Synopsis
A soluble V (acac)3/Al(C2H5)2C1 system was found to polymerize propylene to give a syndiotactic “living” polypropylene having narrow molecular weight distribution \(({\bar M_w}/{\bar M_n} = 1.05 - 1.20)\) at temperatures below -65°C. The coupling reaction between iodine-terminated living polypropylene and monofunctional living polystyrene anion was examined at 50°C and shown to result in the quantitative formation of monodisperse AB block copolymer of propylene and styrene. In addition, sequential polymerization of ethylene and propylene was attempted in the presence of the soluble V (acac)3/Al (C2H5)2Cl system to synthesize block copolymers.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
P. J. Flory, J. Am. Chem. Soc., 62, 1561(1940).
L. Gold, J. Chem. Phys., 28, 91(1958).
M. Szwarc, Nature(London), 178, 1168(1956); M. Szwarc, M. Levy and R. Milkovich, J. Am. Chem. Soc., 78, 2656(1956).
M. Szwarc,;, “Carbanions, Living Polymers and Electron Trancfer Processes”, Interscience, New York, 1968.
H. Hostalka, R. V. Figini and G. V. Schulz, Makromol. Chem., 71, 198(1964).
H. L. Hsieh and O. F. McKinney, J. Polym. Sci. B, 4, 843(1966).
H. Hirota, M. Nakayama and N. Ise, J. Chem. Soc., Faraday trans. I, 68, 58(1972).
M. Szwarc and A. Rembaum, J. Polym. Sci,, 22, 189(1962).
M. Morton and F. R. Ells, J. Polym. Sci., 61, 721(1962).
L. J. Fetters and M. Morton, Macromolecules, 2, 453(1969).
M. Morton, R. F. Kammereck and L. J. Fetters, Macromolecules, 4, 11(1971).
G. Natta and I. Pasquon, Adv. Catal., 11, 1(1959).
G. Bier and G. Lehman, “Copolymerization”, G. E. Ham, Ed. Interscience, New York, 1964, Chapter 4, Section B, pl49.
G. Bier, Angew. Chem., 73, 186(1961).
E. G. Kontos, E. K. Esterbrook and R. D. Gilbert, J. Polym. Sci., 61, 69(1962).
P. Prabhu, A. Schindler, M. H. Theil and R. D. Gilbert, J. Polym. Sci, Polym. Lett. Ed., 18, 389(1980); J. Polym. Sci., Polym. Chem. Ed., 19, 523(1981).
Y. Doi, S. Ueki and T. Keii, Macromolecules, 12, 814(1979).
Y. Doi, S. Ueki and T. Keii, Makromol. Chem., 180, 1359 (1979).
Y. Doi, S. Ueki, S. Nagahara and T. Keii, “IUPAC International Symposium on Macromolecules”, at Florence (1980).
Y. Doi, S. Ueki and T. Keii, Polymer, 21, 1352 (1980).
H. Hsieh, J. Polym. Sci. A, 3 153, 163, 173 (1965).
Z. Grubisic, P. Rempp and H. Benoit, J. Polym. Sci. B, 753(1967).
T. Ogawa, S. Tanaka and S. Hoshino, Kobunshi Kagaku, 29, 6(1972).
A. E. Hamielec and W. H. Ray, J. Appl. Polym. Sci., 13 1319(1969).
A. E. Hamielec, J. Appl Polym. Sci.9 14, 1519 (1970).
L. F. Johnson, F. Heatly and F. A. Bovey, Macromolecules, 3, 175(1970).
Y. Doi and T. Asakura, Makromol. Chem., 176, 507 (1975).
G. Natta, I. Pasquon and A. Zambelli, J. Am. Chem. Soc., 84, 1488(1962).
A. Wurtz, Ann. Chim. Phys.5 44, 275(1855); Ann., 96, 364(1855).
T. Suzuki and Y. Takegami, Bull. Chem. Soc. Jpn., 43, 1484 (1970).
A. Zambelli, C. Tosi and C. Sacchi, Macromolecules, 5, 649 (1972).
A. Zambelli, P. Lacattelli and G. Bajo, Macromolecules, 12, 154(1979).
Y. Doi, Macromolecules, 12, 248(1979).
J. C. W. Chien, J. Am. Chem. Soc., 81, 86(1959).
H. Schnecko, K. A. Jung and L. Grosse, Makromol. Chem., 148, 67(1971).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Plenum Press, New York
About this chapter
Cite this chapter
Doe, Y., Ueki, S., Keii, T. (1983). “Living” Coordination Polymerization of Propylene and its Application to Block Copolymer Synthesis. In: Price, C.C., Vandenberg, E.J. (eds) Coordination Polymerization. Polymer Science and Technology, vol 19. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3575-7_13
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3575-7_13
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3577-1
Online ISBN: 978-1-4613-3575-7
eBook Packages: Springer Book Archive