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Mass spectra of organophosphorus esters and their alteration products

  • Conference paper
Residue Reviews

Part of the book series: Reviews of Environmental Contamination and Toxicology ((RECT,volume 63))

Abstract

There have been a number of recent reviews on the mass spectra of pesticides, including organophosphorus (OP) esters (Biros 1971 a and b, Wacks and Laurie 1971, Garrison et al. 1972, Gillis and Occolowitz 1972, Müller and Korte 1972). The mass spectra of biological esters, including OP esters, have also been extensively reviewed (Hanessian 1971, Milne 1971, Gouw 1972, Santoro 1972, Waller 1972); however, no comprehensive review on OP esters that are added to the environment and their alteration products has been published in which emphasis is placed on structure identification. With increasingly routine use of mass spectrometry and especially gas-liquid chromatography—mass spectrometry (GLC-MS) in pesticide residue and metabolite analysis, a wide variety of investigators find it necessary to interpret the mass spectra of OP compounds. It is mainly for this audience of nonspecialists in mass spectrometry that this review is designed.

This work was supported in part by a Research-Training Grant from the Rockefeller Foundation, New York, N.Y., with Federal funds from the Environmental Protection Agency under Grant R801837 and by the U.S. Department of Agriculture with funds made available through Cotton Incorporated, Project No. 74-655. The contents do not necessarily reflect the views and policies of either the Environmental Protection Agency or the U.S. Department of Agriculture, nor does mention of trade names or commerical products constitute endorsement or recommendation for use.

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  1. J. M. Desmarchelier

    Present address: Division of Entomology, CSIRO, P.O. Box 109, City, Canberra, A.C.T., Australia

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  1. Division of Toxicology and Physiology, Department of Entomology, University of California, Riverside, California, 92502, USA

    D. A. Wustner & T. R. Fukuto

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  1. Department of Entomology, University of California, 92502, Riverside, California, USA

    Francis A. Gunther

  2. Riverside, California, USA

    Jane Davies Gunther

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Desmarchelier, J.M., Wustner, D.A., Fukuto, T.R. (1976). Mass spectra of organophosphorus esters and their alteration products. In: Gunther, F.A., Gunther, J.D. (eds) Residue Reviews. Reviews of Environmental Contamination and Toxicology, vol 63. Springer, New York, NY. https://doi.org/10.1007/978-1-4613-9407-5_3

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