Abstract
The adsorption behavior of polyelectrolyte macro-molecules at an ionic interface, in part, define the ability of that polymer to function as an adhesive. The effects of altering macromolecular solution conformation, via added electrolyte, upon the structure of the adsorbed layer can be monitored by Fourier Transform Infrared Spectroscopy coupled with the technique of attenuated total reflectance. The experimental technique will be elaborated upon, and the results obtained will be expressed in terms of the amount of polymer adsorbed, and the apparent fraction of bound segments on adsorbed molecules.
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© 1983 Plenum Press, New York
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Belton, D.J., Stupp, S.I. (1983). The Relationship Between Adhesion and Polyelectrolyte Solution Conformation as Studied by Fourier Transform IR Spectroscopy. In: Mittal, K.L. (eds) Adhesion Aspects of Polymeric Coatings. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3658-7_12
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DOI: https://doi.org/10.1007/978-1-4613-3658-7_12
Publisher Name: Springer, Boston, MA
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