Abstract
The successful use of any material as a blanket or as a coolant in fusion reactors will depend on a very large number of properties, thermodynamic, physical, chemical, and otherwise. Herein, we review a number of important properties of lithium that pertain to its use as a blanket and/or coolant in a D-T fusion power plant. Among the topics we cover are natural abundance, thermodynamic and transport properties, characterization, analysis, control of species in lithium, and corrosion of materials (including electronic insulators) by molten lithium. Throughout this review we have attempted to indicate the importance of the individual properties as they would affect the overall design considerations of an operating reactor and to point out areas where information is lacking and where additional work is needed.
Work performed under the auspices of the United States Atomic Energy Commission.
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References
W. C. Gough and B. J. Eastlund, Scientific American, 224, 50 (1971).
D. J. Rose, Science, 172, 797 (1971).
J. L. Tuck, Nature 233, 593 (1971).
R. G. Mills, IEEE Spectrum, November, 24 (1971).
Proceedings of the British Nuclear Energy Society Conference on Nuclear Fusion Reactors, UKAEA Culham Laboratory, September 17–19, 1969, Published by the British Nuclear Energy Society, 1970.
D. Steiner, “A Review of the ORNL Fusion Feasibility Studies”, USAEC Report ORNL-TM-3222 (December 1970).
M. J. Lubin and A. P. Fraas, Scientific American, 224, 21 (1971).
J. E. Draley, B. R. T. Frost, D. M. Gruen, M. Kaminsky, and V. A. Maroni, “An Assessment of Some Materials Problems for Fusion Reactors,” in Proc. 1971 Intersociety Energy Conversion Engineering Conf., Society of Automotive Engineers, New York, N.Y., (1971), pp. 1065–1075.
E. F. Johnson, Reference 5, p. 441.
W. R. Grimes and S. Cantor, “Molten Salts as Blanket Fluids in Controlled Fusion Reactors”, presented as a Chapter in this Volume.
J. O. Cowles and A. D. Pasternak, “Lithium Properties Related to Use as a Nuclear Reactor Coolant” USAEC Report UCRL-50647 (April 1969).
D. Steiner, Nuclear Applications and Technology, 9 83 (1970).
J. D. Lee, Reference 5, p. 471.
S. Blow, J. S. Crocker, and B. O. Wade, Reference 5, p. 492.
A. P. Fraas, Reference 5, p. 1.
N. C. Christofilos, “Design for a High Power Density Astron Reactor”, USAEC Report UCRL-72957 (January 1971).
R. Hultgren, R. L. Orr, and K. K. Kelley, “Selected Values of Thermodynamic Properties of Metals and Alloys,” January 1970 Supplement, Inorganic Materials Research Division, Lawrence Radiation Laboratory (Berkeley), University of California.
A. Bernini and H. Cantoni, Nuovo Cimento, 8, 241 (1914).
I. G. Dillon, P. A. Nelson, and S. B. Swanson, J. Chem. Phys., 44, 4229 (1966).
T. B. Douglas, L. F. Epstein, J. L. Dever, and W. H. Howland, J. Am. Chem. SOC, 77, 2144 (1955).
I. I. Novikov, V. A. Gruzdev, O. A. Kraev, A. A. Odintsov, and V. V. Roshchupkin, High Temperature, 7, 65 (1969).
E. I. Gol’tsova, High Temperature, 4, 348 (1966).
E. E. Shpil’rain, Yu. A. Soldatenko, K. A. Yakimovich, V. A. Fomin, V. A. Savchenko, A. M. Belova, D. N. Kagan, and I. F. Dvaniova, High Temperature 3, 870 (1965).
I. I. Novikov, Yu. S. Trelin, and T. A. Tsyganova, High Temperature, 1140 (1960).
A. D. Pasternak, Mater. Sci. Eng., 3 65 (1968/69).
V. M. Anisimov and L. D. Volyak, High Temperature, 7 340 (1969).
D. V. Rigney, S. M. Kapelner, and R. E. Cleary, “The Vapor Pressure of Lithium Between 1307 and 1806°K,” CANEL Report TIM-844 (September 1965).
J. Bohdansky and H. E. J. Schins, J. Phys. Chem., 71, 215 (1967).
J. Bohdansky and H. E. J. Schins, J. Inorg. Nucl. Chem., 29. 2173 (1967).
J. W. Taylor, Phil. Mag., 46, 867 (1955). 30b. P. Y. Achener, “Alkali Metals Evaluation ProgramQuarterly Progress Report,” Report AGN-8202 (November 1966), p. 12.
