Abstract
Plasticization is widely used in polymer technology when it is needed to increase flow and thermoplasticity of plastic materials. A plasticizer in a polymer having many points of attachment along the polymer chains breaks the attachments and masks the centers of force for polymer-polymer intermolecular attraction by selectively solvating the polymer at these points. This produces much the same results as if fewer points of attachment had been present on the macromolecules originally. It is usually assumed that solvents or plasticizers of different types are attached to the polymer macromolecules by forces of different magnitude and that none are bound permanently.
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Zlatkevich, L. (1987). Application of Radiothermoluminescence to the Study of Polymer Systems. In: Radiothermoluminescence and Transitions in Polymers. Polymers Properties and Applications, vol 12. Springer, New York, NY. https://doi.org/10.1007/978-1-4613-8695-7_6
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