Skip to main content
  • 565 Accesses

Abstract

Approximately 30 distinct perturbations of potential, current, and charge have been used in the study of electrode processes. However, no more than 10 to 12 techniques have been widely used, partly because of the difficulty in solving the differential equations relating the response to time for many of the methods proposed. A few of the more popular techniques are described schematically in Table 2.1.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D. T. Sawyer and J. L. Roberts, Jr., Experimental Electrochemistry for Chemists, Wiley (Interscience), New York (1974).

    Google Scholar 

  2. R. N. Adams, Electrochemistry at Solid Electrodes, Marcel Dekker, New York (1969).

    Google Scholar 

  3. P. Delahay, New Instrumental Methods in Electrochemistry, Interscience, New York (1954).

    Google Scholar 

  4. I. M. Kolthoff and J. J. Ungane, Polarography, 2nd ed., Interscience, New York (1952).

    Google Scholar 

  5. A. T. Hubbard and F. C. Hanson, in: Electroanalytical Chemistry (A. J. Bard, ed.), Vol. 4, pp. 129–214, Marcel Dekker, New York (1970).

    Google Scholar 

  6. A. J. Bard and K. S. V. Santhanan, in: Electroanalytical Chemistry (A. J. Bard, ed.), Vol. 4, pp. 215–315, Marcel Dekker, New York (1970).

    Google Scholar 

  7. L. Meites, Polarographic Techniques, 2nd ed., Interscience, New York (1965).

    Google Scholar 

  8. D. Ilkovic, Coll. Czech. Chem. Commun. 8, 13 (1936).

    CAS  Google Scholar 

  9. L. Nemec, J. Electroanal. Chem. 8, 166 (1964).

    Article  CAS  Google Scholar 

  10. W. B. Schaap and P. S. McKinney, Anal. Chem. 36, 1251 (1964).

    Article  CAS  Google Scholar 

  11. I. M. Kolthoff, J. C. Marshall, and S. L. Gupta, J. Electroanal. Chem. 3, 209 (1962).

    Article  CAS  Google Scholar 

  12. J. Devoy, Acta. Chim. Acad. Sci. Hung. 35, 255 (1963).

    Google Scholar 

  13. J. Newman, J. Electrochem. Soc. 113, 501 (1966).

    Article  CAS  Google Scholar 

  14. W. G. French and T. Kuwana, J. Phys. Chem. 68, 1279 (1964).

    Article  CAS  Google Scholar 

  15. H. Angerstein-Kozlowska, B. E. Conway, and W. B. A. Sharp, J. Electroanal. Chem. 43, 9 (1973).

    Article  CAS  Google Scholar 

  16. V. Majer, J. Vesely, and K. Stulik, J. Electroanal. Chem. 45, 113 (1973).

    Article  CAS  Google Scholar 

  17. R. J. Taylor and A. A. Humffay, J. Electroanal. Chem. 42, 347 (1973).

    Article  CAS  Google Scholar 

  18. H. H. Uhlig, Corrosion and Corrosion Control, 2nd ed., Wiley, New York (1971).

    Google Scholar 

  19. R. Piontelli, G. Poli, and G. Serravalle, in: Transactions of the Symposium on Electrode Processes (E. Yeager, ed.), p. 67, Wiley (Interscience), New York (1961).

    Google Scholar 

  20. J. O’M. Bockris and B. E. Conway, J. Sci. Instr. 25, 283 (1948).

    Google Scholar 

  21. J. O’M. Bockris and M. Enyo, Trans. Faraday Soc. 58, 1187 (1962).

    Article  Google Scholar 

  22. E. Mattisson and J. O’M. Bockris, Trans. Faraday Soc. 55, 1856 (1959).

    Google Scholar 

  23. J. O’M. Bockris and H. Kita, J. Electrochem. Soc. 109, 928 (1962).

    Article  Google Scholar 

  24. R. Parsons and F. G. R. Zobel, Trans. Faraday Soc. 62, 3511 (1966).

    Article  CAS  Google Scholar 

  25. N. Berezina and N. V. Nikolaeva-Fedorovich, Elektrokhimiya 3, 3 (1967).

    CAS  Google Scholar 

  26. D. A. Jenkins and C. J. Weedon, J. Electroanal. Chem. 31, 13–14 (1971).

    Article  Google Scholar 

  27. E. Conway, H. Angerstein-Kozlowska, W. B. A. Sharp, and E. E. Criddle, Anal. Chem. 45, 1331 (1973).

    Article  CAS  Google Scholar 

  28. J. G. Graeme, G. E. Tobey, and L. P. Huelsman, Operational Amplifiers: Design and Applications, McGraw-Hill, New York (1971).

