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Electrochemistry in Molten Salts

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Comprehensive Treatise of Electrochemistry

Abstract

According to recent developments in the field, the term molten salts can advantageously be widened in scope to encompass many molten media which may not be wholly ionic or derived from simple salts. Thus, many systems studied within this broad classification may change their ionicity and hence conductivity according to temperature, pressure, or composition, e.g., silicates, group IIB chlorides, and chloroaluminates, respectively. Nevertheless, the majority of melts that have been studied are substantially dissociated in the liquid state, and all processes conducted in these are ipso facto electrochemical. Many of the processes considered here, therefore, involve charge transfer systems, particularly between solids (mainly metals) and melts, viz., electrode processes.(1)

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Authors and Affiliations

  1. Department of Metallurgy & Materials Science, Imperial College, SW7 2BP, London, UK

    D. Inman

  2. Chemistry Branch, R.M.C.S., Shrivenham, Swindon, SN6 8LA, UK

    D. G. Lovering

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  1. D. Inman
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Editors and Affiliations

  1. Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada

    Brian E. Conway

  2. Department of Chemistry, Texas A&M University, College Station, Texas, USA

    John O’M. Bockris , Shahed U. M. Khan  & Ralph E. White ,  & 

  3. Case Laboratories for Electrochemical Studies, Case Western Reserve University, Cleveland, Ohio, USA

    Ernest Yeager

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Inman, D., Lovering, D.G. (1983). Electrochemistry in Molten Salts. In: Conway, B.E., Bockris, J.O., Yeager, E., Khan, S.U.M., White, R.E. (eds) Comprehensive Treatise of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3584-9_10

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