Abstract
The scattering of light by an atomic system was considered in the early days of quantum theory and is described by the KramersHeisenberg scattering formula1. This may be derived by straightforward perturbation theory2 though certain refinements are necessary to include level shifts3. For a two-level atom the scattering is elastic. The atom, initially in the ground state absorbs a photon k, makes a virtual transition to an excited state, then emits a photon k’ returning to its initial state. Energy conservation requires equality of the frequencies ωk = ωk’. The frequency dependence of the scattering cross-section σk divides into three regions. For low frequencies ωk ≪ ωo, where hωo is the separation of the atomic levels, we have Rayleigh scattering and σk ∿ ω 4k . For high frequencies ωk ≫ ωo, the electrons in the atom behave as if essentially free and we have frequency-independent Thomson scattering. For ωk ∿ ωo the cross-section exhibits a sharp peak which is the region of resonance fluorescence.
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© 1976 Plenum Press, New York
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Sheard, F.W. (1976). Spin-Phonon Interactions. In: Challis, L.J., Rampton, V.W., Wyatt, A.F.G. (eds) Phonon Scattering in Solids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4271-7_39
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DOI: https://doi.org/10.1007/978-1-4613-4271-7_39
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