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Mesophase State of Polyorganophosphazenes

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Liquid Crystalline and Mesomorphic Polymers

Part of the book series: Partially Ordered Systems ((PARTIAL.ORDERED))

Abstract

Earlier it was believed [1] that an ordering at a level exceeding the short-range order of low molecular liquids cannot exist above the melting point in flexible-chain polymers which do not contain mesogenic groups. However, recently, a large number of polymers, for example, polyphosphazene, has been found, which cannot be described in the framework of the traditional classification of liquid crystals. An additional type of mesomorphic state, that of a conformationally disordered crystal, was suggested [2,3].

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References

  1. P.J. Flory, Adv. Polymer Sci. 59, 1 (1984).

    CAS  Google Scholar 

  2. B. Wunderlich, M. Müller, J. Grebovicz, and H. Baur, Adv. Polymer Sci. 87, 1 (1988).

    Article  Google Scholar 

  3. B. Wunderlich and J. Grebovicz, Adv. Polymer Sci. 60/61, 2 (1984).

    Google Scholar 

  4. Liquid Crystalline Order in Polymer,edited by N.S. Schneider, G.R. Desper, and J.J. Beres (Academic Press, New York, 1978).

    Google Scholar 

  5. S.V. Vinogradova, D.R. Tur, and I.I. Minosiants, Uspekhi Khim 53, 87 (1984).

    CAS  Google Scholar 

  6. G. Allen, C.J. Levis, and S.M. Todd, Polymer. J. 11, 44 (1970).

    Article  CAS  Google Scholar 

  7. T.P. Russel, D.P. Anderson, R.S. Stein, G.R. Desper, J.J. Beres, and N.S. Schneider, Macromolecules 17, 1795 (1984).

    Article  Google Scholar 

  8. T. Masuko, R.L. Simeone, J.H. Magill, and D.J. Plazek, Macromolecules 17, 2857 (1984).

    Article  CAS  Google Scholar 

  9. M. Kojima and F.H. Magill, Polymer. J. 26, 1971 (1985).

    Article  CAS  Google Scholar 

  10. M. Kojima and F.H. Magill, Makromol. Chem. 187, 649 (1985).

    Article  Google Scholar 

  11. J.H. Magill, J. Petermann, and U. Rieck. Colloid. Polymer. Sci. 264, 570 (1986).

    CAS  Google Scholar 

  12. V.S. Papkov, V.M. Litvinov, N.I. Dubovik, G.L. Slonimsky, D.R. Tur, S.V. Vinogradova, and V.V. Korshak, Dokl. Akad. Nauk SSSR 284, 1423 (1985).

    CAS  Google Scholar 

  13. H.R. Allcock and W.J. Cook, Macromolecules 7, 284 (1974).

    Article  CAS  Google Scholar 

  14. S.V. Vinogradova, D.R. Tur, I.I. Minosiants, L.I. Komarova, and V.V. Korshak, Acta Polymerica 33, 331 (1982).

    Article  CAS  Google Scholar 

  15. D.R. Tur, V.V. Korshak, S.V. Vinogradova, S.A. Pavlova, G.I. Timofeeva, Ts.A. Goguadse, and N.O. Alikhanova, Dokl. Akad. Nauk SSSR 291, 364 (1986).

    CAS  Google Scholar 

  16. V.G. Kulichikhin, E.K. Borisenkova, E.M. Antipov, D.R. Tur, S.V. Vinogradova, and N.A. Platé, Vysokomolek. Soedin. B 29, 484 (1987).

    CAS  Google Scholar 

  17. D.Ya. Tsvankin, V.S. Papkov, V.P. Shukov, Yu.K. Godovsky, V.S. Svistunov, and A.A. Zhdanov, J. Polymer Sci., Polymer Chem. Ed. 23, 1043 (1985).