L. D. Volyak and Yu. P. Os’minin, Buss. J. Phys. Chem., 42, 524 (1968).
N. A. Kalakutskaya, High Temperature, 6, 436 (1968).
D. V. Rigney, S. M. Kapelner, and R. E. Cleary, “The Viscosity of Lithium,” CANEL Report TIM-849 (July 1965).
I. I. Novikov, A. N. Soloviev, E. M. Khabakhnasheva, V. A. Gruzdev, A. I. Pridantzev, and M. Ya. Vasenina, J. Nuclear Energy, 4, 387 (1957). 34b. E. N. de C. Andrade, Proc. Roy. Soc. London, 211, 12 (1952).
E. E. Shpil’rain, I. F. Krainova, High Temperature, 8, 1036 (1970).
J. W. Cooke, J. Chem. Phys., 40, 1902 (1964).
M. N. Arnol’dov, M. N. Ivanovskii, V. I. Subbotin, and B. A. Shmatko, High Temperature, 5 723 (1967).
E. E. Shpil’rain and V. A. Savchenko, High Temperature, 6, 247 (1968).
D. V. Rigney, S. M. Kapelner, and R. E. Cleary, “The Electrical Resistivity of Lithium and Columbium-1 Zirconium Alloy to 1430°C,” CANEL Report TIM-854 (September 1965).
J. F. Freedman and W. D. Robertson, J. Chem. Phys., 34, 769 (1961).
F. Tepper, J. Zelenak, F. Roehlich and V. May, “Thermophysical and Transport Properties of Liquid Metals,” Report AFML-TR-65-99 (May 1965).
M. A. Hoffman and G. A. Carlson, “Calculation Techniques for Estimating the Pressure Losses for Conducting Fluid Flows in Magnetic Fields,” USAEC Report UCRL-51010 (February 1971).
A. Ott and A. Lodding, Z. Naturfoschg., 20A 1578 (1965).
A. Ott and A. Lunden, Z. Naturforschg., 19A, 822 (1964). 44b. A. Lodding and A. Ott, Z. Naturforschg., 21A, 1344 (1966).
J. S. Murry and R. M. Cotts, J. Chem. Phys., 48, 4938 (1968).
J. R. Stehn, M. D. Goldberg, B. A. Magurno, and R. Weiner-Chasman, “Neutron Cross Sections — Vol. I,” USAEC Report BNL-325 (May 1964).
E. Veleckis, “Physical Inorganic Chemistry Semiannual Report, July — December 1971,” USAEC Report ANL-7878 (March 1972), p. 1111.
L. L. Hill, Unpublished Ph.D. Thesis, University of Chicago (1938).
C. E. Messer, “A Survey Report on Lithium Hydride,” USAEC Report NYO-9470 (October 1960).
M. R. J. Perlow, Unpublished Ph.D. Thesis, University of Chicago (1941).
F. K. Heumann and O. N. Salmon, “The Lithium Hydride, Deuteride, and Tritide Systems,” USAEC Report KAPL 1667 (December 1956).
E. Veleckis and E. Van Deventer, “Physical Inorganic Chemistry Semiannual Report, January–June 1972,” USAEC Report ANL-7923 (in press).
C. G. Swain, E. C. Stivers, J. F. Reuwer, Jr., L. J. Schaad, J. Am. Chem. Soc, 80, 5885 (1958).
C. E. Messer, E. B. Damon, P. C. Maybury, J. Mellor, and R. A. Seales, J. Phys. Chem., 62, 220 (1958).
F. C. Chang, “A Study of Ternary Hydride Phases Formed by Reaction of LiH with Selected Metals,” Ph.D. Thesis, University of Denver (1968), University Microfilms, Inc. No. 68-17,837.
E. J. Cairns, C. E. Crouthamel, A. K. Fischer, M. S. Foster, J. C. Hesson, C. E. Johnson, H. Shimotake, and A. D. Tevebaugh, “Galvanic Cells with FusedSalt Electrolytes,” USAEC Report ANL-7316 (November 1967).
