Abstract
In zirconia systems, the tetragonal to monoclinic phase transformation which occurs at ~1000–1200°C is martensitic1,2 and stressinduced.3,4,5 As a result, when the elevated temperature phase is retained metastably at room temperature6 and the transformation is stress-induced,3–5,7 significant gains occur in strength and fracture toughness. The improved strength and toughness in most of these ZrO2 systems have been attributed to the tetragonal to monoclinic phase (t → m) transformation in the vicinity of the propagating cracks.7–16 The stress intensity is reduced upon phase transformation at the crack tip stress field, thereby requiring additional stress for crack extension. Also the transformation was greater, the nearer the transformation temperature Ms to the ambient temperature
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
E. C. Subbarao, H. S. Maiti and K. K. Srivastave, Martensitic transformation in zirconia, Phys. Stat. Sol., A21: 9 (1974).
G. K. Bansal and A. H. Heuer, Martensitic phase transformation in zirconia (ZrO2):I, Acta Metall., 20:1281; (1974).
G. K. Bansal and A. H. Heuer, Martensitic phase transformation in zirconia (ZrO2): II, ibid. 22: 409 (1974).
T. K. Gupta, F. F. Lange, and J. H. Bechtold, Effect of stress-induced phase transformation on the properties of polycrystalline zirconia containing metastable tetragonal phase, J. Mater. Sci., 13:1464 (1978);
T. K. Gupta, Role of stress-induced phase transformation in enhancing strength and toughness of zirconia ceramics, in: Fracture Mechanics of Ceramics, vol. 4, R. C. Bradt, D. P. H. Hasselman and F. F. Lange, ed. Plenum Pub. Corp., New York (1978).
R. C. Garvie, R. H. J. Hannink, and R. T. Pascoe, Ceramic steel, Nature (London), 258: 703 (1975).
N. Claussen, Stress-induced transformation of tetragonal ZrO2 particles in ceramics matrices, J. Am. Ceram. Soc. 61: 85 (1978).
T. K. Gupta, Sintering of tetragonal zirconia and its characteristics, Sci. Sintering, 10:205 (1978);
T. K. Gupta, J. H. Bechtold, R. C. Kuznicki, L. H. Cadoff, and B. R. Rossing, Stabilization of tetragonal phase in polycrystalline zirconia, J. Mater. Sci., 12: 2421 (1977).
C. A. Andersson and T. K. Gupta, Phase stability and transformation toughening in zirconia, in: Advances in Ceramics 3, Science and Technology of Zirconia, A. H. Heuer and L. W. Hobbs, ed., American Ceramic Society, Columbus, Ohio (1981).
F. F. Lange and D. J. Green, Effect of inclusion size on the retention of tetragonal Zr02: Theory and Experiments, in: Advances in Ceramics 3, Science and Technology of Zirconia; A. H. Heuer and L. W. Hobbs, ed., The American Ceramics Society, Columbus, Ohio (1981).
A. H. Heuer, Alloy design in partially stabilized zirconia, in: Advances in Ceramics 3, Science and Technology of Zirconia, A. H. Heuer and L. W. Hobbs, ed., The American Ceramic Society, Columbus, Ohio (1981).
N. Claussen and M. Ruhle, Design of transformation-toughened ceramics, in: Advances in Ceramics 3, Science and Technology of Zirconia, A. H. Heuer and L. W. Hobbs, ed., The American Ceramic Society, Columbus, Ohio (1981).
R. H. J. Hannink, K. A. Johnston, R. T. Pascoe, and R. C. Garvie, Microstructural changes during isothermal aging of a calcia partially stabilized zirconia alloy, in: Advances in Ceramics 3, Science and Technology of Zirconia, A. H. Heuer and L. W. Hobbs, ed., The American Ceramic Society, Columbus, Ohio (1981).
A. G. Evans, D. B. Marshall, and N. H. Burlingame, Transformation toughening in ceramics, in: Advances in Ceramics 3, Science and Technology of Zirconia, A. H. Heuer and L. W. Hobbs, ed., The American Ceramic Society, Columbus, Ohio, 1981.
D. L. Porter, A. G. Evans, and A. H. Heuer, Transformation toughening in partially stabilized zirconia (PSZ), Acta Metall., 27: 1649 (1979).
A. G. Evans and A. H. Heuer, Review-transformation toughening in ceramics: Martensitic transformations in crack-tip stress fields, J. Am. Ceram. Soc., 63: 241 (1980).
A. G. Evans, N. Burlingame, M. Drory, and W. M. Kriven, Martensitic transformation in zirconia - particle size effects and toughening, Acta Metall., 29: 447 (1981).
R. M. McMeeking and A. G. Evans, Mechanics of transformation-toughening in brittle materials, J. Am. Ceram. Soc., 65: 242 (1982).
A. H. Heuer, N. Claussen, W. M. Kriven and M. Ruhle, Stability of tetragonal Zr02 particles in ceramic matrices, J. Am. Ceram. Soc., 65: 642 (1982).
D. L. Porter and A. H. Heuer, Mechanisms of toughening partially stabilized zirconia (PSZ), J. Am. Ceram. Soc., 60: 183 (1977).
V. Vango and S. Roitti, “Equilibrium Phase Diagram of Zr02-Ce02 System,” Ceramurgia, 1: 4 (1971).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1984 Springer Science+Business Media New York
About this chapter
Cite this chapter
Gupta, T.K., Andersson, C.A. (1984). Low Temperature Mechanical Properties of CeO2-Alloyed Tetragonal Zirconia. In: Clark, A.F., Reed, R.P. (eds) Advances in Cryogenic Engineering Materials . Advances in Cryogenic Engineering, vol 30. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-9868-4_43
Download citation
DOI: https://doi.org/10.1007/978-1-4613-9868-4_43
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-9870-7
Online ISBN: 978-1-4613-9868-4
eBook Packages: Springer Book Archive