    Google Scholar 

  29. R. Kalvoda, Chem. Listy 66 (9), 897 (1972).

    Google Scholar 

  30. R. R. Schroeder, in: Computers in Chemistry and Instrumentation (J. S. Mattson, H. B. Mark, and H. C. MacDonald, eds.), Marcel Dekker, New York (1972).

    Google Scholar 

  31. R. Gabe, Br. Corros. J. 7, 236 (1972).

    Google Scholar 

  32. Operational Amplifier Symposium, Anal. Chem. 35, 1770 (1963).

    Article  Google Scholar 

  33. J. A. VonFraunhofer and C. H. Banks, Potentiostat and Its Applications, Butterworths, London (1972).

    Google Scholar 

  34. M. Prazak, Slaboproudy Doz. 17, 237 (1956).

    Google Scholar 

  35. A. Hickling, Trans. Faraday Soc. 38, 27 (1942).

    Article  CAS  Google Scholar 

  36. W. M. Schwarz and I. Shain, Anal. Chem. 35, 1770 (1963).

    Article  CAS  Google Scholar 

  37. J. D. E. Mclntyre and W. F. Peck, Jr., J. Electrochem. Soc. 117, 747 (1970).

    Article  Google Scholar 

  38. K. B. Oldham, J. Electroanal. Chem. 11, 171 (1966).

    Article  CAS  Google Scholar 

  39. J. C. Imbeaux and J. M. Savéant, J. Electroanal. Chem. 31, 183 (1971).

    Article  CAS  Google Scholar 

  40. J. C. Imbeaux and J. M. Savéant, J. Electroanal. Chem. 28, 325 (1970).

    Article  Google Scholar 

  41. W. T. de Vries and E. van Dalen, J. Electroanal. Chem. 10, 183 (1965).

    Article  Google Scholar 

  42. S. Roma and M. Lavacchielli, J. Electroanal. Chem. 22, 117 (1969).

    Article  Google Scholar 

  43. Garreau J. M and J. M. Savéant. J. Electroanal. Chem. 35, 309 (1972).

    Article  CAS  Google Scholar 

  44. G. Booman and W. Holbrook, Anal. Chem. 35, 1793 (1963).

    Article  CAS  Google Scholar 

  45. G. Booman and W. Holbrook, Anal. Chem. 37, 795 (1965).

    Article  CAS  Google Scholar 

  46. Bewick, Electrochim. Acta 13, 825 (1967).

    Article  Google Scholar 

  47. G. Lauer and R. Osteryoung, Anal. Chem. 38, 1106 (1966).

    Article  CAS  Google Scholar 

  48. A. Pilla, J. Electrochem. Soc. 116, 1105 (1969).

    Article  CAS  Google Scholar 

  49. A. A. Pilla in: Computers in Chemistry and Instrumentation (J. S. Mattson, H. B. Mark, and H. C. MacDonald, eds.), Marcel Dekker, New York (1972).

    Google Scholar 

  50. R. Brown, T. G. McCord, D. E. Smith, and D. D. DeFord, Anal. Chem. 38, 1119 (1966).

    Article  CAS  Google Scholar 

  51. R. Brown, D. E. Smith, and G. Booman, Anal. Chem. 40, 1411 (1968).

    Article  CAS  Google Scholar 

  52. E. R. Brown, H. L. Hung, T. G. McCord, D. E. Smith, and G. Booman, Anal. Chem. 40, 1424 (1968).

    Article  CAS  Google Scholar 

  53. E. E. Wells, Anal. Chem. 43, 87 (1971).

    Article  CAS  Google Scholar 

  54. S. Perone, Anal. Chem. 38, 1158 (1966).

    Article  CAS  Google Scholar 

  55. O. R. Brown, Electrochim. Acta 13, 317 (1968).

    Article  CAS  Google Scholar 

  56. N. R. DeTacconi, A. J. Calandra, and A. J. Arvia, Electrochim. Acta 18, 571 (1973).

    Article  CAS  Google Scholar 

  57. D. Britz and W. A. Brocke, J. Electroanal. Chem. 58, 301 (1975).

    Article  CAS  Google Scholar 

  58. C. C. Krischer and R. A. Osteryoung, J. Electrochem. Soc. 112, 735 (1965).

    Article  CAS  Google Scholar 

  59. J. Newman, J. Electrochem. Soc. 117, 507 (1970).

    Article  CAS  Google Scholar 

  60. A. Hickling, Trans. Faraday Soc. 33, 1540 (1937).

    Article  CAS  Google Scholar 

  61. K. Nisancioglu and J. Newman, J. Electrochem. Soc. 120, 1339 (1973).

    Article  CAS  Google Scholar 

  62. R. Bezman, Anal. Chem. 44, 1781 (1972).

    Article  CAS  Google Scholar 

  63. J. Devay, B. Lengyel, and L. Meszaros, Acta Chim. (Budapest) 66, 269 (1970).

    CAS  Google Scholar 

  64. B. R. Sundhein, J. Electrochem. Soc. 115, 158 (1968).

    Article  Google Scholar 

  65. J. W. Hayes and C. N. Reilly, Anal. Chem. 37, 1322 (1965).

    Article  CAS  Google Scholar 

  66. D. Pouli, J. R. Huff, and J. C. Pearson, Anal. Chem. 38, 382 (1966).

    Article  CAS  Google Scholar 

  67. T. B. Warner and S. Schuldiner, J. Electrochem. Soc. 114, 359 (1967).

    Article  CAS  Google Scholar 

  68. P. E. Whitson, H. W. Vanden Born, and D. H. Evans, Anal. Chem. 45, 1298 (1973).

    Article  CAS  Google Scholar 

  69. D. E. Smith, Crit. Rev. Anal. Chem. 2, 247 (1971).

    Article  Google Scholar 

  70. F. Jovic and I. Kontusic, J. Electroanal. Chem. 50, 269 (1974).

    Article  CAS  Google Scholar 

  71. T. R. Mueller and H. C. Jones, Chem. Instrum. 2, 65 (1969).

    Article  CAS  Google Scholar 

  72. T. Rabuzin, G. Smiljanic, and F. Jovic, J. Electroanal. Chem. 27, 397 (1970).

    Article  CAS  Google Scholar 

  73. J. E. Harrar and C. L. Pomernaki, Anal. Chem. 45, 57 (1973).

    Article  CAS  Google Scholar 

  74. W. C. Carter, Instrum. Contr. Syst. 40, 107 (1967).

    Google Scholar 

  75. D. T. Pence and G. L. Booman, Anal. Chem. 38, 1112 (1966).

    Article  CAS  Google Scholar 

  76. D. Garreau and J. M. Savéant, J. Electroanal. Chem. 50, 1 (1974).

    CAS  Google Scholar 

  77. E. V. Bohn, The Transform Analysis of Linear Systems, Addison-Wesley, Reading, Massachusetts (1963).

    Google Scholar 

  78. G. E. Roberts and H. Kaufman, Table of Laplace Transforms, Saunders, Philadelphia, Pennsylvania (1966).

    Google Scholar 

  79. A. Bewick and M. Fleischmann, Electrochim. Acta 11, 1397 (1966).

    Article  CAS  Google Scholar 

  80. A. Bewick and M. Fleischmann, Electrochim. Acta 8, 89 (1963).

    Article  CAS  Google Scholar 

  81. R. D. Armstrong, D. Porter, and H. R. Thrisk, J. Electroanal. Chem. 14, 17 (1967).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1977 Plenum Press, New York

About this chapter

Cite this chapter

Macdonald, D.D. (1977). Experimental Methods. In: Transient Techniques in Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4145-1_2

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-4145-1_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4147-5

  • Online ISBN: 978-1-4613-4145-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics