Abstract
In the early days of quantum chemistry research, major emphasis was placed on method development and calculations were performed on physical systems more to evaluate calculational methods than to gain new insight into these systems. The field has now matured to the point where present-day methods are capable of providing reliable information for systems of experimental interest, including those where large numbers of excited states are involved. Predicting the cross sections and products of photodissociation requires knowledge of large numbers of excited state potential curves or surfaces, particularly repulsive potential curves that are not easily studied spectroscopically. Also, theoretical study of collisions between excited species requires information about excited state potential curves. Calculations of excited state potential curves discussed in this paper support the assertion that current quantum chemistry techniques are now providing physical insight for systems of interest.
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© 1983 Plenum Press, New York
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Saxon, R.P. (1983). Excited States of Small Molecules — Collisional Quenching and Photodissociation. In: Hinze, J. (eds) Energy Storage and Redistribution in Molecules. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3667-9_10
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DOI: https://doi.org/10.1007/978-1-4613-3667-9_10
Publisher Name: Springer, Boston, MA
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