    Article  CAS  Google Scholar 

  18. N.B. Sokolskaya, Ya.S. Freidzon, V.V. Kochervinsky, and V.P. Shibaev, Vysokomolek. Soedin. A 28, 300 (1986).

    CAS  Google Scholar 

  19. V.P. Popov, E.M. Antipov, S.A. Kuptsov, N.N. Kuzmin, I I Bezruk, and S.Ya. Frenkel’, Acta Polymerica 36, 131 (1985).

    Article  CAS  Google Scholar 

  20. P.J. Lemstra, N.A.Y.M. Aerle, and C.V.M. Vastiaansen, Polymer J. 19, 8598 (1987).

    Article  Google Scholar 

  21. N.G. Shirina, Ph.D. Thesis, Moscow, 1986.

    Google Scholar 

  22. A.V. Semakov, E.K. Borisenkova, B.S. Hodyrev, D.R. Tur, and V.G. Kulichikhin, Vysokomolek. Soedin. B 31, 830 (1989).

    Google Scholar 

  23. E.M. Antipov, V.G. Kulichikhin, E.K. Borisenkova, D.R. Tur, and N.A. Platé, Vysokomolek. Soedin. A 31, 2385 (1989).

    CAS  Google Scholar 

  24. W.H. Stockmayer and M. Fixman, J. Polymer Sci. C 12, 137 (1963).

    Google Scholar 

  25. J.E. Hearst, J. Chem. Phys. 40, 1506 (1964).

    Article  CAS  Google Scholar 

  26. M. Bohdanecky, Macromolecules 16, 1483 (1983).

    Article  CAS  Google Scholar 

  27. Y. Chatani and K. Yatsuyanagi, Macromolecules 20, 1042 (1987).

    Article  CAS  Google Scholar 

  28. D.R. Tur, G.I. Timofeeva, Z. Tuzar, and S.V. Vinogradova, Vysokomolek. Soedin. B 31, 712 (1989).

    CAS  Google Scholar 

  29. S.M. Aharoni, Polymer Preprints 22, 116 (1981).

    CAS  Google Scholar 

  30. L.K. Golova, G.Ya. Rudinskaya, S.A. Kuptsov, and N.V. Vasil’eva, Vysokomolek. Soedin. B32, 605 (1990).

    CAS  Google Scholar 

  31. P.K. Ho and M.C. Williams, Polymer Engrg. Sci. 21, 233 (1981).

    Article  CAS  Google Scholar 

  32. L. Sotles, D. Mikulasova, and J. Hudec, Chem. Zwesti. 35, 543 (1981).

    Google Scholar 

  33. C.A. Simonescu, B.C. Simonescu, J. Neamtu, and S. Joan, Polymer J. 28, 165 (1987).

    Article  Google Scholar 

  34. Rheology of Polymers,edited by G.V. Vinogradov and A.Ya. Malkin (Mir, Moscow, 1980).

    Google Scholar 

  35. V.G. Kulichikhin, A.Ya. Malkin, E.G. Kogan, and A.V. Volokhina, Khim. Volokna. 6, 26 (1978).

    Google Scholar 

  36. V.G. Kulichikhin, V.A. Platonov, L.P. Braverman, T.A. Rozdestvenskaya, E.S. Kogan, N.V. Vasil’eva, and A.V. Volokhina, Vysokomolek. Soedin. 29, 2537 (1987).

    CAS  Google Scholar 

  37. G.C. Berry, H. Nakayasu, and T.G. Fox, J. Polymer Sci., Polymer Phys. Ed. 17, 1825 (1979).

    Article  CAS  Google Scholar 

  38. G. Allen, C.J. Lewis, and S.M. Todd, Polymer J. 11, 3144 (1970).

    Google Scholar 

  39. B. Chu and C. Gulari, Macromolecules 12, 445 (1979).

    Article  CAS  Google Scholar 

  40. S.P. Papkov, Vysokomolek. Soedin. 24, 869 (1982).

    CAS  Google Scholar 

  41. A.Ya. Malkin, L.P. Braverman, E.P. Plotnikova, and V.G. Kulichikhin, Vysokomolek. Soedin. 18, 2596 (1976).

    CAS  Google Scholar 

  42. N.P. Krasnikova, D.E. Dreval, E.V. Kotova, E.P. Plotnikova, G.V. Vinogradov, G.P. Belov, and Z. Pelczbauer, Vysokomolek. Soedin. 24, 1423 (1982).

