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Concerted Reactions

  • Francis A. Carey
  • Richard J. Sundberg

Abstract

There are many reactions in organic chemistry that give no evidence of involving intermediates when they are subjected to the usual probes for studying reaction mechanisms. Highly polar transition states do not seem to be involved either, since the rates of the reactions are insensitive to solvent polarity. Efforts to detect free-radical intermediates by physical or chemical means have not been successful, and the reaction rates are neither increased by initiators nor decreased by inhibitors of free-radical reactions. This lack of evidence for intermediates leads to the conclusion that the reactions are single-step processes in which bond making and bond breaking both contribute to the structure at the transition state, although not necessarily to the same degree. Such processes are called concerted reactions. There are numerous examples ofboth unimolecular and bimolecular concerted reactions.

Keywords

High Occupied Molecular Orbital Cycloaddition Reaction Orbital Symmetry Claisen Rearrangement Concerted Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1990

Authors and Affiliations

  • Francis A. Carey
    • 1
  • Richard J. Sundberg
    • 1
  1. 1.University of VirginiaCharlottesvilleUSA

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