Abstract
Microanalytical techniques were first developed by Pregl [1] for the determination of elementary composition of organic materials. Such procedures provided a means of characterization for materials such as products of biological processes which were available in small amounts only. The observation of precipitation reactions under the microscope [2] permitted the scaling down of qualitative analytical procedures for inorganic materials, and the formation of colors and precipitates was used for qualitative microanalysis in Feigl’s “Tüpfelanalyse” (spot analysis)[3]. However, the separation methods of chemical quantitative (“wet”) analysis were difficult to adapt, mainly because of the strong capillary effects in the manipulation of liquids in the microscopic domain.
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Heinrich, K.F.J. (1978). Methods of Microprobe Analysis. In: Toribara, T.Y., Coleman, J.R., Dahneke, B.E., Feldman, I. (eds) Environmental Pollutants. Environmental Science Research, vol 13. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4033-1_16
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