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Phase Relationships, Basic Metallurgy, and Superconducting Properties of Nb3Sn and Related Compounds

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Part of the book series: Advances in Cryogenic Engineering ((ACRE,volume 28))

Abstract

Since the discovery of the high Tc superconductors, V3Si and Nb3Sn in 1953,1 the A15 type superconductors have been the subject of more than a thousand publications. The great interest in the A15 materials has, of course, been mainly motivated by their high TC values, the highest known to date having been measured for Nb3Ge: Tc = 23 K.2 From the known data it follows that the maximum Tc in an A15 type compound containing a nontransition element, i.e., Nb3Sn, Nb3Ge, Nb3Ga, Nb3A1, V3Si, or V3Ga, can only be reached if the following conditions are fulfilled: a) stoichiometric composition, b) perfect long-range atomic order, and c) stability of the cubic A15 phase at low temperatures.

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References

  1. G. F. Hardy and J. D. Hulm, Phys. Rev. 87:884 (1953); B. T. Matthias, T. H. Geballe, S. Geller, and E. Corenzwit, Phys. Rev. 95: 1435 (1954).

    Article  Google Scholar 

  2. J. R. Gavaler, Appl. Phys. Lett. 23: 480 (1973).

    Article  CAS  Google Scholar 

  3. L. D. Hartsough and R. H. Hammond, Sol. State Commun. 9: 885 (1971).

    Article  CAS  Google Scholar 

  4. R. H. Hammond and S. Hazra, in: “Proc. Low Temp. Phys. LT13,” Plenum Press, New York (1972), p. 465; G. R. Johnson and D. H. Douglas, J. Low Temp. Phys, 14:565 (1974) and 14:575 (1974); R. E. Somekh and J. E. Evetts, Sol. State Commun. 9:733 (1977); R. M. Waterstrat, F. Haensler, and J. Muller, J. Appl. Phys. 50:4763 (1979).

    Google Scholar 

  5. J. R. Gavaler, M. A. Janocko, and C. K. Jones, in: “Proc. Low Temp. Phys. LT13,” Vol. 3, Plenum Press, New York (1972), p. 558.

    Google Scholar 

  6. R. Mailfert, B. W. Batterman, and J. J. Hanak, Phys. Lett. 22: 315 (1967).

    Google Scholar 

  7. B. W. Batterman and C. S. Barrett, Phys. Rev. Lett. 13:390 (1964); Phys. Rev. 149: 296 (1966).

    Article  CAS  Google Scholar 

  8. R. Roberge, H. LeHuy, and S. Foner, Phys. Lett. 82A: 259 (1981).

    Article  Google Scholar 

  9. R. Flükiger, KfK Report No. 3140, Kernforschungszentrum Karlsruhe (unpublished) (Oct. 1980); R. Flükiger, W. Schauer, W. Specking, B. Schmidt, and E. Springer, IEEE Trans. Magn. MAG-17:2285 (1981). R. Flükiger, W. Schauer, W. Specking, L. Oddi, L. Pintschovius, W. Müllner, and B. Lachal, in: “Advances in Cryogenic EngineeringHHHMaterials,” Vol. 28, Plenum Press, New York (1982), p.

    Google Scholar 

  10. W. W. Wendtlandt, in: “Thermal Methods of Analysis,” 2d edition, P. J. Elving and I. M. Kotthoff, eds., John Wiley & Sons, New York (1974), and references therein.

    Google Scholar 

  11. R. Flükiger and J. L. Jorda, in: “Phase Diagrams in Metallurgy and Ceramics,” M. Carter, ed., National Bureau of Standards Special Publication No. 196 (1978), p. 375; R. Flükiger, in: “Superconductor Materials Science,” S. Foner and B. B. Schwartz, eds., Plenum Press, New York (1981), p. 511.

    Google Scholar 

  12. J. L. Jorda, R. Flükiger, and J. Muller, J. Mater. Sci. 13: 2471 (1978).

    Article  CAS  Google Scholar 

  13. J. L. Jorda, R. Flükiger, and J. Muller, J. Less-Common Met. 55: 249 (1977).

    Article  CAS  Google Scholar 

  14. J. L. Jorda, R. Flükiger, and J. Muller, J. Less-Common Met. 62: 25 (1978).

    Article  CAS  Google Scholar 

  15. J. L. Jorda, R. Flükiger, and J. Muller, J. Less-Common Met. 75:227(1980); J. Muller, Rep. Prog. Phys. 43: 641 (1980).

    Article  CAS  Google Scholar 

  16. R. Flükiger, J. L. Staudenmann, and P. Fischer, J. Less-Common Met. 50: 253 (1976).

    Article  Google Scholar 

  17. H. A. C. M. Brüning, Philips Res. Rep. 22: 349 (1967).

    Google Scholar 

  18. J. L. Jorda and J. Muller, to be published in J. Less-Common Met.

    Google Scholar 

  19. E. C. Van Reuth and R. M. Waterstrat, Acta Crystallogr. B24: 186 (1968).

    Article  Google Scholar 

  20. R. Flükiger, Ph.D. Thesis No. 1570, University of Geneva, Geneva, Switzerland (1972).

    Google Scholar 

  21. R. Flükiger and J. L. Jorda, Sol. State Commun. 22: 109 (1977). 412

    Google Scholar 

  22. A. Müller, Z. Naturforsch. 25A: 1659 (1970).

    Google Scholar 

  23. S. Moehlecke, A. R. Sweedler, and D. E. Cox, Phys. Rev. B21: 2712 (1980).

    Article  CAS  Google Scholar 

  24. R. Flükiger, J. L. Jorda, A. Junod, and P. Fischer, to be published in Appl. Phys. Commun.

    Google Scholar 

  25. J. Kwo, R. H. Hammond, and T. H. Geballe, J. Appl. Phys. 51: 1726 (1980).

    Article  CAS  Google Scholar 

  26. R. Flükiger, S. Foner, and E. J. McNiff, Jr., in: “Superconductivity in d- and f-Band Metals,” H. Suhl and M. B. Maple, eds., Academic Press, New York (1980), p. 265.

    Google Scholar 

  27. J. P. Charlesworth, I. Macphail, and P. E. Madsen, J. Mater. Sci. 5: 580 (1970).

    Article  CAS  Google Scholar 

  28. H. Devantay, J. L. Jorda, M. Decroux, J. Muller, and R. Fliikiger, to be published in J. Mater. Sci.

    Google Scholar 

  29. H. W. King, in: “The Mechanism of Phase Transformations in Crystalline Solids,” Monograph No. 33, Institute of Metals (1980), p. 196.

    Google Scholar 

  30. R. Flükiger and L. Oddi, to be published.

    Google Scholar 

  31. J. L. Staudenmann, Solid State Phys. 23:121 (1977), 26: 461 (1978).

    CAS  Google Scholar 

  32. R. Flükiger, unpublished results.

    Google Scholar 

  33. C. W. Chu and L. J. Vieland, J. Low Temp. Phys. 17: 25 (1974).

    Article  CAS  Google Scholar 

  34. L. J. Vieland, J. Phys. Chem. Solids 31: 1449 (1970).

    Article  CAS  Google Scholar 

  35. L. J. Vieland, R. W. Cohen, and W. Rehwald, Phys. Rev. Lett. 26: 373.

    Google Scholar 

  36. A. Junod, J. Muller, H. Rietschel, and E. Schneider, J. Phys. Chem. Solids 39: 317 (1978).

    Article  CAS  Google Scholar 

  37. A. J. Arko, D. H. Lowndes, F. A. Muller, L. W. Roeland, J. Wolfrat, A. T. Van Kessel, H. W. Myron, R. M. Muller, and G. W. Webb, Phys. Rev. Lett. 4: 1590 (1980).

    Google Scholar 

  38. P. Muller, Ph.D. Thesis, University of Erlangen, FRG (1980).

    Google Scholar 

  39. B. Pannetier, T. H. Gebballe, R. H. Hammond, and J. F. Gibbone, to be published in Proc. LT16, Los Angeles (1981).

    Google Scholar 

  40. T. P. Orlando, J. A. Alexander, S. J. Bending, J. Kwo, S. J. Poon, R. H. Hammond, R. Beasley, E. J. McNiff, Jr., and S. Foner, IEEE Trans. Magn. MAG-17: 368 (1981).

    Article  CAS  Google Scholar 

  41. L. J. Vieland and A. W. Wicklund, Phys. Rev. B 11: 3311 (1975).

    Article  CAS  Google Scholar 

  42. P. R. Sahm, Phys. Lett. 26A: 459 (1968).

    Article  CAS  Google Scholar 

  43. M. Lehmann, Ph.D. Thesis, University of Erlangen, FRG (1980).

    Google Scholar 

  44. M. Suenaga, in: “Superconductor Materials Science,” S. Foner and B. B. Schwartz, eds., Plenum Press, New York (1981).

    Google Scholar 

  45. L. J. Vieland and A. W. Wicklund, Physics Lett. 34A: 43 (1971).

    Article  CAS  Google Scholar 

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Flükiger, R. (1982). Phase Relationships, Basic Metallurgy, and Superconducting Properties of Nb3Sn and Related Compounds. In: Reed, R.P., Clark, A.F. (eds) Advances in Cryogenic Engineering Materials . Advances in Cryogenic Engineering Materials , vol 28. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3542-9_39

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  • DOI: https://doi.org/10.1007/978-1-4613-3542-9_39

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3544-3

  • Online ISBN: 978-1-4613-3542-9

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