Skip to main content

Recent Electroanalytical Studies in Molten Fluorides

  • Conference paper
Characterization of Solutes in Nonaqueous Solvents
  • 149 Accesses

Abstract

We have been interested for some time (1–32) in the application of modern electroanalytical methods to the study of molten fluoride salt systems of interest to nuclear reactor technology. The development of in situ (in-line) monitoring techniques has been one of the main goals of this research. An obvious advantage of in-line monitoring is that it would provide immediate knowledge of the behavior of the reactor fuel and at the same time eliminate sampling and other time consuming procedures. Experience with this and other programs has generally demonstrated the value of in-line analysis, both in more economical analyses and, frequently, in more timely and meaningful results.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D. L. Manning, J. Electroanal. Chem., 6, 227 (1963).

    Article  CAS  Google Scholar 

  2. D. L. Manning and G. Mamantov, J. Electroanal. Chem., 6, 328 (1963).

    Article  CAS  Google Scholar 

  3. D. L. Manning, J. Electroanal. Chem., 7, 302 (1964).

    Article  CAS  Google Scholar 

  4. D. L. Manning and G. Mamantov, J. Electroanal. Chem., 7, 102 (1964).

    Article  CAS  Google Scholar 

  5. G. Mamantov, D. L. Manning, and J. M. Dale, J. Electroanal. Chem., 9, 253 (1965).

    Article  CAS  Google Scholar 

  6. D. L. Manning, J. M. Dale, and G. Mamantov, in Polarography, 1964, G. J. Hills, ed., Vol. 2, p. 1143, MacMillan, London, 1966.

    Google Scholar 

  7. G. Mamantov and D. L. Manning, Anal. Chem., 38, 1494 (1966).

    Article  CAS  Google Scholar 

  8. J. P. Young, G. Mamantov, and F. L. Whiting, J. Phys. Chem., 71, 782 (1967).

    Article  CAS  Google Scholar 

  9. D. L. Manning and G. Mamantov, Electroanal. Chem., 17, 137 (1968).

    Article  Google Scholar 

  10. G. Mamantov and D. L. Manning, J. Electroanal Chem., 18, 309 (1968).

    Article  CAS  Google Scholar 

  11. H. W. Jenkins, G. Mamantov, and D. L. Manning, J. Electroanal. Chem., 19, 385 (1968).

    Article  CAS  Google Scholar 

  12. H. W. Jenkins, Jr., “Electrochemical Measurements in Molten Fluorides,” Ph.D. Dissertation, The University of Tennessee, March 1969.

    Google Scholar 

  13. G. Mamantov, in Molten Salts; Characterization and Analysis, G. Mamantov, ed., M. Dekker, New York, N.Y. 1969.

    Google Scholar 

  14. D. L. Manning and J. M. Dale, in Molten Salts: Characterization and Analysis, G. Mamantov, ed., M. Dekker, New York, N.Y. 1969.

    Google Scholar 

  15. H. W. Jenkins, G. Mamantov, D. L. Manning, and J. P. Young, J. Electrochem. Soc., 116, 1712 (1969).

    Article  CAS  Google Scholar 

  16. H. W, Jenkins, G. Mamantov, and D. L. Manning, J. Electrochem. Soc., 117, 183 (1970).

    Article  CAS  Google Scholar 

  17. F. L. Whiting, “Studies of the Superoxide Ion and Otner Solute Species in Molten Fluorides,” Ph.D. Dissertation, The University of Tennessee, August 1970.

    Google Scholar 

  18. D. L. Manning and G. Mamantov, High Temp. Sci., 3, 533 (1971).

    CAS  Google Scholar 

  19. F. R. Clayton, Jr., “Electrochemical Studies in Molten Fluorides and Fluoroborates,” Ph.D. Dissertation, The University of Tennessee, March 1972.

    Google Scholar 

  20. H. R. Bronstein and D. L. Manning, J. Electrochem. Soc., 119, 125 (1972).

    Article  CAS  Google Scholar 

  21. F. R. Clayton, Jr., G. Mamantov, and D. L. Manning, J. Electrochem. Soc., 120, 1193 (1973).

    Article  CAS  Google Scholar 

  22. F. R. Clayton, Jr., G. Mamantov, and D. L. Manning, J. Electrochem. Soc., 120, 1199 (1973).

    Article  CAS  Google Scholar 

  23. F. R. Clayton, Jr., G. Mamantov, and D. L. Manning, High Temp. Sci., 5, 358 (1973).

    CAS  Google Scholar 

  24. G. Ting, “Thermodynamic and Electrochemical Studies of Niobium in Molten Fluorides and Chloroaluminates,” Ph.D. Dissertation, The University of Tennessee, August 1973.

    Google Scholar 

  25. F. L. Whiting, G. Mamantov, and J. P. Young, J. Inorg. Nucl. Chem., 35, 1553 (1973).

    Article  CAS  Google Scholar 

  26. J. S. Hammond and D. L. Manning, High Temp. Sci., 5, 50 (1973).

    CAS  Google Scholar 

  27. D. L. Manning and G. Mamantov, Electrochim. Acta, 19, 177 (1974).

    Article  CAS  Google Scholar 

  28. F. R. Clayton, Jr., G. Mamantov, and D. L. Manning, J. Electrochem. Soc., 121, 86 (1974).

    Article  CAS  Google Scholar 

  29. G. Mamantov, B. Gilbert, K. W. Fung, R. Marassi, P. Rolland, G. Torsi, K. A. Bowman, D. L. Brotherton, L. E. McCurry, and G. Ting, in Proceedings of the International Symposium on Molten Salts, J. P. Pemsler, ed., The Electrochemical Society, Princeton, New Jersey, 1976, pp. 234–239.

    Google Scholar 

  30. J. R. Keiser, D. L. Manning, and R. E. Clausing, in Proceedings of the International Symposium on Molten Salts, J. P. Pemsler, ed., The Electrochemical Society, Inc., Princeton, New Jersey, 1976, pp. 315–323.

    Google Scholar 

  31. D. L. Manning and G. Mamantov, High Temp. Sci., 8, 219 (1976).

    CAS  Google Scholar 

  32. D. L. Manning and G. Mamantov, J. Electrochem. Soc., 124, 480 (1977).

    Article  CAS  Google Scholar 

  33. M. W. Rosenthal, P. N. Haubenreich, and R. B. Briggs, Oak Ridge National Laboratory Report, ORNL-4812 (1972).

    Google Scholar 

  34. T. R. Mueller and H. C. Jones, Chem. Instrum., 2, 65 (1969).

    Article  CAS  Google Scholar 

  35. J. H. Shaffer, et al., Oak Ridge National Laboratory Report, ORNL-3951 (1964).

    Google Scholar 

  36. B. Gilbert, G. Mamantov, and G. M. Begun, Inorg. Nucl. Chem. Letters, 10, 1123 (1974).

    Article  CAS  Google Scholar 

  37. C. E. Bamberger, H. F. McDuffie and C. F. Baes, Jr., Nucl. Sci., and Eng., 22, 14 (1965).

    CAS  Google Scholar 

  38. D. Y. Valentine and A. D. Kelmers, Oak Ridge National Laboratory Report, ORNL-5078, 29 (1975).

    Google Scholar 

  39. L. E. McNeese in ref. 33, p. 331.

    Google Scholar 

  40. D. Cubicciotti, J. Electrochem. Soc., 115, 1138 (1968).

    Article  CAS  Google Scholar 

  41. A. S. Meyer, et al., Oak Ridge National Laboratory Report, ORNL-5047, 56 (1975).

    Google Scholar 

  42. R. S. Nicholson and I. Shain, Anal. Chem., 36, 706 (1964).

    Article  CAS  Google Scholar 

  43. W. H. Reinmuth, Anal. Chem., 32, 1514 (1960).

    Article  CAS  Google Scholar 

  44. P. Delahay, New Instrumental Methods in Electrochemistry, Interscience, New York, 1954, p. 184.

    Google Scholar 

  45. H. E. McCoy, in ref. 33, p. 207.

    Google Scholar 

  46. D. Y. Valentine and A. D. Kelmers, Oak Ridge National Laboratory Report, ORNL-5132, 24 (1976).

    Google Scholar 

  47. C. E. Bamberger, J. P. Young, and R. G. Ross, J. Inorg. Nucl. Chem., 36, 1158 (1974).

    Article  CAS  Google Scholar 

  48. L. M. Toth, Abstract ANAL-54, American Chemical Society Meeting, San Francisco, Calif., August 29-September 3, 1976.

    Google Scholar 

  49. R. W. Murray, in Physical Methods of Chemistry, Part IIA: Electrochemical Methods, A. Weissberger and B. W. Rossiter, eds., Wiley-Interscience, 1971, p. 601.

    Google Scholar 

  50. R. D. Armstrong, T. Dickinson, and K. Taylor, J. Electroanal. Chem., 64, 155 (1975).

    Article  CAS  Google Scholar 

  51. A. L. Bacarella and J. C. Griess, Jr., J. Electrochem. Soc., 120, 459 (1973).

    Article  CAS  Google Scholar 

  52. H. R. Bronstein and F. A. Posey, Oak Ridge National Laboratory Report, ORNL-5132, 29 (1976).

    Google Scholar 

  53. W. R. Grimes, in reference 33, p. Ill.

    Google Scholar 

  54. A. S. Meyer, et al., Oak Ridge National Laboratory Report, ORNL-4449, 157 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1978 Plenum Press, New York

About this paper

Cite this paper

Manning, D.L., Mamantov, G. (1978). Recent Electroanalytical Studies in Molten Fluorides. In: Mamantov, G. (eds) Characterization of Solutes in Nonaqueous Solvents. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3982-3_14

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-3982-3_14

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3984-7

  • Online ISBN: 978-1-4613-3982-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics