Skip to main content

Electrochemical Synthesis and Characterization of Tetrathioethylenes in Nonaqueous Solvents

  • Conference paper
Characterization of Solutes in Nonaqueous Solvents

Abstract

The chemistry of tetrathioethylenes (TTEs) is dominated by their electron donor properties and reversible step-wise oxidation to radical cations and dications (Equation 1).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. See S. Hünig and H. C. Steinmetzer, J. Liebigs Ann. Chem., 1060, 1090 (1976) for recent papers in this series.

    Article  Google Scholar 

  2. D. H. Geske and M. V. Merritt, J. Amer. Chem. Soc., 91, 6921 (1969).

    Article  CAS  Google Scholar 

  3. N. D. Canfield, J. Q. Chambers, and D. L. Coffen, J. Electroanal. Chem., 24, A7 (1970).

    Article  Google Scholar 

  4. D. L. Coffen, J. Q. Chambers, D. R. Williams, P. E. Garrett, and N. D. Canfield, J. Amer. Chem. Soc., 93, 2258 (1971).

    Article  CAS  Google Scholar 

  5. S. Hünig, H. Schlaf, G. Kiesslich, and D. Scheutzow, Tetrahedron Lett., 2271 (1969).

    Google Scholar 

  6. J. Ferraris, D. O. Cowan, V. Walatka, Jr., and J. H. Perlstein, J. Amer. Chem. Soc., 95, 948 (1973).

    Article  CAS  Google Scholar 

  7. L. B. Coleman, J. J. Cohen, D. J. Sandman, F. G. Yamagashi, A. J. Garito, and A. J. Heeger, Solid State Commun., 12, 1125 (1973).

    Article  CAS  Google Scholar 

  8. M. R. Suchanski and R. P. Van Duyne, J. Amer. Chem. Soc., 98, 250 (1976).

    Article  CAS  Google Scholar 

  9. T. J. Kistenmacher, T. E. Phillips, and D. O. Cowan, Acta Crystallogr., Sect. B, 30, 763 (1974).

    Article  CAS  Google Scholar 

  10. G. A. Thomas, et al., Phys. Rev. B, 13B, 5105 (1976).

    Article  Google Scholar 

  11. M. J. Cohen, L. B. Coleman, A. F. Garito, and A. J. Heeger, ibid., p 5111.

    Google Scholar 

  12. T. D. Schultz and S. Etemad, ibid., p 4928.

    Google Scholar 

  13. P. M. Chaikin, J. F. Kwak, R. L. Green, S. Etemad, and E. M. Engler, Solid State Commun., 19, 1201 (1976).

    Article  CAS  Google Scholar 

  14. E. M. Engler and V. V. Patel, J. Amer. Chem. Soc., 96, 7376 (1974).

    Article  CAS  Google Scholar 

  15. A. N. Bloch, D. O. Cowan, K. Bechgaard, R. E. Pyle, R. H. Banks, and T. O. Poehler, Phys. Rev. Lett., 34, 1561 (1975).

    Article  CAS  Google Scholar 

  16. F. Wudl, D. Wobschall, and E. J. Hufnagel, J. Amer. Chem. Soc., 94, 670 (1972).

    Article  CAS  Google Scholar 

  17. B. A. Scott, J. B. Torrance, S. J. LaPlaca, P. Corfield, D. C. Green, and S. Etemad, Bull. Amer. Phys. Soc., 20, 496 (1975).

    Google Scholar 

  18. S. J. LaPlaca, P. W. R. Corfield, R. Thomas, and B. A. Scott, Solid State Commun., 17, 635 (1975).

    Article  CAS  Google Scholar 

  19. D. J. Dahm, G. R. Johnson, F. L. May, M. G. Miles, and J. D. Wilson, Cryst. Struct. Commun., 4, 673 (1975).

    CAS  Google Scholar 

  20. J. J. Daly and F. Sanz, Acta Cryst., B31, 620 (1975).

    CAS  Google Scholar 

  21. R. B. Somoano, A. Gupta, V. Hadek, T. Datta, M. Jones, R. Deck, and A. M. Hermann, J. Chem. Phys., 63, 4970 (1975).

    Article  CAS  Google Scholar 

  22. R. J. Warmack, T. A. Callcott, and C. R. Watson, Phys. Rev. B, 12, 3336 (1975).

    Article  CAS  Google Scholar 

  23. B. A. Scott, F. B. Kaufman, and E. M. Engler, J. Amer. Chem. Soc., 98, 4342 (1976).

    Article  CAS  Google Scholar 

  24. E. M. Engler, Chem. Technology, 6, 274 (1976).

    CAS  Google Scholar 

  25. F. Wudl, J. Amer. Chem. Soc., 97, 1962 (1975).

    Article  CAS  Google Scholar 

  26. F. B. Kaufman, E. M. Engler, D. C. Green, and J. Q. Chambers, J. Amer. Chem. Soc., 98, 1596 (1976).

    Article  CAS  Google Scholar 

  27. V. D. Parker, J. Amer. Chem. Soc., 96, 5656 (1974)

    Article  CAS  Google Scholar 

  28. M. E. Peover, Electrochim. Acta, 13, 1083 (1968).

    Article  CAS  Google Scholar 

  29. E. M. Engler, F. B. Kaufman, D. C. Green, C. E. Klots, and R. N. Compton, J. Amer. Chem. Soc., 97, 2921 (1975).

    Article  CAS  Google Scholar 

  30. A. F. Garito and A. J. Heeger, Accts. Chem. Res., 7, 232 (1974).

    Article  CAS  Google Scholar 

  31. N. D. Canfield, Ph.D. Thesis, The University of Tennessee, Knoxville, Tennessee, 1974.

    Google Scholar 

  32. R. S. Nicholson and I. Shain, Anal. Chem., 36, 706 (1964).

    Article  CAS  Google Scholar 

  33. R. Dietz and B. E. Larcombe, J. Chem. Soc., B, 1369 (1970).

    Google Scholar 

  34. R. E. Sioda, J. Phys. Chem., 72, 2322 (1968).

    Article  CAS  Google Scholar 

  35. M. F. Marcus and M. D. Hawley, Biochim. Biophys. Acta, 201, 1 (1970).

    CAS  Google Scholar 

  36. A. I. Popov and D. H. Geske, J. Amer. Chem. Soc., 80, 5346 (1958)

    Article  CAS  Google Scholar 

  37. I. V. Nelson and R. T. Iwamoto, J. Electroanal. Chem., 7, 218 (1964)

    Article  CAS  Google Scholar 

  38. F. Magno, G. Mazzocchin, and G. Bontempelli, J. Electroanal. Chem., 47, 461 (1973).

    Article  CAS  Google Scholar 

  39. R. M. Harnden, P. R. Moses and J. Q. Chambers, J.C.S. Chem. Commun., 11 (1977).

    Google Scholar 

  40. M. T. Reetz, Angew. Chem. Int. Ed., 13, 402 (1974).

    Article  Google Scholar 

  41. M. T. Reetz, Tetrahedron, 29, 2189 (1973).

    Article  CAS  Google Scholar 

  42. J. F. O’Donnel, J. T. Ayres, and C. K. Mann, Anal. Chem., 37, 1161 (1965).

    Article  Google Scholar 

  43. M. Walter and L. Ramaley, Ibid., 45, 165 (1973).

    CAS  Google Scholar 

  44. J. A. Lanning and J. Q. Chambers, Ibid., 45, 1010 (1973).

    CAS  Google Scholar 

  45. L. R. Melby, H. D. Hartzler, and W. A. Sheppard, J. Org. Chem., 39, 2456 (1974)

    Article  CAS  Google Scholar 

  46. F. Wudl and M. L. Kaplan, ibid., p 3608.

    Google Scholar 

  47. S. Hünig, G. Kiesslich, H. Quast, and D, Scheutzow, J. Liebigs Ann. Chem., 310 (1973).

    Google Scholar 

  48. S. Wawzonek and S. M. Heilmann, J. Org. Chem., 39, 511 (1974)

    Article  CAS  Google Scholar 

  49. P. R. Moses and J. Q. Chambers, J. Amer. Chem. Soc., 94, 945 (1974).

    Article  Google Scholar 

  50. M. Mizuno, M. P. Cava, and A. F. Garito, J. Org. Chem., 41 1484 (1976).

    Article  CAS  Google Scholar 

  51. R. M. Harnden, M. S. Thesis, The University of Tennessee, Knoxville, Tennessee, 1976.

    Google Scholar 

  52. R. N. Adams, “Electrochemistry at Solid Electrodes,” Marcel Dekker, Inc., New York, NY (1969).

    Google Scholar 

  53. P. Calas, J. M. Fahre, E. Toreilles, and L. Giral, C. R. Acad. Sci. Paris, Ser. C, 280, 901 (1975).

    CAS  Google Scholar 

  54. L. B. Coleman, F. G. Yamagishi, A. F. Garito, and A. J. Heeger, Phys. Lett., 51A, 412 (1975).

    CAS  Google Scholar 

  55. P. R. Moses, Ph.D. Thesis, The University of Tennessee, Knoxville, Tennessee, 1974.

    Google Scholar 

  56. H. D. Hartzler, J. Amer. Chem. Soc., 95, 4379 (1973).

    Article  CAS  Google Scholar 

  57. K. Bechgaard, D. O. Cowan, and A. N. Bloch, Mol. Cryst., Liq. Cryst., 32, 227 (1976).

    Article  CAS  Google Scholar 

  58. E. M. Engler, D. C. Green, and J. Q. Chambers, J.C.S. Chem. Commun., 148 (1976).

    Google Scholar 

  59. R. C. Wheland and J. L. Gilson, J. Amer. Chem. Soc., 98, 3916 (1976).

    Article  CAS  Google Scholar 

  60. C. K. Mann in “Electroanalytical Chemistry,” Vol. 3, A. J. Bard, editor, Marcel Dekker, Inc., New York, p. 64 (1969).

    Google Scholar 

  61. J. Q. Chambers and D. C. Green, unpublished result.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1978 Plenum Press, New York

About this paper

Cite this paper

Chambers, J.Q., Harnden, R.M., Canfield, N.D. (1978). Electrochemical Synthesis and Characterization of Tetrathioethylenes in Nonaqueous Solvents. In: Mamantov, G. (eds) Characterization of Solutes in Nonaqueous Solvents. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3982-3_8

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-3982-3_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3984-7

  • Online ISBN: 978-1-4613-3982-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics