Abstract
Kinetic equations for first, second, and third order reactions between organic molecules and hydrophilic ions in micellar solutions are derived. The approach depends upon the validity of two new assumptions. First, in accord with other recent treatments, rate enhancements are assumed to arise primarily from the large increase in the relative concentrations of the organic and hydrophilic substrates upon incorporation into the micellar phase. Second, the Stern layer of the micelle is assumed to be saturated with respect to its counterion.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
C. A. Bunton, Prog. Solid State Chem., 8, 239 (1973).
J. H. Fendler, E. H. Fendler, “Catalysis in Micellar and Macromolecular Systems”, Academic Press, New York, 1975.
E. H. Cordes, Editor, “Reaction Kinetics in Micelles”, Plenum Press, New York, 1973.
E. H. Cordes, R. B. Dunlap, Accts. Chem. Res., 2, 329 (1969)
E. H. Cordes, C. Gitler, Prog. Biorg. Chem., 2,-1 (1973).
L. Romsted, Thesis, Indiana University, 1975.
K. Shirahama, Bull. Chem. Soc. Jap., 48, 2673 (1975).
I. V. Berezin, K. Martinek, A. K. Yatsimirskii, Russ. Chem. Revs., 42, 787 and references (1973).
K. Martinek, A. P. Osipov, A. K. Yatsimirskii, V. A. Dadali, I. V. Berezin, Tetrahedron Letters, 1279 and references (1975).
D. Stigter, J. Phys. Chem., 68, 3603 (1964).
D. Stigter, K. J. Mysels, J. Phys. Chem., 59, 45 (1955).
E. W. Anaker, in “Cationic Surfactants”, E. Jungerman, Editor, p. 203, Marcel Dekker, New York, 1970.
D. Stigter, J. Phys. Chem., 70, 1323 (1966).
K. C. Evans, J. Chem. Soc., Pt. 1, 579 (1956).
C. Botré, V. L. Crescenzi, A. Mele, J. Phys. Chem., 63, 297 (1969).
J. W. Larsen, L. G. Magid, J. Amer. Chem. Soc., 96, 5774 (1969).
G. C. Kresheck, in “Water: A Comprehensive Treatise”,F. Franks, Editor, Vol. 4, p. 95, Plenum Press, New York, 1975.
A. Ray, P. Mukerjee, J. Phys. Chem., 70, 2138 (1966).
P. Mukerjee, A. Ray, J. Phys. Chem., 70, 2150 (1966).
K. D. Heckmann, R. F. Woodbridge, in “Proc. IVth Intern. Cong. Sur. Act. Sub.”, Vol. 2, p. 519, Gordon and Breach, New York, 1967.
K. J. Mysels, L.H. Princen, J. Phys. Chem., 63, 1696 (1959).
K. Shinoda, in “Proc. IVth Intern. Cong. Sur. Act. Sub.”, Vol. 2, p. 527, Gordon and Breach, New York, 1967.
L. R. Romsted, E. H. Cordes, J. Amer. Chem. Soc., 90, 4404 (1968).
J. Albrizzio, J. Archila, T. Rudolfo, E. H. Cordes, J. Org Chem., 37, 871 (1972).
J. L. Kurz, J. Phys. Chem., 66, 2239 (1962)
H. Nogami, Y. Kanakubo, Chem.-Pharm. Bull. (1963).
C. A. Bunton, B. Wolfe, J. Amer. Chem. Soc., 95, 3742 (1973).
C. A. Bunton, L. G. Ionescu, J. Amer. Chem. Soc., 95, 2912 (1973).
C. A. Bunton, B. Wolfe, J. Amer. Chem. Soc., 96, 7747 (1974).
R. B. Dunlap, E. H. Cordes, J. Amer. Chem. Soc., 90, 4395 (1968).
C. A. Bunton, R. J. R.bin, Tetrahedron Letters, 55 (1975).
J. Baumrucker, M. Calzadilla, M. Centeno, G. Lehrman, M. Urdaneta, P. Linguist, D. Dunham, M. Price, B. Sears, E. H. Cordes, J. Amer. Chem. Soc., 94, 8164 (1972).
R. N. Linguist, E. H. Cordes, J. Amer. Chem. Soc., 90, 1269 (1968).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1977 Plenum Press, New York
About this chapter
Cite this chapter
Romsted, L.S. (1977). A General Kinetic Theory of Rate Enhancements for Reactions between Organic Substrates and Hydrophilic Ions in Micellar Systems. In: Mittal, K.L. (eds) Micellization, Solubilization, and Microemulsions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4157-4_2
Download citation
DOI: https://doi.org/10.1007/978-1-4613-4157-4_2
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-4159-8
Online ISBN: 978-1-4613-4157-4
eBook Packages: Springer Book Archive