C. E. Johnson, R. R. Heinrich, and C. E. Crouthamel, J. Phys. Chem., 70, 242 (1966).
J. A. Plambeck, J. P. Elder, and H. A. Laitinen, J. Electrochem. Soc., 113, 931 (1966).
E. E. Hoffman, “Solubility of Nitrogen and Oxygen in Lithium and Methods of Lithium Purification,” in ASTM Special Technical Publication No. 272 (1960) p. 195. 59b. E. E. Hoffman, “Corrosion of Materials in Lithium at Elevated Temperatures,” USAEC Report ORNL-2674 (March 1959).
R. P. Eliott, Constitution of Binary Alloys-First Supplement, McGraw Hill, New York (1965), p. 219.
P. I. Fedorov and M. T. Su, Hua Hsueh Hsueh Pao (J. Chinese Chem. Soc.), 23, 30 (1957).
D. R. Secrist, “A Study of the Lithium-Boron-Carbon System,” USAEC Report KAPL-2182 (1962).
K. J. Kelly, E. W. Hobart, and R. G. Bjork, “Studies Concerning the Chemical States of Carbon, Nitrogen, and Oxygen in Alkali Metals,” Report CNLM-6337 (1965).
R. L. Eichelberger, R. L. McKisson, and B. G. Johnson, “Solubility of Refractory Metals and Alloys in Potassium and Lithium,” Report CR-1371 (1969).
W. Arbiter and S. Lazerus, “Purification of Lithium by Vacuum Distillation,” Report NDA-39 (1957).
B. D. Holt, Anal. Chem., 31, 51 (1959).
D. R. Vissers, J. T. Holmes, and P. A. Nelson, Trans. Am. Nuol. Soc, 14, 610 (1971).
D. R. Vissers, Argonne National Laboratory (private communication).
P. W. Benjamin, C. D. Kemshall, and D. L. E. Smith, “A Technique for Measuring the Tritium Content of Small Samples of Irradiated Lithium Metal,” AWRE Report NR/A-2/62 (October 1962).
L. Burris, F. A. Cafasso, R. J. Meyer, M. H. Barsky, and H. S. Edwards, “Interim Methods for the Analysis of Sodium and Cover Gas,” USAEC Report ANL/ST-6 (1971) p. 77.
P. A. Nelson, Argonne National Laboratory (private communication).
L. P. Pepkowitz and W. C. Judd, Anal. Chem., 22, 1283 (1950).
J. C. White, W. J. Ross, and R. Rowan, Anal. Chem., 26, 210 (1954).
N. I. Sax and H. Steinmetz, “Determination of Oxygen in Lithium Metal,” USAEC Report ORNL-2570 (October 1958).
R. J. Jaworowski, J. R. Potts, and E. W. Hobart, Anal. Chem., 35, 1275 (1963).
G. Goldberg, A. S. Meyer, and J. C. White, Jr., Anal. Chem., 32, 314 (1960).
G. Goldberg, Anal. Chem., 34, 1343 (1962).
Z. M. Turovtseva and N, F. Litvinova, Proceedings of the United Nations International Conference on the Peaceful Uses of Atomic Energy (2nd Geneva Conference), 28, 593 (1958).
J. C. Bate and G. W. Leddicote, Oak Ridge National Laboratory Analytical Chemistry Division Annual Progress Report, January–December 1957, USAEC Report ORNL-2453 (January 1958).
L. C. Bate, Nucleonics, 21, 72 (1963).
E. L. Steele and R. Lukens, Development of Neutron Activation Analysis Procedures for the Determination of Oxygen in Potassium, 1st and 2nd Quarterly Progress Reports, Report GA-4855 (January 1964).
J. Faraday and C. R. Bingham, “Determination of Oxygen, Carbon, and Nitrogen in Lithium and Lithium Hydride by Photon-Activation Analysis,” NRL Report PB-181071 (1962).
E. E. Konovalov, I. B. Dmitrieva, M. N. Arnol’dov, V. P. Emel’yanov, A. V. Milovidora, A. G. Karabash, and M. N. Ivanovskii, Zhurnal Analiticheskoi Khimii, 23, 1510 (1968).
R. F. Gahn, Anal. Chem., 41, 1303 (1969).
G. P. Stavropoulos and F. A. Cafasso, Trans. Am. Nucl. Soc., 14, 621 (1971).
L. G. Hays and D. O’Connor, “A 2000°F Lithium Erosion and Component Performance Experiment,” NASA Report No. 32-1150 (1967).
W. A. Ross, E. T. Weber, B. R. Grundy, and E. Berkey, Trans Am. Nucl. Soc., 14, 621 (1971).
Zirconium Corporation of America (Zircoa).
