilibrium Systems. Wiley, NY (1977)
Rohatgi, P.K., Asthana, R., Das, S.: Solidification, structures, and properties of cast metal - ceramic particle composites. Int Metals Rev 31, 115–139 (1986)
Rohatgi, P.K., Pai, B.C., Panda, S.C.: Preparation of cast aluminum-silica particulate composites. J Mater. Sci. 14, 2277–2283 (1979)
Ryan, N.J.: Using platelet technology to seal and locate leaks in subsea umbilical lines. Offshore Technology Conference held in Houston, OTC-18882-PP, 30 April–3 May 2007
Sen, R., Govindaraj, A., Rao, C.N.R.: Metal-filled and hollow carbon nanotubes obtained by the decomposition of metal-containing free precursor molecules. Chem. Mater. 9, 2078–2081 (1997)
Shinya, N., Kyono, J., Laha, K.: Self-healing effect of boron nitride precipitation in austenitic stainless steel. J. Intell Mater Syst. Struct. 17, 1127–1133 (2006)
Sloof, W.G.: Self healing in coatings at high temperatures. In: van der Zwaag, S. (ed.) Self Healing Materials – An Alternative Approach to 20 Centuries of Materials Science, pp. 309–321. Springer, Dordrecht, The Netherlands (2007)
Slowik, M.A.: Research: Self-Healing Materials Using Electro-hydrodynamics. http://www.princeton.edu/~cml/html/research/self_healing.html (2009). Accessed 31 Oct 2009
Takahashi, K., Ando, K., Nakao, W., Tsutagawa, Y.: Effect of SiC nano-sizing on self-crack-healing during service. Proceedings of 1st International Conference on Self-Healing Materials, Noordwijik aan Zee, The Netherlands, 18–20 April 2007
Therriault, D., White, S.R., Lewis, J.A.: Chaotic mixing in threedimensional microvascular networks fabricated by direct-write assembly. Nat Mater. 2, 265–271 (2003)
Tolstoi, D.M.: Significance of the normal degree of freedom and natural normal vibrations in contact friction. Wear 10, 199–213 (1967)
Toohey, K.S., Sottos, N.R., Lewis, J.A., Moore, J.S., White, S.R.: Self-healing materials with microvascular netweorks. Nat Mater. 6, 581–585 (2007)
Trask, R.S., Williams, G.J., Bond, I.: Bioinspired self-healing of advanced composite structures using hollow glass fibers. J. R. Soc. Interface 4, 363–373 (2007)
Trask, R.S., Bond, I.P.: Biomimetic self-healing of advanced composite structures using hollow glass fibers. Smart Mater. Struct. 15, 704–710 (2006)
Wang, Z.X., Dutta, I., Majumdar, B.S.: Thermomechanical response of a lead-free solder reinforced with a shape-memory alloy. Scripta Mater. 54, 627–632 (2005)
White, S.R., Sottos, N.R., Geubelle, P.H., Moore, J.S., Kessler, M.R., Sriram, S.R., Brown, E.N., Viswanathan, S.: Autonomic healing of polymer composites. Nature 409, 794–797 (2001)
Williams, G.J., Trask, R.S., Bond, I.P.: Self-healing functionality for CFRP. Proceedings of 1st International Conference on Self-Healing Materials, Noordwijik aan Zee, The Netherlands, 18–20 April 2007
Wool, R.P.: Self-healing materials: a review. Soft Matter 4, 400–418 (2008)
Xiao, Y., Amano, R.S.: Aluminized composite solid propellant particle path in combustion chamber of solid rocket motor. Advances in Fluid Mechanics, pp. 153–164. WIT, UK (2006)
Zhang, M.Q., Rong, M.Z., Yin, T.: Self-healing polymers and polymer composites. In: Ghosh, S.K. (ed.) Self-healing Materials: Fundamentals, Design Strategies, and Applications, pp. 29–72. Wiley WCH, Weinheim (2009)
Zhou, B.L.: Bio-inspired study of structural materials. Mater. Sci. Eng. C 11, 13–18 (2000)
Zhu, A.W., Chen, J., Starke, E.A.: Precipitation strengthening in stress-aged Al-XCu alloys. Acta Mater. 48, 2239–2246 (2000)
Zucchelli, A., Minak, G., Lotti, F.: Self-repairing vitreous enamel coating for metal substrate. In Proceedings of 2nd International Conference on Self-Healing Materials, Chicago (2009)
van der Zwaag, S. (ed.): Self Healing Materials – An Alternative Approach to 20 Centuries of Materials Science. Springer, Dordrecht, The Netherlands (2007)
van der Zwaag, S.: Self-healing behaviour in man-made engineering materials: bioinspired but taking into account their intrinsic character. Phil. Trans. R. Soc. A 367, 1689–1704 (2009)
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Nosonovsky, M., Rohatgi, P.K. (2011). Thermodynamic Principles of Self-Healing Metallic Materials. In: Biomimetics in Materials Science. Springer Series in Materials Science, vol 152. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0926-7_2
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