    CAS  Google Scholar 

  43. N.V. Vasil’eva, V.G. Kulichikhin, L.K. Golova, D.R. Tur, S.V. Vinogradova, and S.P. Papkov, Vysokomolek. Soedin. A 31, 852 (1989).

    Google Scholar 

  44. V.G. Kulichikhin, A.Ya. Malkin, and S.P. Papkov, Vysokomolek. Soedin. A26, 451 (1984).

    CAS  Google Scholar 

  45. D.G. Baird, in Polymer Liquid Crystals, Proceedings of the 2nd Symposium Division Polymer Chemistry, New York (1985).

    Google Scholar 

  46. G.V. Vinogradov, E.K. Borisenkova, and M.P. Zabugina, Dokl. Akad. Nauk SSSR 277, 614 (1984).

    CAS  Google Scholar 

  47. E. Baer, A. Hiltner, and H.D. Keith, Science 235, 1015 (1987).

    Article  CAS  Google Scholar 

  48. L.C. Sawyer and M. Jaffe, J. Mater. Sci. 21, 1897 (1986).

    Article  CAS  Google Scholar 

  49. V.G. Kulichikhin, O.V. Vasil’eva, I.A. Litvinov, E.M. Antipov, I.L. Parsamyan, and N.A. Platé, J. Appl. Polymer Sci., 42, 363 (1991).

    Article  CAS  Google Scholar 

  50. M.V. Tsebrenko, G.V. Vinogradov, T.I. Ablazova, and A.V. Yudin, Kolloid. J. 38, 200 (1976).

    CAS  Google Scholar 

  51. V.G. Kulichikhin, E.K. Borisenkova, D.R. Tur. V.V. Barancheeva, I.I. Konstantinov, E.M. Antipov, V.E. Dreval, and N.A. Platé, Vysokomolek. Soedin. A 31, 1636 (1989).

    CAS  Google Scholar 

  52. M. Amano and K. Nakagawa, Polymer J. 28, 263 (1987).

    Article  CAS  Google Scholar 

  53. A. Siegman, A. Dagan, and S. Kenig, Polymer J. 26, 1325 (1985).

    Article  Google Scholar 

  54. E.K. Borisenkova, D.R. Tur. I.A. Litvinov, V.G. Kulichikhin, and N.A. Plate, Vysokomolek. Soedin. A32, 1505 (1990).

    CAS  Google Scholar 

  55. R.A. Weiss, H. Wansoo, and L. Nicolais, Polymer Engrg. Sci. 27, 684 (1987).

    Article  CAS  Google Scholar 

  56. K.G. Blizard and D.G. Baird, Polymer Engrg. Sci. 27, 653 (1987).

    Article  CAS  Google Scholar 

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Authors
  1. V. G. Kulichikhin
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  2. E. M. Antipov
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  3. E. K. Borisenkova
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  4. D. R. Tur
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Moscow State University, 119899, Moscow B-234, Russia

    Valery P. Shibaev

  2. Department of Physics, San Jose State University, One Washington Square, San Jose, CA, 95192-0106, USA

    Lui Lam

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© 1994 Springer-Verlag New York, Inc.

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Kulichikhin, V.G., Antipov, E.M., Borisenkova, E.K., Tur, D.R. (1994). Mesophase State of Polyorganophosphazenes. In: Shibaev, V.P., Lam, L. (eds) Liquid Crystalline and Mesomorphic Polymers. Partially Ordered Systems. Springer, New York, NY. https://doi.org/10.1007/978-1-4613-8333-8_8

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  • DOI: https://doi.org/10.1007/978-1-4613-8333-8_8

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4613-8335-2

  • Online ISBN: 978-1-4613-8333-8

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