T. W. Gilbert, A. S. Meyer, and J. C. White, Anal. Chem., 29, 1627 (1957).
J. R. Potts and W. E. Hobart, “The Determination of Carbon in Lithium,” USAEC Report TID-7606 (1960).
J. M. McKee, W. H. Caplinger, and M. Kolodney, Nuol. Applications, 5, 236 (1968).
D. F. Anthrop, “Solubilities of Transition Metals in Liquid Alkali and Alkaline Earth Metals, Lanthanum, and Cerium: A Critical Review of Literature,” USAEC Report UCRL-50315 (1968).
N. I. Sax, N.Y. Chu, R. H. Miles, and R. W. Miles, “Determination of Nitrogen in Lithium,” USAEC Report NDA-38 (June 1957).
H. Leavenworth, R. E. Cleary, and W. D. Bratton, “Solubility of Structural Metals in Lithium,” Report PWAC-356 (1961).
H. Leavenworth, R. E. Cleary, and W. D. Bratton, Acta Met., 9, 519 (1961).
Y. F. Bychkov, A. N. Rozanov, and V. B. Yakovelva, Atomnaya Energiya, 7 531 (1959).
R. F. Koenig, “Corrosion of Zirconia and Its Alloys in Liquid Metals,” USAEC Report KAPL-982 (1953).
R. E. Cleary, S. S. Blecherman, and J. E. Corliss, “Solubility of Refractory Metals in Lithium and Potassium,” PWAC Report TIM-850 (1965).
H. E. Evans and W. R. Watson, J. Nucl. Mater., 40, 195 (1971).
D. S. Jesseman, G. D. Roben, A. L. Grunewald, W. L. Fleshman, K. Anderson, and V. P. Calkins, “Preliminary Investigation of Metallic Elements in Molten Lithium,” Report NEPA-1465 (1950).
J. R. DiStefano, “Corrosion of Refractory Metals by Lithium,” USAEC Report ORNL-3551 (1964).
R. L. Klueh, Corrosion by Liquid Metals, J. E. Draley and J. R. Weeks, eds., Plenum Press, New York (1970), p. 177.
M. S. Freed and K. J. Kelly, “Corrosion of Columbium Base and Other Structural Alloys in High Temperature Lithium,” CANEL Report PWAC-355.
J. F. Cunningham, “Resistance of Metallic Materials to Corrosion Attack by High-Temperature Lithium,” USAEC Report ORNL-CF-51-7-135 (1951).
J. A. DeMastry and N. M. Greenauer, “Investigation of High-Temperature Refractory Metals and Alloys for Thermionic Converters,” USAF Report BMI-AFPL-TR 65-29 (1965).
J. H. Devan, A. P. Litman, J. R. Distefano, and C. E. Sessions, “Lithium and Potassium Corrosion Studies with Refractory Metals,” in Alkali Metal Coolants, International Atomic Energy Agency, Vienna (1967), p. 675.
A. Romano, A. Fleitman, and C. Klamut, “Behavior of Refractory Metals and Alloys in Boiling Sodium and Other Boiling Alkali Metals,” in Proceedings of the Alkali Metal Coolants Symposium, International Atomic Energy Agency, Vienna (1967).
R. W. Harrison, “The Effects of Welding Atmosphere on the Lithium Corrosion of Refractory Alloys,” in Corrosion by Liquid Metals, J. E. Draley and J. R. Weeks, eds., Plenum Press, New York (1970), p. 217.
C. E. Sessions, “Effects of Oxygen, Heat Treatment, and Test Temperature on the Compatibility of Several Advanced Refractory Alloys with Lithium,” USAEC Report ORNL-4430 (April 1971).
D. Elliot, D. Cerini, and L. Hays “Liquid MHD Power Conversion,” Space Programs Summary No. 37-41, Vol. IV, Jet Propulsion Laboratory, Pasadena, California (June 1966).
M. L. Kyle and J. R. Pavlik, Development of High Energy Batteries for Electric Vehicles, Progress Report for the Period July 1970–June 1971, USAEC Report ANL-7888 (December 1971), p. 59.
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Cairns, E.J., Cafasso, F.A., Maroni, V.A. (1972). A Review of the Chemical, Physical, and Thermal Properties of Lithium that are Related to its Use in Fusion Reactors. In: Gruen, D.M. (eds) The Chemistry of Fusion Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4595-4_3
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