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Ionic Liquids

  • John O’M. Bockris
  • Ronald A. Fredlein

Abstract

The probability that a hole in a liquid will have a radius between r and r + dr is P dr and is given by
$$ P\,dr=(16{a^{7/2}}r^{6}/15{\pi^{1/2}})\, {\rm exp}(-ar^{2})dr $$
(6.1.1)
where
$$ a=4\pi \gamma /kT $$
(6.1.2)
and γ is the surface tension of the liquid. Show that the mean hole volume v h is given by
$$P \,dr=(16{a^{7/2}}r^{6}/15{\pi^{1/2}})\, {\rm exp}(-ar^{2})dr $$
(6.1.3)
Use the data of Table 6.1.1 to calculate the mean size of holes in molten salts and compare these values with the volumes of the ions concerned. Comment on the conclusion.

Keywords

Ionic Liquid Molten Salt Transport Number Hole Formation Silver Deposition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1973

Authors and Affiliations

  • John O’M. Bockris
    • 1
  • Ronald A. Fredlein
    • 2
  1. 1.The Flinders UniversityAdelaideAustralia
  2. 2.The University of NewcastleAustralia

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